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Two Bisupporting Keggin-Type POM-Based Hybrids Decorated by [Zn(phen)2]2+ Fragments

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Abstract

Two bisupporting Keggin-type polyoxoanion-based hybrids decorated by [Zn(phen)2]2+ complexes, [Zn(phen)2]2(PW VI11 WVO40) (1) and K[Zn(phen)2(H2O)]2(OH) (SiW12O40)·H2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized, and characterized by elemental analysis, IR spectra, UV–Vis spectrum, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis, and single-crystal X-ray diffraction. The structural analyses reveal that compound 1 consists of a 0D bisupporting Keggin-type heteropoly blue cluster obtained by using reductant glucose, which is grafted by two [Zn(phen)2]2+ fragments; compound 2 presents a 1D infinite chain, which is constructed from bisupporting [SiW12O40]4− polyoxoanions decorated by [Zn(phen)2(H2O)]2+ fragments and K+ ions. Additionally, the electrochemical behaviors of two compounds were studied.

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References

  1. D. L. Long, R. Tsunashima, and L. Cronin (2010). Angew. Chem. Int. Ed. 49, 1736.

    Article  CAS  Google Scholar 

  2. H. N. Miras, J. Yan, D. L. Long, and L. Cronin (2012). Chem. Soc. Rev. 41, 7403.

    Article  CAS  Google Scholar 

  3. C. Ritchie, E. M. Burkholder, D. L. Long, D. Adam, P. Kogerler, and L. Cronin (2007). Chem. Commun. 0, 468.

    Article  CAS  Google Scholar 

  4. M. T. Pope, Heteropoly and Isopoly Oxometalates, (Springer, Berlin, 1983).

  5. M. T. Pope and A. Müller (1991). Angew. Chem. Int. Ed. 30, 34.

    Article  Google Scholar 

  6. V. Soghmonian, Q. Chem, R. C. Haushalter, and J. Zubieta (1993). Science. 259, 1596.

    Article  Google Scholar 

  7. K. Fukaya and T. Yamase (2003). Angew. Chem. Int. Ed. 42, 654.

    Article  CAS  Google Scholar 

  8. X. M. Zhang, M. L. Tong, and X. M. Chen (2000). Chem. Commun. 18, 1817.

    Article  Google Scholar 

  9. L. H. Bi, R. D. Huang, J. Peng, E. B. Wang, Y. H. Wang and C. W. Hu (2001). J. Chem. Soc. Dalton Trans. 30, 121.

    Google Scholar 

  10. Q. Zhai, X. Wu, S. Chen, L. Chen, and C. Lu (2007). Inorg. Chim. Acta. 360, 3484.

    Article  CAS  Google Scholar 

  11. H. H. Yu, X. B. Cui, J. Lu, Y. H. Sun, W. J. Duan, J. W. Cui, Z. H. Yi, J. Q. Xu, and T. G. Wang (2008). J. Mol. Struct. 879, 156.

    Article  CAS  Google Scholar 

  12. Y. Wang, D. R. Xiao, E. B. Wang, L. L. Fan, and J. Liu (2007). Transit. Metal Chem. 32, 950.

    Article  CAS  Google Scholar 

  13. Y. Shen, J. Peng, H. Zhang, C. Chen, F. Zhang, and A. M. Bond (2011). J. Mater. Chem. 21, 6995.

    Article  CAS  Google Scholar 

  14. Z. G. Han, H. Y. Ma, J. Peng, Y. H. Chen, E. B. Wang, and N. H. Hu (2004). Inorg. Chem. Commun. 7, 182.

    Article  CAS  Google Scholar 

  15. G. Y. Luan, Y. G. Li, S. T. Wang, E. B. Wang, Z. B. Han, C. W. Hu, N. H. Hu, and H. Q. Jia (2003). Dalton. Trans. 32, 233.

    Google Scholar 

  16. S. Reinoso, P. Vitoria, L. Lezama, A. Luque, and J. M. Gutiérrez-Zorrilla (2003). Inorg. Chem. 42, 3709.

    Article  CAS  Google Scholar 

  17. W. Huang, L. Todaro, G. P. A. Yap, R. Beer, L. C. Francesconi, and T. Polenova (2004). J. Am. Chem. Soc. 126, 11564.

    Article  CAS  Google Scholar 

  18. Y. Ishii, Y. Takenaka, and K. Konishi (2004). Angew. Chem. Int. Ed. 43, 2702.

    Article  CAS  Google Scholar 

  19. U. Kortz, S. Nellutla, A. C. Stowe, N. S. Dalal, J. van Tol, and B. S. Bassil (2003). Inorg. Chem. 43, 144.

    Article  Google Scholar 

  20. U. Kortz, S. Nellutla, A. C. Stowe, N. S. Dalal, U. Rauwald, W. Danquah, and D. Ravot (2004). Inorg. Chem. 43, 2308.

    Article  CAS  Google Scholar 

  21. L. H. Bi, U. Kortz, S. Nellutla, A. C. Stowe, J. van Tol, N. S. Dalal, B. Keita, and L. Nadjo (2005). Inorg. Chem. 44, 896.

    Article  CAS  Google Scholar 

  22. S. Chang, C. Qin, E. B. Wang, Y. G. Li, and X. L. Wang (2006). Inorg. Chem. Commun. 9, 727.

    Article  CAS  Google Scholar 

  23. C. M. Wang, S. T. Zheng, and G. Y. Yang (2009). J. Clust. Sci. 20, 489.

    Article  CAS  Google Scholar 

  24. Y. Xu, J. Q. Xu, K. L. Zhang, Y. Zhang, and X. Z. You (2000). Chem. Commun. 36, 153.

  25. M. Yuan, Y. G. Li, E. B. Wang, C. G. Tian, L. Wang, C. W. Hu, N. H. Hu, and H. Q. Jia (2003). Inorg. Chem. 42, 3670.

    Article  CAS  Google Scholar 

  26. J. W. Cui, X. B. Cui, H. H. Yu, J. Q. Xu, Z. H. Yi, and W. J. Duan (2008). Inorg. Chim. Acta. 361, 2641.

    Article  CAS  Google Scholar 

  27. L. M. Dai, Y. Ma, E. B. Wang, Y. Lu, X. X. Xu, and X. L. Bai (2006). Transit. Metal Chem. 31, 340.

    Article  CAS  Google Scholar 

  28. Y. Y. Zhu, L. Shen, C. X. Qin, and X. Wei (2007). Chin. J. Inorg. Chem. 23, 310.

    Google Scholar 

  29. L. M. Dai, W. S. You, E. B. Wang, X. L. Wang, X. M. Han, W. W. Li, and Y. Fang (2009). Inorg. Chim. Acta. 362, 4967.

    Article  CAS  Google Scholar 

  30. A. Tézé and G. Hervé (1977). J. Inorg. Nucl. Chem. 39, 999.

    Article  Google Scholar 

  31. G. M. Sheldrick, SHELXS-97, Program for solution of crystal structures (University of Göottingen, Germany, 1997).

  32. G. M. Sheldrick, SHELXS-97, Program for refinement of crystal structures (University of Göottingen, Germany, 1997).

  33. Y.-K. Lu, X.-B. Cui, Y. Chen, J.-N. Xu, Q.-B. Zhang, Y.-B. Liu, J.-Q. Xu, and T.-G. Wang (2009). J. Solid State Chem. 182, 2111.

    Article  CAS  Google Scholar 

  34. N. E. Brese and M. O’Keeffe (1991). Acta Crystallogr. B. 47, 192.

    Article  Google Scholar 

  35. C. Rocchiccioli-Deltcheff, M. Fournier, R. Franck, and R. Thouvenot (1983). Inorg. Chem. 22, 207.

    Article  CAS  Google Scholar 

  36. C. L. Meng, P. P. Zhang, J. Peng, X. Wang, Y. Shen, M. G. Liu, D. D. Wang, and K. Alimaje (2012). J. Clust. Sci. 23, 567.

    Article  CAS  Google Scholar 

  37. X. Wang, J. Peng, M. G. Liu, D. D. Wang, C. L. Meng, Y. Li, and Z. Y. Shi (2012). CrystEngComm. 14, 3220.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is financially supported by the National Natural Science Foundation of China (21071029).

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People’s Republic of China

    Kundawlet Alimaje, Xiang Wang, Zhe-Yu Zhang, Jun Peng, Zhen-Yu Shi, Xia Yu & Zi-Xing Ren

  2. School of Chemistry and Bioscience, Yili Normal University, Yining, 835000, Xinjiang, People’s Republic of China

    Kundawlet Alimaje

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  1. Kundawlet Alimaje
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  2. Xiang Wang
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  7. Zi-Xing Ren
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Correspondence to Jun Peng.

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Alimaje, K., Wang, X., Zhang, ZY. et al. Two Bisupporting Keggin-Type POM-Based Hybrids Decorated by [Zn(phen)2]2+ Fragments. J Clust Sci 24, 1021–1030 (2013). https://doi.org/10.1007/s10876-013-0594-z

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  • DOI: https://doi.org/10.1007/s10876-013-0594-z

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