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Photoluminescence and Magnetism Study of Blue Light Emitting the Oxygen-Bridged Open-Cubane Cobalt(II) Cluster

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Abstract

A new cubane-based cobalt(II) cluster, [Co4L4] (1), where H2L = 2-((E)-(2-hydroxyethylimino) methyl)-4-chlorophenol has been prepared using a solvothermal process and characterized by structural, optical and magnetism. The crystal structure of 1 consists of a tetranuclear Co4O4 core in an open-cubane framework. Each cobalt(II) ion is penta-coordinated in a distorted square pyramidal geometry (τCo1=Co1i = 0.030, τCo2=Co2i = 0.023). Furthermore, the photoluminescence analysis indicates that 1 has a strong blue emission which should be attributed to coordination of the metal to the ligand. The temperature dependence of the magnetic susceptibilities of 1 shows antiferromagnetic coupling (J = − 26.61 ± 0.01) between cobalt(II) ions.

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Acknowledgements

The authors are grateful to the Research Funds of Balikesir University (BAP–2017/199) for the financial support and Balikesir University, Science and Technology Application and Research Center (BUBTAM) for the use of the Photoluminescence Spectrometer. The authors are also very grateful to Prof. Dr. Andrea Caneschi (Laboratory of Molecular Magnetism, Department of Chemistry, University of Florence) for the use of SQUID magnetometer and helpful suggestions.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science and Art, Balikesir University, 10145, Balikesir, Turkey

    Elif Gungor, Mustafa Burak Coban, Hulya Kara & Yasemin Acar

  2. Center of Science and Technology Application and Research, Balikesir University, 10145, Balikesir, Turkey

    Mustafa Burak Coban

  3. Department of Physics, Faculty of Science, Mugla Sitki Kocman University, 48170, Mugla, Turkey

    Hulya Kara

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  1. Elif Gungor
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Correspondence to Elif Gungor or Hulya Kara.

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Gungor, E., Coban, M.B., Kara, H. et al. Photoluminescence and Magnetism Study of Blue Light Emitting the Oxygen-Bridged Open-Cubane Cobalt(II) Cluster. J Clust Sci 29, 967–974 (2018). https://doi.org/10.1007/s10876-018-1406-2

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