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Silver and Sodium Fluorescein Co-doped Phosphomolybdate Microspindle: Synthesis and Spectroscopic Properties

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Abstract

A novel phosphomolybdate material has been prepared using chemical precipitation method by means of doping silver ion and sodium fluorescein. This hybrid material exhibits extremely rare spindle morphology in polyoxometalate based materials. Control experiments are carried out to explore the impact factors of this peculiar shape in self-assembly process. Interestingly, the microspindle exhibits a dual-emission spectrum with the peaks centered at 467 and 512 nm, corresponding to the phosphomolybdate and sodium fluorescein related photoluminescence, respectively. Therefore, the successful preparations in this work not only enrich the structural diversity, but also provide us with an enlightening synthetic strategy for the functionalization of polyoxometalate based materials.

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Acknowledgements

This work was supported by the NSFC-Henan Joint Fund of China (U1504201), the Basic and Frontier Technology Research Plan of Henan Province (152300410192), 2017 Henan Postdoctoral Science Foundation. The authors gratefully acknowledge Qiangsheng Wang for the ESI–MS characterization and Chaofeng He from shiyanjia lab for the test of XPS, TEM and TG–DTA tests (www.shiyanjia.com).

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Correspondence to Guan Wang.

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Meng, R., He, X., Chen, J. et al. Silver and Sodium Fluorescein Co-doped Phosphomolybdate Microspindle: Synthesis and Spectroscopic Properties. J Clust Sci 30, 141–149 (2019). https://doi.org/10.1007/s10876-018-1470-7

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