A Double-Layered {Cu9} Nanocage with Diacylhydrazine: Synthesis, Structure and Magnetic Properties

Abstract

The reaction of a multidentate diacylhydrazine ligand N,N′-bis(2-hydroxy-3-naphthoyl)oxalylhydrazide (H6hnohz) with copper acetate in the presence of pyridine (Py), resulted in a novel Cu nanocluster, [CuII9(hnohz)3(Py)8]·7DMSO (1). This nanocluster consists of a {CuII4} and a {CuII5} cluster units, which were linked together by the coordination bonds between them owing to the Jahn–Teller effects of the CuII centers and flexible coordination modes of the hnohz6− ligands. The Py was found to act as not only the deprotonating reagent in the synthesis, but the peripheral ligand in molecular structure. Whether in {CuII4} or in {CuII5} unit, the CuII ions are approximatively coplanar. And the meaning planes of two units are just parallel. Thus 1 displays a double-layered cage-like skeleton that was rarely reported in previous literature. Variable temperature magnetic susceptibility measurement revealed dominate antiferromagnetic couplings between the CuII ions in the system of 1.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21961008 and 21771043) and the Guangxi Natural Science Foundation (No. 2018GXNSFAA138123).

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Correspondence to Kai Wang or Shu-Ying Luo or Fu-Pei Liang.

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Huang, S., Xu, F., Qi, S. et al. A Double-Layered {Cu9} Nanocage with Diacylhydrazine: Synthesis, Structure and Magnetic Properties. J Clust Sci (2020). https://doi.org/10.1007/s10876-020-01838-z

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Keywords

  • Cu nanocage
  • Diacylhydrazine
  • Magnetic properties