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Journal of Cluster Science

, Volume 18, Issue 2, pp 406–413 | Cite as

A Novel 3D Platinum–Thallium Coordination Polymer having Strong Metal–Metal Interactions

  • Guoqiang Wu
  • Daqi Wang
Article

Abstract

A new three-dimensional platinum(II)–thallium(I) coordination polymer [{Pt(pda)(NHCOtBu)2}4Tl4][Pt(CN)4]2·2H 2 O (pda = 1,2-propyldiamine) has been prepared from the direct reaction of [Tl2Pt(CN)4] and [Pt(pda)(NHCOtBu)2] in water, and its structure was characterized by X-ray diffraction analysis. The compound crystallizes in monoclinic, space group Pn, a = 11.567(2) Å, b = 11.570(2) Å, c = 37.677(8)Å, β = 94.64(3)°, V = 5025.8(17) Å3, Z = 2, R1 = 0.0679 and wR2 = 0.1574 [I >  2σ (I)], Goodness-of-fit on F 2 = 1.055. The compound exhibits a novel 3D network structure consisting of [Pt(CN)4]2− connected 1D infinite Pt–Tl–Pt–Tl chains via strong Pt–Tl bonds.

Keywords

Platinum thallium coordination polymer metal–metal interaction 

Notes

Acknowledgements

G. W. thanks Zhejiang Provincial Natural Science Foundation for the financial support of this work.

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  1. 1.Department of Chemical EngineeringWest Branch of Zhejiang University of TechnologyQuzhouChina
  2. 2.Department of ChemistryLiaocheng UniversityLiaochengChina

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