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Two New Extended Frameworks Constructed from the Sandwiching Polytungstoantimonate Clusters

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Abstract

Two new tungstoantimonates Na4H2[{Co(H2O)3}2Co(H2O)2W(H2O)2 (B-β-SbW9O33)2]·33H2O (1) and H4[Mn2(H2O)8Mn3.5(H2O)7W0.5(H2O)(B-β-SbW9O33)2]·20H2O (2) have been obtained by the routine synthetic reactions in the aqueous solutions and characterized by elemental analysis, IR, TG analysis. Compound 1 is built from the sandwich-type polyoxoanions [{Co(H2O)3}2Co(H2O)2W(H2O)2(B-β-SbW9O33)2]6−, linked by Na+ cations to construct a 1-D chain-like structure. Compound 2 shows an interesting 2-D structure built up from sandwich-type anions [Mn3.5(H2O)7W0.5(H2O)(B-β-SbW9O33)2]8− linked by additional Mn2+ ions, which represents the first example of pure inorganic 2-D structure based on the Mn-containing sandwich-type polytungstoantimonate clusters. The electrochemical and photochemical catalysis activities of compounds 1 and 2 have also been investigated.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20701005), the Postdoctoral Station Foundation of Ministry of Education (No. 20060200002), Science and Technology Creation Foundation of Northeast Normal University (NENU-STC07009) and the Testing Foundation of Northeast Normal University.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Ren Min Street, No. 5268, Changchun, Jilin, 130024, People’s Republic of China

    Bao-Wang Chen, Wei-Lin Chen, Yang-Guang Li & En-Bo Wang

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  1. Bao-Wang Chen
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  2. Wei-Lin Chen
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Correspondence to En-Bo Wang.

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Chen, BW., Chen, WL., Li, YG. et al. Two New Extended Frameworks Constructed from the Sandwiching Polytungstoantimonate Clusters. J Clust Sci 22, 73–85 (2011). https://doi.org/10.1007/s10876-011-0360-z

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