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Journal of Cluster Science

, Volume 25, Issue 2, pp 377–385 | Cite as

1D Chain-Like Architecture in Anderson Heteropolymolybdate {[Eu(H2O)6]2(TeMo6O24)}·6H2O: Synthesis and Characterization

  • Miao Yu
  • Bo Gao
  • Dadong Liang
Original Paper

Abstract

A new Anderson-based heteropolymolybdate {[Eu(H2O)6]2(TeMo6O24)}·6H2O (1) has been hydrothermally synthesized and characterized by elemental analyses, IR, thermal stability analysis, XRD and single crystal X-ray diffraction. Compound 1 crystallizes in the triclinic system, space group P-1, a = 9.4023(6) Å, b = 10.2530(7) Å, c = 10.6525(10) Å, α = 101.583(7)º, β = 108.024(7)º, γ = 107.150(6)º, V = 883.60(12) Å3, Z = 1, R1 = 0.0338, wR2 = 0.0849. Compound 1 exhibits 1D chain-like structure formed by the alternative connection between Anderson type polyoxoanions [TeMo6O24]6− and Eu3+ along a-axis. Compound 1 displays good fluorescent emission of the Eu3+ ion at room temperature.

Keywords

Polyoxometalate Anderson-type anion Hydrothermal synthesis Lanthanide 

Notes

Acknowledgments

This work was supported by the Technology Department of Jilin Province of China (Grant no. 2009324) and the Analysis and Testing Foundation of Northeast Normal University.

Supplementary material

10876_2013_616_MOESM1_ESM.pdf (164 kb)
Supplementary material (PDF 163 kb)

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  1. 1.Department of FoundationJilin Business and Technology CollegeChangchunPeople’s Republic of China
  2. 2.Department of Resources and EnvironmentJilin Agriculture UniversityChangchunPeople’s Republic of China

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