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Journal of Cluster Science

, Volume 23, Issue 2, pp 411–420 | Cite as

Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

  • Wen-Hua Zhang
  • Yong-Hui Wang
  • Ya-Wei Li
  • Guang Yang
Original Paper

Abstract

The Ag(I) and Cu(I) complexes of 4-amino-3,5-dipentyl-4H-1,2,4-triazole (4-NH2-3,5-(C5H11)2tz) and 3,5-dipentyl-1H-1,2,4-triazole (3,5-(C5H11)2tzH) have been synthesized and characterized. X-Ray analysis shows that {Ag4[4-NH2-3,5-(C5H11)2tz]6}(BF4)4 is a tetranuclear complex featuring an Ag4tz6 cluster; {Ag[3,5-(C5H11)2tz]}n exhibits a 3D structure of lvt-a topology; and {Cu2[3,5-(C5H11)2tz]Br}n is a Cu4Br4-cluster based 3D complex with the dia topology.

Keywords

Silver Copper Triazole Synthesis Structure Cu4Br4 cluster 

Notes

Acknowledgments

This work has been supported by the NSF of China (No. 21071126 and No. J0830412) and a research grant for undergraduate students of Zhengzhou University.

Supplementary material

10876_2012_445_MOESM1_ESM.doc (1.1 mb)
Supplementary material 1 (DOC 1163 kb)

References

  1. 1.
    W. Ouellette, S. Jones, and J. Zubieta (2011). CrystEngComm 13, 4457.Google Scholar
  2. 2.
    G. Aromí, L. A. Barrios, O. Roubeau, and P. Gamez (2011). Coord. Chem. Rev. 255, 485.CrossRefGoogle Scholar
  3. 3.
    J. G. Haasnoot (2000). Coord. Chem. Rev. 200–202, 131.CrossRefGoogle Scholar
  4. 4.
    G. Yang, Y.-L. Wang, J.-P. Li, Y. Zhu, S.-M. Wang, H.-W. Hou, Y.-T. Fan, and S. W. Ng (2007). Eur. J. Inorg. Chem. 714.Google Scholar
  5. 5.
    G. Yang, Y.-L. Wang, L.-L. Liu, and S. W. Ng (2009). Transition Met. Chem. 34, 751.CrossRefGoogle Scholar
  6. 6.
    G. Yang, P.-P. Zhang, L.-L. Liu, J.-K. Kou, H.-W. Hou, and Y.-T. Fan (2009). CrystEngComm 11, 663.Google Scholar
  7. 7.
    J.-P. Zhang, Y.-Y. Lin, X.-C. Huang, and X.-M. Chen (2005). J. Am. Chem. Soc. 127, 5495.CrossRefGoogle Scholar
  8. 8.
    J.-P. Zhang and X.-M. Chen (2006). Chem. Commun. 16, 1689.CrossRefGoogle Scholar
  9. 9.
    J.-P. Zhang, X.-L. Qi, Z.-J. Liu, A.-X. Zhu, Y. Chen, J. Wang, and X.-M. Chen (2011). Cryst. Growth Des. 11, 796.CrossRefGoogle Scholar
  10. 10.
    J.-P. Zhang, Y.-B. Zhang, J.-B. Lin, and X.-M. Chen (2011). Chem. Rev. doi 10.1021/cr200139g.
  11. 11.
    Y.-H. Wang, H. Xu, G. Yang, and H.-W. Hou (2011). J. Chem. Crystallogr. 41, 434.CrossRefGoogle Scholar
  12. 12.
    Reitz, D. B. (1991). PCT Int. Appl. WO 9117148 A1 19911114.Google Scholar
  13. 13.
    R. M. Herbst and J. A. Garrison (1953). J. Org. Chem. 18, 872.CrossRefGoogle Scholar
  14. 14.
    F. Bentiss, M. Lagrenée, H. Vezin, M. Bouanis, and B. Mernari (2002). J. Heterocyclic Chem. 39, 93.CrossRefGoogle Scholar
  15. 15.
    W. Ouellette, A. V. Prosvirin, V. Chieffo, K. R. Dunbar, B. Hudson, and J. Zubieta (2006). Inorg. Chem. 45, 9346.CrossRefGoogle Scholar
  16. 16.
    W. J. Geary (1971). Coord. Chem. Rev. 7, 81.CrossRefGoogle Scholar
  17. 17.
    M. O’Keeffe, M. A. Peskov, S. J. Ramsden, and O. M. Yaghi (2008). Acc. Chem. Res. 41, 1782.CrossRefGoogle Scholar
  18. 18.
    O. Delgado-Friedrichs, M. O’Keeffe, and O. M. Yaghi (2007). Phys. Chem. Chem. Phys. 9, 1035.CrossRefGoogle Scholar
  19. 19.
    O. Delgado-Friedrichs, M. D. Foster, M. O’Keeffe, D. M. Proserpio, M. M. J. Treacy, and O. M. Yaghi (2005). J. Solid State Chem. 178, 2533.CrossRefGoogle Scholar
  20. 20.
    More information can be found at http://rcsr.anu.edu.au and http://gavrog.sourceforge.net/.
  21. 21.
    P. Pyykkö (1997). Chem. Rev. 97, 597.CrossRefGoogle Scholar
  22. 22.
    R. Peng, M. Li, and D. Li (2011). Coord. Chem. Rev. 254, 1.CrossRefGoogle Scholar
  23. 23.
    G. M. Sheldrick (2008). Acta Crystallogr. A64, 112.Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Wen-Hua Zhang
    • 1
  • Yong-Hui Wang
    • 2
  • Ya-Wei Li
    • 1
  • Guang Yang
    • 1
  1. 1.Department of ChemistryZhengzhou UniversityZhengzhouChina
  2. 2.The Centre of Supervision and Inspection of Quality and Technique at SanmenxiaSanmenxiaChina

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