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Five Transition-Metal-Substituted Polyoxometalates: Syntheses, Structures and Electrochemical Properties

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Abstract

A series of transition metal, such as Ni/Mn/Zn, substituted sandwich-type polyoxometalates, H9Na(enMe)3[Ni4(H2O)2(PW9O34)2]·31H2O (1), H8Na2[Ni4(H2O)2(PW9O34)2]·34H2O (2), H8Na2[Mn4(H2O)2(PW9O34)2]·29H2O (3), H4Na6[Mn4(H2O)2(PW9O34)2]·41H2O (4), H5Na7[Zn4(H2O)2(GeW9O34)2]·25H2O (5) have been synthesized under mild hydrothermal conditions and characterized by IR spectra, thermogravimetric analysis, elemental analysis, single-crystal X-ray diffraction and powder X-ray diffraction, respectively. The structure analysis reveals that 1–5 contain a similar sandwich-type polyoxoanion unit [M4(H2O)2(XW9O34)2]10−/12− (M = Ni2+/Mn2+/Zn2+; X = PV/GeIV), which are further linked by Na+ cations to form 1- to 3-D structures, respectively. Furthermore, the electrochemical properties of 1, 4 and 5 have been studied in 0.5 mol L−1 Na2SO4/H2SO4 supporting electrolyte, and show that 1, 4 and 5 possess comparatively apparent catalytic activities toward the NaNO2 or H2O2 reduction.

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Acknowledgements

This work was supported by the NSFC (Nos. 21571016, 21831001 and 91122028), the NSFC for Distinguished Young Scholars (No. 20725101).

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  1. MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Zhi-Hui Ni, Zhong Zhang & Guo-Yu Yang

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  1. Zhi-Hui Ni
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Correspondence to Guo-Yu Yang.

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Ni, ZH., Zhang, Z. & Yang, GY. Five Transition-Metal-Substituted Polyoxometalates: Syntheses, Structures and Electrochemical Properties. J Clust Sci 30, 637–645 (2019). https://doi.org/10.1007/s10876-019-01523-w

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