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Cation–π Interaction of the Univalent Silver Cation with [2.2.2]Paracyclophane in the Gas Phase and in the Solid State: Experimental and Theoretical Study

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Abstract

Employing electrospray ionization mass spectrometry, it was proven experimentally that the [2.2.2]paracyclophane–Ag+ complex (i.e., [Ag(C24H24)]+) exists in the gas phase. Further, applying quantum chemical DFT calculations, the most probable structure of this cationic complex [Ag(C24H24)]+ was derived. Finally, in the solid state, the complex [2.2.2]paracyclophane–silver triflate–monohydrate (i.e., C24H24–AgCF3SO3–H2O), crystallizing in the monoclinic system with the centrosymmetric space group P21/c, was prepared and analysed by X-ray crystallography.

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Acknowledgements

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 entitled “Environmental Aspects of Sustainable Development of Society,” as well as by the Czech Ministry of Education, Youth, and Sports (Project MSMT No.:20/2015).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Kamýcká 129, 165 21, Prague 6-Suchdol, Czech Republic

    Blanka Klepetářová, Emanuel Makrlík & Magdalena Kvíčalová

  2. University of Chemistry and Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    David Sýkora, Stanislav Böhm & Petr Vaňura

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  1. Blanka Klepetářová
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  2. Emanuel Makrlík
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Klepetářová, B., Makrlík, E., Sýkora, D. et al. Cation–π Interaction of the Univalent Silver Cation with [2.2.2]Paracyclophane in the Gas Phase and in the Solid State: Experimental and Theoretical Study. J Clust Sci 30, 53–60 (2019). https://doi.org/10.1007/s10876-018-1461-8

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  • DOI: https://doi.org/10.1007/s10876-018-1461-8

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