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Journal of Atmospheric Chemistry

, Volume 75, Issue 1, pp 1–16 | Cite as

Atmospheric chemistry of hydrogen fluoride

  • Meng-Dawn Cheng
Article
  • 387 Downloads

Abstract

Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence.

Keywords

HF Hazard Dispersion Transport 

Notes

Acknowledgements

The author acknowledges the assistance of ORNL RSIC for making the HGSYSTEM and HGSYSTEM/UF6 packages available. The reviews of the draft manuscript by Paula Cable-Dunlap and Erik Kabela, and two anonymous reviewers are greatly appreciated. Oak Ridge National Laboratory is managed by UT-BATTELLE, LLC for the U.S. DEPARTMENT OF ENERGY under contract DE-AC05-00OR22725.

References

  1. Agency for Toxic Substances and Disease Registry (ATSDR) (1993) Toxicological Profile for Fluorides, Hydrogen Fluoride and Fluorine. U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA.Google Scholar
  2. Aiuppa, A., Franco, A., von Glasow, R., Allen, A.G., D’Alessandro, W., Mather, T.A., Pyle, D.M., Valenza, M.: The tropospheric processing of acidic gases and hydrogen Sulphide in volcanic gas plumes as inferred from field and model investigations. Atmos. Chem. Phys. 7, 1441–1450 (2007)CrossRefGoogle Scholar
  3. Allen, A.G., Oppenheimer, C., Ferm, M., Baxter, P.J., Horrocks, L.A., Galle, B., McGonigle, A.J.S., Duffell, H.J.: Primary sulfate aerosol and associated emissions from Masaya volcano, Nicaragua. J. Geophys. Res. 107(D23), (2002)Google Scholar
  4. Amoore, J.E., Hautala, E.: Odor as an aid to chemical safety: odor thresholds compared with threshold limit values and volatilities for 214 industrial Chemicals in air and Water Dilution. J. Appl. Toxicol. 3, 272–290 (1983)CrossRefGoogle Scholar
  5. Babushok, V., Burgess, D.F.R., Linteris, G., Tsang, W., Miziolek, A.: Modeling of hydrogen fluoride formation from flame suppressants during combustion. HOTWC. 95, 239–249 (1995)Google Scholar
  6. Baverez, M. and R. De Marco Adsorption of hydrogen fluoride on certain smelter-grade Aluminas, J. Metals, January, 10–14.(1980) Google Scholar
  7. Brasseur, G.P., Orlando, J.J., Tyndall, G.S.: Atmospheric chemistry and global change. Oxford University Press, New York, NY (1999)Google Scholar
  8. Brimblecombe, P.: Air composition and chemistry. Cambridge University Press, Cambridge, UK (1996)Google Scholar
  9. Brown, A.T., Chipperfield, M.P., Boone, C., Wilson, C., Walker, K.A., Bernath, P.F.: Trends in atmospheric halogen Containing gases since 2004. J. Quant. Spectro. Rad. Transfer. 112, 2552–2566 (2011)CrossRefGoogle Scholar
  10. California Environmental Protection Agency (1997) Technical Support Document for the Determination of Noncancer Chronic Reference Exposure Levels. Google Scholar
  11. Cicerone, R.J., Stolarski, R.S., Walters, S.: Stratospheric ozone destruction by man-made Chlorofluoromethanes. Science. 185, 1165–1167 (1974)CrossRefGoogle Scholar
  12. Convair (1959) Fission Product Field Release Test-I. Report NARF-59-32T (AFSWC-TR-59-44)Google Scholar
  13. Delmelle, P., Stix, J., Baxter, P.J., Garcia-Alvarez, J., Barquero, J.: Atmospheric dispersion. Environmental Effects, and Potential Health Hazard Associated with the Low-Attitude Gas Plume of Masaya Volcano, Nicaragua, Bull Volcanol. 64, 423–434 (2002)Google Scholar
  14. Dore, C.J., Murrells, T.P., Passant, N.R., Hobson, M.M., Thistlethwaite, G., Wagner, A., Li, Y., Bush, T., King, K.R., Norris, J., Coleman, P.J., Walker, C., Stewart, R.A., Tsagatakis, I., Conolly, C., Brophy, N.C.J., Hann, M.R.: UK Emissions of Air Pollutants 1970 to 2006 (2008)Google Scholar
  15. Environment Agency (2005) A Review of the Toxicity and Environmental Behavior of Hydrogen Fluoride in Air, ISBN: 1844323579, Rio House, Waterside Drive, Aztec West, Almondsbury, Bristol, BS32 4UD.Google Scholar
  16. Fthenakis, V.M.: HGSYSTEM: a review, critique, and comparison with other models. J. Loss Prev. Process Ind. 12, 525–531 (1999)CrossRefGoogle Scholar
  17. Fthenakis, V.M., Zakkay, V.: A theoretical study of absorption of toxic gases by spraying. J. Loss Prev. Process Ind. 3, 197–206 (1990)CrossRefGoogle Scholar
  18. Goff, F., Janik, C.J., Delgado, H., Werner, C., Counce, D., Stimac, J.A., Siebe, C., Love, S.P., Williams, S.N., Fischer, T., Johnson, L.: Geochemical surveillance of magmatic volatiles at Popocatpetl volcano. Mexico. Geo. Soc. Amer. Bull. 110(6), 695–710 (1998)CrossRefGoogle Scholar
  19. Gribble, G.W. Naturally Occurring Organofluorines, Ch. 5, in the handbook of environmental chemistry, Vol. 3 part N., eds. A.H. Neilson, springer-Verlag, berlin Heidelberg.(2002) Google Scholar
  20. Hanna, S.R., Chang, J.C., Zhang, J.X.: Technical documentation of HGSYSTEM/UF6 model, report 1331. Earth Tech, Concord, MA (1994)Google Scholar
  21. Hanna, S.R., Chang, J.C., Zhang, X.J.: Modeling accidental release to the atmosphere of a dense reactive chemical (uranium hexafluoride). Atmos. Environ. 31, 901–908 (1997)CrossRefGoogle Scholar
  22. Hanna, S.R., J.C. Chang, J.X. Zhang, S.G. Bloom, W.D. Goode, Jr, D.A. Lombardi, and M.W. Yambert (1998) HGSYSTEMUF6. Model for Simulating Dispersion due to Atmospheric Release of UF6, US DOE Report Number ESTSC--001242IBMPC00Google Scholar
  23. Hanson, D.R., Ravishankara, A.R.: Heterogeneous chemistry of HBr and HF. J. Phys. Chem. 96, 9441–9446 (1992)CrossRefGoogle Scholar
  24. Havens, J.: Review of dense gas dispersion field experiments. J. Loss Prev. Process Ind. 5, 28–41 (1992)CrossRefGoogle Scholar
  25. Hu, S.-W., Wang, X.-Y., Chu, T.-W., Liu, X.-Q.: Theoretical mechanism study of UF6 hydrolysis in the gas phase (II) J. Phys. Chem. A. 113, 9243–9248 (2009)CrossRefGoogle Scholar
  26. Israel, G.W.: Deposition velocity of gaseous fluorides on alfalfa. Atmos. Environ. 8, 1329–1330 (1974)CrossRefGoogle Scholar
  27. Jarry, R.L., Davis, W.: The vapor pressure, association, and heat of vaporization of hydrogen fluoride. J. Phys. Chem. 57, 600–604 (1953)CrossRefGoogle Scholar
  28. Kanno, S., Ito, T., Omura, T.: Studies on the photochemistry of aliphatic hydrogenated hydrocarbons: formation of hydrogen fluoride and hydrogen Chloride by the photochemical reaction of dichlorodifluoromethane with nitrogen oxide in air. Chemosphere. 8, 503–508 (1977)CrossRefGoogle Scholar
  29. Kohlhepp, R., R. Ruhnke, M. P. Chipperfield, M. De Mazie’re, J. Notholt, S. Barthlott, R. L. Batchelor, R. D. Blatherwick, Th. Blumenstock, M. T. Coffey, P. Demoulin, H. Fast, W. Feng, A. Goldman, D. W. T. Griffith, K. Hamann, J. W. Hannigan, F. Hase, N. B. Jones, A. Kagawa, I. Kaiser, Y. Kasai, O. Kirner, W. Kouker, R. Lindenmaier, E. Mahieu, R. L. Mittermeier, B. Monge-Sanz, I. Morino, I. Murata, H. Nakajima, M. Palm, C. Paton-Walsh, U. Raffalski, Th. Reddmann, M. Rettinger, C. P. Rinsland, E. Rozanov, M. Schneider, C. Senten, C. Servais, B.-M. Sinnhuber, D. Smale, K. Strong, R. Sussmann, J. R. Taylor, G. Vanhaelewyn, T. Warneke, C. Whaley, M. Wiehle, and S. W. Wood (2012) Observed and simulated time evolution of HCl, ClONO2, and HF Total column abundances, Atmos. Chem. Phys., 12:3527–3557.Google Scholar
  30. Kollman, P.A., Allen, L.C.: Theory of the hydrogen bond: Ab Initio calculations of hydrogen fluoride dimer and the mixed water-hydrogen fluoride dimer. J. Chem. Phys. 52, 5085–5094 (1970)CrossRefGoogle Scholar
  31. Krupcik, J., Kristin, M., Valachovicova, M., Janiga, S.: Effect of etching with gaseous hydrogen Chloride on the quality of glass capillary columns. J. Chromatography A. 126, 147–160 (1976)CrossRefGoogle Scholar
  32. Kullman, G.J., Jones, W.G., Cornwell, R.J., Parker, J.E., J.E.: Characterization of Air Contaminants Formed by the Interaction of Lava and Sea Water. Environ. Health Persp. 102(5) (1994) http://ehpnet1.niehs.nih.gov/docs/1994/102-5/kullman.html
  33. Lines, I.G. (1995) A Review of the Manufacture, Uses, Incidents and Hazard Models for Hydrogen Fluoride, HSE Contract Research Report, No. 79/1995. ISBN 0-7176-0983-9.Google Scholar
  34. Linteris, G., Gmurczyk, G.: Parametric study of hydrogen fluoride formation in suppressed fires. HOTWC. 95, 227–238 (1995)Google Scholar
  35. Liu, S.-Y., Michael, D.W., Dykstra, C.E., Lisy, J.M.: The stabilities of hydrogen fluoride Trimer and tetramer. J. Chem. Phys. 84, 5032–5036 (1986)CrossRefGoogle Scholar
  36. Lombardi, D. A. and M.-D. Cheng Modeling Downwind Hazards After an Accidental Release of Chlorine Trifluoride, The Annual Meeting of Air and Waste Management Association Paper 9606125–5. Washington, D.C. United States. Dept. of Energy.; Oak Ridge, Tenn.: distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy (1996)Google Scholar
  37. Mankin, W.G., M.T. Coffey, K.V. Chance, W.A. Traub, B. Carli, F. Mencaraglia, S. Piccioli, I.G. Nolt, J.V. Radostitz, R. Zander, G. Roland, D.W. Johnson, G.M Stokes, C.B. Farmer, and R.K. Seals (1990) Intercomparison of measurements of stratospheric hydrogen fluoride, J. Atmos. Chem., 10: 219–236.Google Scholar
  38. Molina, M.J., Rowland, F.S.: Stratospheric sink for Chlorofluoromethanes: chlorine atom-catalysed destruction of ozone. Nature. 249, 810–812 (1974)CrossRefGoogle Scholar
  39. Nair, S.K., Chambers, D.B., Radonjic, Z., Park, S.: Transport, chemistry, and thermodynamics of uranium hexafluoride in the atmosphere – evaluation of models using field data. Atmos. Environ. 32, 1729–1741 (1998)CrossRefGoogle Scholar
  40. Oppenheimer, C., Francis, P., Burton, M., Maciejewski, A.J.H., Boardman, L.: Remote measurement of volcanic gases by Fourier transform infrared spectroscopy. Appl. Phys. B Lasers Opt. 67, 505–515 (1998)CrossRefGoogle Scholar
  41. Petersen, R.L., Diener, R.: Vapour barrier assessment Programme for delaying and diluting heavier-than-air HF vapour clouds. J. Loss Prev. Process Ind. 3, 187–196 (1990)CrossRefGoogle Scholar
  42. Puttock, J.S., McFarlane, K., Prothero, A., Rees, F.J., Roberts, P.T., Witlox, H.W.M., Blewitt, D.N.: Dispersion models and hydrogen fluoride predictions. J. Loss Prev. Process Ind. 4, 16–26 (1991)CrossRefGoogle Scholar
  43. Raj, P.K. (1990) Hydrogen Fluoride and Fluorine Dispersion Models Integration into the Air Force Dispersion Assessment Model (ADAM), final report GL-TR-90-0321, Geophysics Laboratory, Air Force Systems Command, US Air Force, Hanscom Air Force Base, MA.Google Scholar
  44. Reisinger, A.R., Jones, N.B., Matthews, W.A., Rinsland, C.P.: Southern hemisphere ground based measurements of carbonyl fluoride (COF2) and hydrogen fluoride (HF): partitioning between fluoride reservoir species. Geophys. Res. Lett. 21, 797–800 (1994)CrossRefGoogle Scholar
  45. Schatz, K.W., Koopman, R.P.: Water spray mitigation of hydrofluoric acid releases. J. Loss Prev. Process Ind. 3, 222–233 (1990)CrossRefGoogle Scholar
  46. Schotte, W.: Collection of phase equilibrium data for separation technology. Ind. Eng. Chem. Process. Des. Dev. 19, 432–439 (1980)CrossRefGoogle Scholar
  47. Schotte, W.: Fog formation of hydrogen fluoride in air. Ind. Eng. Chem. Res. 26, 300–306 (1987)CrossRefGoogle Scholar
  48. Seinfeld, J.H., Pandis, S.N.: Atmospheric chemistry and physics: from air pollution to climate change. John Wiley & Sons, New York, NY (1998)Google Scholar
  49. Shevchuk, I.M., G.I. Agapov, and T.A. Markelova (1990) Corrosion of Structural Materials of Air Heaters in Air Flow Containing Hydrogen Fluoride, New Materials and Corrosion Control, UDC 620.193.4:669.71. Translated from Khimicheskoe I Neftyanoe Mashinostroenie, 11: 26, November 1989.Google Scholar
  50. Shinohara, H., Kazahaya, K., Saito, G., Matsushima, N., Kawanabe, Y.: Degassing activity from Iwodake Rhyolitic cone, Satsuma-Iwojima volcano, Japan: formation of a new degassing vent, 1990-1999. Earth Plants Space. 54, 175–185 (2002)CrossRefGoogle Scholar
  51. Smith, D.F.: Hydrogen fluoride polymer Spectrum. Hexamer and Tetramer, J Chem Phys. 28, 1040–1056 (1958)Google Scholar
  52. Tamir, A., Wisniak, J.: Activity coefficient calculations in multicomponent associating systems. Chem. Engr. Sci. 33, 651–656 (1978)CrossRefGoogle Scholar
  53. Tressaud, A. (2006) Fluorine and the Environment – Atmospheric Chemistry, Emissions, and Lithosphere, eds., Elsevier, Oxford, UK. ISBN-10: 0-444-52811-3.Google Scholar
  54. U.S. Department of Health and Human Services: Hazardous substances data Bank. National Toxicology Information Program, National Library of Medicine, Bethesda, MD (1993)Google Scholar
  55. U.S. Environmental Protection Agency (1977) Wet and dry deposition – A Synopsis Containing Estimates of Deposition Velocities for Some Pollutants and Trace Gases in the Atmosphere, report CERL-037, April.Google Scholar
  56. U.S. Environmental Protection Agency (1986) Hydrogen Chloride and Hydrogen Fluoride Emission Factors for the NAPAP Emission Inventory, project summary EPA/600/S7–85/041, January.Google Scholar
  57. Webber, D.M., Mercer, A., Jones, S.J.: Hydrogen fluoride source terms and dispersion. J. Loss Prev. Process Ind. 7, 94–105 (1994)CrossRefGoogle Scholar
  58. Witlox, H.W.M.: The HEGADAS model for ground-level heavy-gas dispersion – I. Steady-state model. Atmos. Environ. 28, 2917–2932 (1994a)CrossRefGoogle Scholar
  59. Witlox, H.W.M.: The HEGADAS model for ground-level heavy-gas dispersion – II. Time-dependent model. Atmos. Environ. 28, 2933–2946 (1994b)CrossRefGoogle Scholar
  60. Witlox, H.W.M., McFarlane, K.: Interfacing dispersion models in the HGSYSTEM hazard-assessment package. Atmos. Environ. 28, 2947–2962 (1994)CrossRefGoogle Scholar
  61. Zander, R., Gunson, M.R., Farmer, C.B., Rinsland, C.P., Irion, F.W., Mahieu, E.: The 1985 chlorine and Fluorine inventories in the stratosphere based on ATMOS observations at 30° north latitude. J. Atmos. Chem. 15, 171–196 (1992)CrossRefGoogle Scholar
  62. Zander, R., Roland, G., Delbouille, L., Sauval, A., Farmer, C.B., Norton, R.H.: Monitoring of the integrated column of hydrogen fluoride above the Jungfraujoch Station since 1977 – the HF/HCl column ratio. J. Atmos. Chem. 5, 385–394 (1987)CrossRefGoogle Scholar

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© Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  1. 1.Environmental Sciences DivisionOak Ridge National LaboratoryOak RidgeUSA

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