Journal of Cluster Science

, Volume 24, Issue 4, pp 1021–1030 | Cite as

Two Bisupporting Keggin-Type POM-Based Hybrids Decorated by [Zn(phen)2]2+ Fragments

  • Kundawlet Alimaje
  • Xiang Wang
  • Zhe-Yu Zhang
  • Jun Peng
  • Zhen-Yu Shi
  • Xia Yu
  • Zi-Xing Ren
Original Paper


Two bisupporting Keggin-type polyoxoanion-based hybrids decorated by [Zn(phen)2]2+ complexes, [Zn(phen)2]2(PW 11 VI WVO40) (1) and K[Zn(phen)2(H2O)]2(OH) (SiW12O40)·H2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized, and characterized by elemental analysis, IR spectra, UV–Vis spectrum, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis, and single-crystal X-ray diffraction. The structural analyses reveal that compound 1 consists of a 0D bisupporting Keggin-type heteropoly blue cluster obtained by using reductant glucose, which is grafted by two [Zn(phen)2]2+ fragments; compound 2 presents a 1D infinite chain, which is constructed from bisupporting [SiW12O40]4− polyoxoanions decorated by [Zn(phen)2(H2O)]2+ fragments and K+ ions. Additionally, the electrochemical behaviors of two compounds were studied.


Polyoxometalates  Bisupporting  [Zn(phen)2]2+ fragments  Hydrothermal synthesis 



This work is financially supported by the National Natural Science Foundation of China (21071029).

Supplementary material

10876_2013_594_MOESM1_ESM.doc (544 kb)
Supplementary material 1 (DOC 544 kb)


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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Kundawlet Alimaje
    • 1
    • 2
  • Xiang Wang
    • 1
  • Zhe-Yu Zhang
    • 1
  • Jun Peng
    • 1
  • Zhen-Yu Shi
    • 1
  • Xia Yu
    • 1
  • Zi-Xing Ren
    • 1
  1. 1.Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of ChemistryNortheast Normal UniversityChangchunPeople’s Republic of China
  2. 2.School of Chemistry and BioscienceYili Normal UniversityYiningPeople’s Republic of China

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