Photoluminescence Properties of a New Sm(III) Complex/PMMA Electrospun Composite Fibers

Abstract

In this paper, a Sm(III) cluster-based 2D coordination polymer {[Sm(2-stp)·3(H2O)]·(H2O)}n, (where 2-stp = 2-sulfoterephthalate), 1 has been synthesized hydrothermally and doped into poly(methyl methacrylate (PMMA) fibers through electrospinning technique to get a new 1D luminescent composite fibers, Sm/PMMA. The crystal structure of Sm(III) complex has been determined by single crystal X-ray diffraction measurements. Sm/PMMA composite fibers have been characterized by field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), photoluminescence spectroscopy (PL), and thermogravimetric analysis (TGA) in comparison to that of the pure Sm(III) complex. The luminescent spectra of the composite nanofibers (Sm/PMMA) has demonstrated strong characteristic emission of Sm(III) ions and has also pointed out much better thermal stability than the pure Sm(III) complex.

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Acknowledgements

The authors are grateful to the Research Funds of Mugla Sitki Kocman University (BAP-2017/295 and BAP-2018/067) for the financial support, Dokuz Eylul University for the use of the Agilent Xcalibur Eos diffractometer (purchased under University Research Grant No. 2010.KB.FEN.13) and Balikesir University, Science and Technology Application and Research Center (BUBTAM) for the use of the Photoluminescence Spectrometer.

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Correspondence to Hulya Kara or Mustafa Burak Coban.

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Kara, H., Oylumluoglu, G. & Coban, M.B. Photoluminescence Properties of a New Sm(III) Complex/PMMA Electrospun Composite Fibers. J Clust Sci 31, 701–708 (2020). https://doi.org/10.1007/s10876-019-01677-7

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Keywords

  • Electrospinning
  • Luminescent nanofibers
  • Sm(III) complex
  • Crystal structure