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Journal of Fluorescence

, Volume 18, Issue 2, pp 269–276 | Cite as

Photocharacterization of Novel Ruthenium Dyes and Their Utilities as Oxygen Sensing Materials in Presence of Perfluorochemicals

  • Ozlem Oter
  • Kadriye Ertekin
  • Osman Dayan
  • Bekir Cetinkaya
Original Paper

Abstract

Photophysical constants of three novel ruthenium dyes derived from tridentate pyridinediimine (pydim) ligands has been declared and their photoluminescent properties were investigated in solvents of dichloromethane (DCM), tetrahydrofuran (THF) and ethanol (EtOH) by UV-Visible absorption, emission and excitation spectra. The quantum yield, fluorescence decay time, molar extinction coefficient and Stoke’s shift values of the novel ruthenium complexes were determined. The perfluoro compound (PFC) nonadecafluorodecanoic acid which is also known as medical gas carrier has been used for the first time together with newly synthesized Ruthenium complexes in ethyl alcohol. The utilities of oxygen sensing materials were investigated in EtOH in presence of chemically and biochemically inert PFC.

Keywords

Perfluorochemicals (PFCs) Ruthenium complex Quantum yield Fluorescence spectroscopy Optical oxygen sensing 

Notes

Acknowledgements

We thank Prof. Dr. Jean-Marie Salmon and Dr. Anne-Cecile Ribou for allowing time resolved based studies in their laboratory. Funding for this research was provided by the TUBITAK and Scientific Research Funds of Dokuz Eylul University (Project No.: 04.kb.fen.105).

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Ozlem Oter
    • 1
  • Kadriye Ertekin
    • 1
    • 3
  • Osman Dayan
    • 2
  • Bekir Cetinkaya
    • 2
  1. 1.Faculty of Arts and Sciences, Department of ChemistryUniversity of Dokuz EylulIzmirTurkey
  2. 2.Faculty of Science, Department of ChemistryUniversity of EgeIzmirTurkey
  3. 3.Dokuz Eylul Universitesi Fen-Edebiyat Fakultesi Kimya BolumuIzmirTurkey

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