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Journal of Cluster Science

, Volume 20, Issue 1, pp 165–176 | Cite as

Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations

  • Konstantin A. Brylev
  • Nikolay G. Naumov
  • Alexander V. Virovets
  • Sung-Jin Kim
  • Vladimir E. Fedorov
Original Paper

Abstract

Three novel coordination polymers K5[MnMo6Se8(CN)6] · 8H2O (1), (Me4N)4[{Mn(H2O)2}1.5Mo6Se8(CN)6] · 4H2O (2), and K3[{Mn2(H2O)4}Mo6Se8(CN)6] · 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen–N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] · 8H2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN)6]7− cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

Keywords

Molybdenum Cluster Compounds Cyanides Crystal structure 

Notes

Acknowledgements

This research was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) (Grant : R11-2005-008-03001-0). N. G. Naumov gratefully thanks KOSEF Brain Pool for financial support. Also we thank Prof. Vladislav A. Blatov (Samara State University) for the opportunity to use TOPOS4.0 Professional software package.

References

  1. 1.
    N. G. Naumov, A. V. Virovets, M. N. Sokolov, S. B. Artemkina, and V. E. Fedorov (1998). Angew. Chem. Int. Ed. 37, 1943.CrossRefGoogle Scholar
  2. 2.
    L. G. Beauvais, M. P. Shores, and J. R. Long (1998). Chem. Mater. 10, 3783.CrossRefGoogle Scholar
  3. 3.
    N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov (1999). Solid State Sci. 1, 473.CrossRefGoogle Scholar
  4. 4.
    N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov (2000). J. Solid State Chem. 153, 195.CrossRefGoogle Scholar
  5. 5.
    L. G. Beauvais, M. P. Shores, and J. R. Long (2000). J. Am. Chem. Soc. 122, 2763.CrossRefGoogle Scholar
  6. 6.
    M. V. Bennett, M. P. Shores, L. G. Beauvais, and J. R. Long (2000). J. Am. Chem. Soc. 122, 6664.CrossRefGoogle Scholar
  7. 7.
    N. G. Naumov, D. V. Soldatov, J. A. Ripmeester, S. B. Artemkina, and V. E. Fedorov (2001). Chem. Commun., 571.Google Scholar
  8. 8.
    M. V. Bennett, L. G. Beauvais, M. P. Shores, and J. R. Long (2001). J. Am. Chem. Soc. 123, 8022.CrossRefGoogle Scholar
  9. 9.
    V. E. Fedorov, N. G. Naumov, Y. V. Mironov, A. V. Virovets, S. B. Artemkina, K. A. Brylev, S. S. Yarovoi, O. A. Efremova, and U. H. Peak (2002). J. Struct. Chem. (Engl. Trans.). 43, 669.Google Scholar
  10. 10.
    K. A. Brylev, Y. V. Mironov, N. G. Naumov, V. E. Fedorov, and J. A. Ibers (2004). Inorg. Chem. 43, 4833.CrossRefGoogle Scholar
  11. 11.
    Y. V. Mironov, N. G. Naumov, K. A. Brylev, O. A. Efremova, V. E. Fedorov, and K. Hegetschweiler (2004). Angew. Chem. Int. Ed. 43, 1297.CrossRefGoogle Scholar
  12. 12.
    K. A. Brylev, G. Pilet, N. G. Naumov, A. Perrin, and V. E. Fedorov (2005). Eur. J. Inorg. Chem., 461.Google Scholar
  13. 13.
    M. S. Tarasenko, A. Y. Ledneva, N. G. Naumov, D. Y. Naumov, and V. E. Fedorov (2005). J. Clust. Sci. 16, 353.CrossRefGoogle Scholar
  14. 14.
    S. Kim, Y. Kim, Y. Kal, and S. J. Kim (2007). Inorg. Chim. Acta. 360, 1870.CrossRefGoogle Scholar
  15. 15.
    S. Jin and F. J. DiSalvo (2002). Chem. Mater. 14, 3448.CrossRefGoogle Scholar
  16. 16.
    S. Cordier, N. G. Naumov, D. Salloum, F. Paul, and C. Perrin (2004). Inorg. Chem. 43, 219.CrossRefGoogle Scholar
  17. 17.
    N. G. Naumov, S. Cordier, and C. Perrin (2005). Solid State Sci. 7, 1517.CrossRefGoogle Scholar
  18. 18.
    J. J. Zhang, H. J. Zhou, and A. Lachgar (2007). Angew. Chem. Int. Ed. 46, 4995.CrossRefGoogle Scholar
  19. 19.
    H. J. Zhou, and A. Lachgar (2007). Eur. J. Inorg. Chem., 1053.Google Scholar
  20. 20.
    Y. V. Mironov, A. V. Virovets, N. G. Naumov, V. N. Ikorskii, and V. E. Fedorov (2000). Chem. Eur. J. 6, 1361.CrossRefGoogle Scholar
  21. 21.
    C. Magliocchi, X. B. Xie, and T. Hughbanks (2000). Inorg. Chem. 39, 5000.CrossRefGoogle Scholar
  22. 22.
    V. T. Kasumov, A. A. Medzhidov, I. A. Golubeva, T. P. Vishnyakova, O. V. Shubina, and R. Z. Rzaev (1991). Koord. khim. 17, 1698.Google Scholar
  23. 23.
    J. de Meulenaer and H. Tompa (1965). Acta Crystallogr. Sect. A: Found. Crystallogr. 19, 1014.Google Scholar
  24. 24.
    G. M. Sheldrick SHELX-97. Release 97–2 (Göttingen University, Germany, 1998).Google Scholar
  25. 25.
    P. van der Sluis and A. L. Spek (1990). Acta Crystallogr. Sect. A: Found. Crystallogr. 46, 194.CrossRefGoogle Scholar
  26. 26.
    A. L. Spek (2003). J. Appl. Cryst. 36, 7.CrossRefGoogle Scholar
  27. 27.
    V. A. Blatov (2006). CompComm. Newsletter. 7, 4.Google Scholar
  28. 28.
    Y. Kim, S. M. Park, W. Nam, and S. J. Kim (2001). Chem. Commun., 1470.Google Scholar
  29. 29.
    Y. Kim, S. M. Park, and S. J. Kim (2002). Inorg. Chem. Commun. 5, 592.CrossRefGoogle Scholar
  30. 30.
    B. Yan, H. Zhou, and A. Lachgar (2003). Inorg. Chem. 42, 8818.CrossRefGoogle Scholar
  31. 31.
    O. D. Friedrichs, M. O. O’Keeffe, and O. M. Yaghi (2003). Acta Crystallogr. Sect. A: Found. Crystallogr. 59, 515.CrossRefGoogle Scholar
  32. 32.
    M. P. Shores, L. G. Beauvais, and J. R. Long (1999). J. Am. Chem. Soc. 121, 775.CrossRefGoogle Scholar
  33. 33.
    N. G. Naumov, A. V. Virovets, S. B. Artemkina, D. Y. Naumov, J. A. K. Howard, and V. E. Fedorov (2004). J. Solid State Chem. 177, 1896.CrossRefGoogle Scholar
  34. 34.
    M. P. Shores, L. G. Beauvais, and J. R. Long (1999). Inorg. Chem. 38, 1648.CrossRefGoogle Scholar
  35. 35.
    N. G. Naumov, M. N. Sokolov, H. Imoto, T. Saito, and V. E. Fedorov (2001). J. Struct. Chem. (Engl. Trans.). 42, 326.Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Konstantin A. Brylev
    • 1
  • Nikolay G. Naumov
    • 1
  • Alexander V. Virovets
    • 1
  • Sung-Jin Kim
    • 2
  • Vladimir E. Fedorov
    • 1
  1. 1.Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussia
  2. 2.Ewha Womans UniversitySeoulRepublic of Korea

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