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Journal of Fluorescence

, Volume 21, Issue 1, pp 289–297 | Cite as

Synthesis, Characterization and Photoluminescence Study of Novel Sulfobetaine Polyelectrolytes

  • Nazia Tarannum
  • Hirdyesh Mishra
  • Meenakshi Singh
Original Paper

Abstract

A novel sulfobetaine copolymer is developed via polycondensation approach. The comonomers, melamine, condenses with a diketone, 5,5-dimethyl-1,3-cyclohexane (dimedone) to produce polyimine chain based on Schiff base chemistry. Dimedone-[N,N’ melaminium] propane sulfonate copolymer crystals were obtained on treatment of the polyimine with sulfopropylating agent, 1,3-propane sultone with a crosslinker, di(ethylene glycol diacrylate) (DEGDA). This crosslinked sulfobetaine polymer yielded fine needle like single crystals and shows strong blue fluorescence and a week green phosphorescence. Multi-exponential fluorescence decay function indicates the presence of different conformers both in solution and crystalline phase. This easy straightforward protocol for synthesis of crystalline, soluble, and luminescent polymer could prove to be a landmark in development of next generation smart functional materials.

Keywords

Polyimine Sulfobetaine Crosslinking Luminescence 

Notes

Acknowledgements

The financial support by Department of Science and Technology [SR/S2/CMP-65/2007] is gratefully acknowledged. Authors acknowledge Prof.GVS Sastry (SEM), Dr. B Ray (GPC) and Dr. S Pant with his research group for their kind help. Authors are also highly thankful to Prof. C.D. Geddes, Director Institute of fluorescence, UMBC, Baltimore MD, USA for some of the time domain fluorescence measurements.

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Nazia Tarannum
    • 1
  • Hirdyesh Mishra
    • 2
  • Meenakshi Singh
    • 1
  1. 1.Department of Chemistry, MMVBanaras Hindu UniversityVaranasiIndia
  2. 2.Department of Physics, MMVBanaras Hindu UniversityVaranasiIndia

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