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Journal of Cluster Science

, Volume 21, Issue 2, pp 147–154 | Cite as

A New Molybdophosphate Constructed From {Mo 2 V O4(H2O)6}2+ and 1-Hydroxyethylidenediphosphonate

  • Hua-Qiao Tan
  • Wei-Lin Chen
  • Ding Liu
  • En-Bo Wang
Original Paper

Abstract

A new molybdophosphate (NH4)8{Mo 2 V O4[(Mo 2 VI O6)CH3C(O)(PO3)2]2}·14H2O (1), has been synthesized by the reaction of {Mo 2 V O4(H2O)6}2+ fragments with 1-hydroxyethylidenediphosphonate (hedp HOC(CH3)(PO3H2)2), and it is characterized by 31P NMR, IR, UV, element analysis, TG and single-crystal X-ray analysis. The structure analysis reveals that the polyoxoanion can be described as two {(Mo 2 VI O6)(CH3C(O)(PO3)2} units connected by a {Mo 2 V O4}2+ moiety. In the structure, the six Mo atoms are arranged into a new “W-shaped” structure, which represents a new kind of molybdophosphate.

Keywords

Polymolybdate 1-Hydroxyethylidenediphosphonate Crystal structure 31P NMR 

Notes

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 20701005/20701006); the Postdoctoral station Foundation of Ministry of Education (No. 20060200002); the Testing Foundation of Northeast Normal University (NENU); Science and Technology Creation Foundation of NENU (NENU-STC07009) and the Program for Changjiang Scholars and Innovative Research Team in University.

Supplementary material

10876_2010_313_MOESM1_ESM.doc (2.8 mb)
Supplementary material 1 (DOC 2828 kb)

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • Hua-Qiao Tan
    • 1
  • Wei-Lin Chen
    • 1
  • Ding Liu
    • 1
  • En-Bo Wang
    • 1
  1. 1.Key Laboratory of Polyoxometalates Science of Ministry of Education, Department of ChemistryNortheast Normal UniversityChangchunPeople’s Republic of China

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