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Journal of Cluster Science

, Volume 22, Issue 1, pp 73–85 | Cite as

Two New Extended Frameworks Constructed from the Sandwiching Polytungstoantimonate Clusters

  • Bao-Wang Chen
  • Wei-Lin Chen
  • Yang-Guang Li
  • En-Bo Wang
Original Paper

Abstract

Two new tungstoantimonates Na4H2[{Co(H2O)3}2Co(H2O)2W(H2O)2 (B-β-SbW9O33)2]·33H2O (1) and H4[Mn2(H2O)8Mn3.5(H2O)7W0.5(H2O)(B-β-SbW9O33)2]·20H2O (2) have been obtained by the routine synthetic reactions in the aqueous solutions and characterized by elemental analysis, IR, TG analysis. Compound 1 is built from the sandwich-type polyoxoanions [{Co(H2O)3}2Co(H2O)2W(H2O)2(B-β-SbW9O33)2]6−, linked by Na+ cations to construct a 1-D chain-like structure. Compound 2 shows an interesting 2-D structure built up from sandwich-type anions [Mn3.5(H2O)7W0.5(H2O)(B-β-SbW9O33)2]8− linked by additional Mn2+ ions, which represents the first example of pure inorganic 2-D structure based on the Mn-containing sandwich-type polytungstoantimonate clusters. The electrochemical and photochemical catalysis activities of compounds 1 and 2 have also been investigated.

Keywords

Polyoxometalates Sandwich-type structure Extended structure Photochemical catalysis 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20701005), the Postdoctoral Station Foundation of Ministry of Education (No. 20060200002), Science and Technology Creation Foundation of Northeast Normal University (NENU-STC07009) and the Testing Foundation of Northeast Normal University.

Supplementary material

10876_2011_360_MOESM1_ESM.doc (2.2 mb)
Supplementary material 1 (DOC 2300 kb)

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Bao-Wang Chen
    • 1
  • Wei-Lin Chen
    • 1
  • Yang-Guang Li
    • 1
  • En-Bo Wang
    • 1
  1. 1.Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of ChemistryNortheast Normal UniversityChangchunPeople’s Republic of China

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