Skip to main content
SpringerLink
Log in

A New Metal–Organic Framework Constructed from Trinuclear {Cd3} Clusters as Secondary Building Units

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A novel metal–organic framework, {[H2N(CH3)2][Cd3(BTC)2(BTA)(H2O)2]·2H2O}n (1) (H3BTC = 1,3,5-benzenetricarboxylate, HBTA = 1H-Benzotriazolate), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis. Compound 1 represents a new (3,3,6)-connected structural topology constructed by trinuclear {Cd3} clusters as secondary building units. Moreover, the luminescence properties of 1 have been well investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Y. F. Zeng, X. Hu, F. C. Liu, and X. H. Bu (2009). Chem. Soc. Rev. 38, 469.

    Article  CAS  Google Scholar 

  2. Y. Cui, S. J. Lee, and W. B. Lin (2003). J. Am. Chem. Soc. 125, 6014.

    Article  CAS  Google Scholar 

  3. J. R. Li, J. Sculley, and H. C. Zhou (2012). Chem. Rev. 112, 869.

    Article  CAS  Google Scholar 

  4. Q. Chen, Z. Chang, W. C. Song, H. Song, H. B. Song, T. L. Hu, and X. H. Bu (2013). Angew. Chem. Int. Ed. 52, 11550.

    Article  CAS  Google Scholar 

  5. D. Tian, Q. Chen, Y. Li, Y. H. Zhang, Z. Chang, and X. H. Bu (2014). Angew. Chem. Int. Ed. 53, 837.

    Article  CAS  Google Scholar 

  6. L. Hou, W. J. Shi, Y. Y. Wang, Y. Guo, C. Jin, and Q. Z. Shi (2011). Chem. Commun. 47, 5464.

    Article  CAS  Google Scholar 

  7. C. Y. Sun, C. Qin, C. G. Wang, Z. M. Su, S. Wang, X. L. Wang, G. S. Yang, K. Z. Shao, Y. Q. Lan, and E. B. Wang (2011). Adv. Mater. 23, 5629.

    Article  CAS  Google Scholar 

  8. Y. Q. Chen, G. R. Li, Z. Chang, Y. K. Qu, Y. H. Zhang, and X. H. Bu (2013). Chem. Sci. 4, 3678.

    Article  CAS  Google Scholar 

  9. L. Hou, L. N. Jia, W. J. Shi, Y. Y. Wang, B. Liu, and Q. Z. Shi (2013). Dalton Trans. 42, 3653.

    Article  CAS  Google Scholar 

  10. Y. Q. Lan, H. L. Jiang, S. L. Li, and Q. Xu (2011). Adv. Mater. 23, 5015.

    Article  CAS  Google Scholar 

  11. Y. J. Cui, Y. F. Yue, G. D. Qian, and B. L. Chen (2012). Chem. Rev. 112, 1126.

    Article  CAS  Google Scholar 

  12. M. Eddaoudi, D. Moler, H. L. Li, T. M. Reineke, M. O’Keeffe, and O. M. Yaghi (2001). Acc. Chem. Res. 34, 319.

    Article  CAS  Google Scholar 

  13. N. W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, and O. M. Yaghi (2005). Acc. Chem. Res. 38, 176.

    Article  CAS  Google Scholar 

  14. M. O’keeffe, M. A. Peskov, S. J. Ramsden, and O. M. Yaghi (2008). Acc. Chem. Res. 41, 1782.

    Article  Google Scholar 

  15. D. J. Tranchemontagne, J. L. Mendoza-Cortes, M. O’Keeffe, and O. M. Yaghi (2009). Chem. Soc. Rev. 38, 1257.

    Article  CAS  Google Scholar 

  16. Y. L. Bai, J. Tao, R. B. Huang, and L. S. Zheng (2008). Angew. Chem. Int. Ed. 47, 5344.

    Article  CAS  Google Scholar 

  17. Z. Q. Jiang, G. Y. Jiang, F. Wang, Z. Zhao, and J. Zhang (2012). Chem. Commun. 48, 3653.

    Article  CAS  Google Scholar 

  18. M. Du, C. P. Li, C. S. Liu, and S. M. Fang (2013). Coord. Chem. Rev. 257, 1282.

    Article  CAS  Google Scholar 

  19. G. P. Yang, L. Hou, X. J. Luan, B. Wu, and Y. Y. Wang (2012). Chem. Soc. Rev. 41, 6992.

    Article  CAS  Google Scholar 

  20. X. L. Zhao, F. L. Liu, L. L. Zhang, D. Sun, R. M. Wang, Z. Ju, D. Q. Yuan, and D. F. Sun (2014). Chem. Eur. J. 20, 649.

    Article  CAS  Google Scholar 

  21. Z. J. Lin, J. Lü, M. C. Hong, and R. Cao (2014). Chem. Soc. Rev. 43, 5867.

    Article  CAS  Google Scholar 

  22. L. T. Du, Z. Y. Lu, K. Y. Zheng, J. Y. Wang, X. Zheng, Y. Pan, X. Z. You, and J. F. Bai (2013). J. Am. Chem. Soc. 135, 562.

    Article  CAS  Google Scholar 

  23. S. S. Chen, M. Chen, S. Takamizawa, P. Wang, G. C. Lv, and W. Y. Sun (2011). Chem. Commun. 47, 4902.

    Article  CAS  Google Scholar 

  24. J. I. Feldblyum, M. Liu, D. W. Gidley, and A. J. Matzger (2011). J. Am. Chem. Soc. 133, 18257.

    Article  CAS  Google Scholar 

  25. S. T. Zheng, J. T. Bu, Y. F. Li, T. Wu, F. Zuo, P. Y. Feng, and X. H. Bu (2010). J. Am. Chem. Soc. 132, 17062.

    Article  CAS  Google Scholar 

  26. G. M. Sheldrick SHELXL97, Program for Crystal Structure Refinement (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  27. G. M. Sheldrick SHELXS97, Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  28. A. L. Spek PLATON, A Multipurpose Crystallographic Tool (Utrecht University, Utrecht, 2003).

    Google Scholar 

  29. V. A. Blatov TOPOS, A multipurpose Crystallochemical Analysis with the Program Package (Samara State University, Russia, 2004).

    Google Scholar 

  30. Reticular Chemistry Structure Resource (RCSR), http://rcsr.anu.edu.au/.

  31. Y. Y. Qin, J. Zhang, Z. J. Li, L. Zhang, X. Y. Cao, and Y. G. Yao (2008). Chem. Commun. 44, 2532.

    Article  Google Scholar 

  32. M. Du, X. J. Jiang, and X. J. Zhao (2006). Inorg. Chem. 45, 3998.

    Article  CAS  Google Scholar 

  33. X. L. Qi, S. Y. Liu, R. B. Lin, P. Q. Liao, J. W. Ye, Z. H. Lai, Y. Y. Guan, J. P. Zhang, and X. M. Chen (2013). Chem. Commun. 49, 6864.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the NNSF of China (21403102, 51303076 and 51172102).

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Liaocheng University, Liaocheng, 252000, People’s Republic of China

    Hui-Yan Ma, Chang-Hua Su, Jie Yin & Xin Shao

  2. School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng, 252000, People’s Republic of China

    Yun-Wu Li

Authors
  1. Hui-Yan Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chang-Hua Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jie Yin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yun-Wu Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xin Shao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yun-Wu Li or Xin Shao.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOC 710 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ma, HY., Su, CH., Yin, J. et al. A New Metal–Organic Framework Constructed from Trinuclear {Cd3} Clusters as Secondary Building Units. J Clust Sci 26, 1403–1411 (2015). https://doi.org/10.1007/s10876-014-0822-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-014-0822-1

Keywords

Search

Navigation