Abstract
The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m−3 respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.
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References
Andreini, B.P., Baroni, R., Galimberti, E., Sesana, G.: Aldehydes in the atmospheric environment: Evaluation of human exposure in the north-west area of Milan. Microchem. J. 67(1–3), 11–19 (2000). doi:10.1016/S0026-265X(00)00087-4
Arnold, F., Knop, G., Ziereis, H.: Acetone measurements in the upper troposphere and lower stratosphere—implications for hydroxyl radical abundances. Nature 321, 505–507 (1986). doi:10.1038/321505a0
Atkinson, R.: Gas-phase troposphere chemistry of organic chemistry: A review. Atmos. Environ. 24A, 1–41 (1990)
Atkinson, R.: Atmospheric chemistry of VOCs and NOX. Atmos. Environ. 34, 2063–2101 (2000). doi:10.1016/S1352-2310(99)00460-4
Báez, A.P., Belmont, R., Padilla, H.: Measurements of formaldehyde and acetaldehyde in the atmosphere of Mexico City. Environ. Pollut. 89, 163–167 (1995). doi:10.1016/0269-7491(94)00059-M
Báez, A.P., Padilla, H., Cevantes, J., Pereyra, D., Torres, M.C., Garcia, R., Belmont, R.: Preliminary study of the determination of ambient carbonyls in Xalapa City, Veracruz, Mexico. Atmos. Environ. 35, 1813–1819 (2001). doi:10.1016/S1352-2310(00)00475-1
Báez, A., Padilla, H., Garcia, R., Torres, M.D., Rosas, I., Belmont, R.: Carbonyl levels in indoor and outdoor air in Mexico City and Xalapa, Mexico. Sci. Total Environ. 302, 211–226 (2003). doi:10.1016/S0048-9697(02)00344-3
Bakeas, E.B., Argyris, D.I., Siskos, P.A.: Carbonyl compounds in the urban environment of Athens, Greece. Chemosphere 52, 805–813 (2003). doi:10.1016/S0045-6535(03)00257-1
Bowman, J.H., Barket Jr., D., Shepson, P.B.: Atmospheric chemistry of nonanal. Environ. Sci. Technol. 37, 2218–2225 (2003). doi:10.1021/es026220p
Carlier, P., Hannachi, H., Mouvier, G.: The chemistry of carbonyl compounds in the atmosphere-a review. Atmos. Environ. 20, 2079–2099 (1986). doi:10.1016/0004-6981(86)90304-5
Cavalcante, R.M., Campelo, C.S., Barbosa, M.J., Silveira, E.R., Carvalho, T.V., Nascimento, R.F.: Determination of carbonyl compounds in air and cancer risk assessment in an academic institute in Fortaleza, Brazil. Atmos. Environ. 40, 5701–5711 (2006). doi:10.1016/j.atmosenv.2006.04.056
Cecinato, A., Yassaa, N., Di Palo, V., Possanzini, M.: Observation of volatile and semi volatile carbonyls in an Algerian urban environment using dinitrophenylhydrazine/silica-HPLC and pentafluorophenylhydrazine/silica-GC-MS. J. Environ. Monit. 4, 223–228 (2002). doi:10.1039/b110616n
Cerón, R.M., Cerón, J.G., Muriel, M.: Diurnal and seasonal trends in carbonyl levels in a semi-urban coastal site in the Gulf of Campeche, Mexico. Atmos. Environ. 41, 63–71 (2007). doi:10.1016/j.atmosenv.2006.08.008
Chi, Y.G.: Determination of carbonyl compounds in the atmosphere and from plant emission by LC/MS. Dissertation for Doctor Degree in Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, November (2007)
Chi, Y., Feng, Y., Wen, S., Lü, H., Zhang, W., Sheng, G., Fu, J.: Determination of carbonyl compounds in the atmosphere by DNPH derivatization and LC–ESI-MS/MS detection. Talanta 72, 539–545 (2007). doi:10.1016/j.talanta.2006.11.018
Christensen, C.S., Skov, H., Lohse, C.: Temporal variation of carbonyl compound concentrations at a semi-rural site in Denmark. Atmos. Environ. 34, 287–296 (2000). doi:10.1016/S1352-2310(99)00297-6
Ciccioli, P., Brancaleoni, E., Frattoni, M., Cecinato, A., Brachetti, A.: Ubiquitous occurrence of semi-volatile carbonyl compounds in tropospheric samples and their possible source. Atmos. Environ. 27A, 1891–1901 (1993)
Correa, S., Martins, E., Arbilla, G.: Formaldehyde and acetaldehyde in a high traffic street of Rio de janeiro, Brazil. Atmos. Environ. 37, 23–29 (2003). doi:10.1016/S1352-2310(02)00805-1
Duan, J., Tan, J., Yang, L., Wu, S., Hao, J.: Concentration, sources and ozone formation potential of volatile organic compounds (VOCs) during ozone episode in Beijing. Atmos. Environ. 88, 25–35 (2008)
Duane, M., Poma, B., Rembges, D., Astorga, C., Larsen, B.R.: Isoprene and its degradation products as strong ozone precursors in Insubria, northern Italy. Atmos. Environ. 36, 3867–3879 (2002). doi:10.1016/S1352-2310(02)00359-X
Feng, Y.L., Wen, S., Wang, X.M., Sheng, G.Y., He, Q.S., Tang, J.H., Fu, J.M.: Indoor and outdoor carbonyl compounds in the hotel ballrooms in Guangzhou, China. Atmos. Environ. 38, 103–112 (2004). doi:10.1016/j.atmosenv.2003.09.061
Feng, Y.L., Wen, S., Chen, Y.J., Wang, X.M., Lu, H.X., Bi, X.H., Sheng, G.Y., Fu, J.M.: Ambient levels of carbonyl compounds and their sources in Guangzhou, China. Atmos. Environ. 39, 1789–1800 (2005). doi:10.1016/j.atmosenv.2004.10.009
Feng, J., Hu, M., Chan, C.K., Lau, P.S., Fang, M., He, L., Tang, X.: A comparative study of the organic matter in PM2.5 from three Chinese megacities in three different climatic zones. Atmos. Environ 40, 3983–3994 (2006). doi:10.1016/j.atmosenv.2006.02.017
Granby, K., Christensen, C.S., Lohse, C.: Urban and semi-rural observations of carboxylic acids and carbonyls. Atmos. Environ. 31, 1403–1415 (1997). doi:10.1016/S1352-2310(96)00347-0
Grosjean, D.: Formaldehyde and other carbonyls in Los Angeles ambient air. Environ. Sci. Technol. 16, 254–262 (1982). doi:10.1021/es00099a005
Grosjean, E., Grosjean, D., Fraser, M.P., Cass, G.R.: Air quality model evaluation data for organics. 2. C1-C14 carbonyls in Los Angeles. Environ. Sci. Technol 30, 2687–2703 (1996). doi:10.1021/es950758w
Grosjean, D., Grosjean, E., Moreira, L.F.R.: Speciated ambient carbonyls in Rio de Janeiro, Brazil. Environ. Sci. Technol. 36, 1389–1395 (2002). doi:10.1021/es0111232
Hellén, H., Hakola, H., Reissell, A., Ruuskanen, T.M.: Carbonyl compounds in boreal coniferous forest air in Hyytiälä, Southern Finland. Atmos. Chem. Phys. Discuss. 4, 2991–3011 (2004)
Hellén, H., Hakola, H., Pirjola, L., Laurila, T., Pystynen, K.H.: Ambient air concentrations, source profiles and source apportionment of 71 different C2–C10 volatile organic compounds in urban and residential areas of Finland. Environ. Sci. Technol. 40, 103–108 (2006). doi:10.1021/es051659d
Ho, K.F., Lee, S.C., Louie, P.K.K., Zou, S.C.: Seasonal variation of carbonyl compound concentrations in urban area of Hong Kong. Atmos. Environ. 36, 1259–1265 (2002). doi:10.1016/S1352-2310(01)00570-2
Ho, K.F., Lee, S.C., Tsai, W.Y.: Carbonyl compounds in the roadside environment of Hong Kong. J. Hazard. Mater. A133(1–3), 24–29 (2006). doi:10.1016/j.jhazmat.2005.09.054
Huang, J., Feng, Y., Xiong, B., Fu, J., Sheng, G.: Ambient Levels of Carbonyl Compounds in Shanghai. China Environ. Sci. (2009)
International Agency for Research on Cancer (IARC).: The IARC Monographs Series—IARC classifies formaldehyde as carcinogenic to humans—press release No. 153, 15 June (2004)
Jacob, D.J., Field, B.D., Jin, E.M., Bey, I., Li, Q., Logan, J.A., Yantosca, R.M.: Atmospheric budget of acetone. J. Geophys. Res. 107(D10), 4100 (2002). doi:10.1029/2001JD000694
Khwaja, H.A., Narang, A.: Carbonyls and non-methane hydrocarbons at a rural mountain site in northeastern United States. Chemosphere 71, 2030–2043 (2008). doi:10.1016/j.chemosphere.2008.01.042
Kwok, E.S.C., Atkinson, R.: Estimation of hydroxyl reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update. Atmos. Environ. 39, 1685–1995 (1995). doi:10.1016/1352-2310(95)00069-B
Lary, D.J., Shallcross, D.E.: Central role of carbonyl compounds in atmospheric chemistry. J. Geophys. Res. 105, 19771–19778 (2000). doi:10.1029/1999JD901184
Lee, S.C., Ho, K.F., Chan, L.Y., Zielinska, B., Chow, J.C.: Polycyclic aromatic hydrocarbons (PAHs) and carbonyl compounds in urban atmosphere of Hong Kong. Atmos. Environ. 35(34), 5949–5960 (2001). doi:10.1016/S1352-2310(01)00374-0
Levart, A., Veber, M.: Determination of aldehydes and ketones in air samples using cryotrapping sampling. Chemosphere 44, 701–708 (2001). doi:10.1016/S0045-6535(00)00369-6
Liu, W., Zhang, J., Zhang, L., Turpin, B.J., Weisel, C.P., Morandi, M.T., Stock, T.H., Colome, S., Kornl, R.: Estimating contributions of indoor and outdoor sources to indoor carbonyl concentrations in three urban areas of the United States. Atmos. Environ. 40(12), 2202–2214 (2006). doi:10.1016/j.atmosenv.2005.12.005
Liu, L., Flatoy, F., Ordóñez, C., Hak, C., Junkermann, W., Andreani-Aksoyoglu, S., Mellqvist, J., Galle, B., Prévôt, A.S.H., Isaksen, I.S.A.: Photochemnical modeling in the Po basin with focus on formaldehyde and ozone. Atmos. Chem. Phys. 7, 121–137 (2007)
Lü, H.X., Wen, S., Feng, Y., Wang, X., Bi, X., Sheng, G., Fu, J.: Indoor and outdoor carbonyl compounds and BTEX in the hospitals of Guangzhou, China. Sci. Total Environ. 368(2–3), 574–584 (2006). doi:10.1016/j.scitotenv.2006.03.044
Macintosh, D.L., Zimmer-Dauphinee, S.A., Manning, R.O., Williams, P.L.: Aldehyde concentrations in ambient air of coastal Georgia, U.S.A. Environ. Monit. Assess 63, 1573–2959 (2000). doi:10.1023/A:1006234610865
Montero, L., Vasconcello, S.P., Souza, S.R., Pires, M.A.F., Sanchez-ccoyllo, O.R., Andrade, M.F., Carvalho, L.R.F.: Measurements of atmospheric carboxylic acids and carbonyl compounds in Sao Paulo city, Brazil. Environ. Sci. Technol. 35(15), 3071–3081 (2001). doi:10.1021/es001875g
Moortgat, G., Grossmann, D., Boddenberg, A., Dallmann, G., Ligon, A.P., Turner, W.V., Gab, S., Slemr, F., Wieprecht, W., Acker, K., Kibler, M., Schlomski, S., Bachmann, K.: Hydrogen peroxide, organic peroxides and higher carbonyl compounds determined during the BERLIOZ campain. J. Atmos. Chem 42, 443–436 (2002). doi:10.1023/A:1015743013107
Moussa, S.G., El-Fadel, M., Saliba, N.A.: Seasonal, diurnal and nocturnal behaviors of lower carbonyl compounds in the urban environment of Beirut, Lebanon. Atmos. Environ. 40, 2459–2468 (2006). doi:10.1016/j.atmosenv.2005.12.031
Müller, K., Pelzing, M., Gnauk, T., Kappe, A., Teichmann, U., Spindler, G., Haferkorn, S., Jahn, Y., Herrmann, H.: Monoterpene emissions and carbonyl compound air concentrations during the blooming period of rape (Brassica napus). Chemosphere 49, 1247–1256 (2002). doi:10.1016/S0045-6535(02)00610-0
Müller, K., Haferkorn, S., Grabmer, W., Wisthaler, A., Hanser, A., Kreuzwieser, J., Cojocariu, C., Rennenberg, H., Herrmann, H.: Biogenic carbonyl compounds within and above a coniferous forest in Germany. Atmos. Environ. 40, S81–S91 (2006). doi:10.1016/j.atmosenv.2005.10.070
Nguyen, H.T., Takenaka, N., Bandow, H., Maeda, Y., Oliva, S., Botelho, M., Tavares, T.: Atmopsheric alcohols and aldehydes concentrations measured in Osaka, Japan and in Sao Paulo, Brazil. Atmos. Environ. 35, 3075–3083 (2001). doi:10.1016/S1352-2310(01)00136-4
Ohura, T., Amagai, T., Fusaya, M.: Regional assessment of ambient volatile organic compounds in an industrial harbor area, Shizuoka, Japan. Atmos. Environ. 40, 238–248 (2006). doi:10.1016/j.atmosenv.2005.09.064
Owen, S., Boissard, C., Street, R.A., Duckham, S.C.: Screening of 18 Mediterranean plant species for volatile organic compounds emissions. Atmos. Environ 31(S1), 101–117 (1997). doi:10.1016/S1352-2310(97)00078-2
Pal, R., Kim, K.-H., Hong, Y.-J., Jeon, E.-C.: The pollution status of atmospheric carbonyls in a highly industrialized area. J. Hazard. Mater. 153, 1122–1135 (2008). doi:10.1016/j.jhazmat.2007.09.068
Pang, X., Mu, Y.: Seasonal and diurnal variations of carbonyl compounds in Beijing ambient air. Atmos. Environ. 40, 6313–6320 (2006). doi:10.1016/j.atmosenv.2006.05.044
Peng, Q.T., Hu, W.X., Hou, X.J.: A New HPLC Method to Determine Carbonyl Compounds in Air. Chin. Chem. Lett. 13(12), 1199–1202 (2002)
Pinto, J.P., Solci, M.C.: Comparison of rural and urban atmospheric aldehydes in Londrina, Brazil. J. Braz. Chem. Soc. 18(5), 928–936 (2007). doi:10.1590/S0103-50532007000500009
Possanzini, M., Di Palo, V., Petricca, M., Fratarcangeli, R., Brocco, D.: Measurement of lower carbonyls in Rome urban ambient air. Atmos. Environ. 30, 3757–3764 (1996). doi:10.1016/1352-2310(96)00110-0
Possanzini, M., Di Palo, V., Cecinato, A.: Sources and photodecompositon of formaldehyde and acetaldehyde in Rome ambient air. Atmos. Environ. 36, 3195–3201 (2002). doi:10.1016/S1352-2310(02)00192-9
Possanzini, M., Tagliacozzo, G., Cecinato, A.: Ambient Levels and Sources of Lower Carbonyls at Montelibretti, Rome (Italy). Water Air Soil Pollut. 183, 447–454 (2007). doi:10.1007/s11270-007-9393-1
Satsumabayashi, H., Kurita, H., Chang, Y.S., Carmichael, G.R.: Photochemical formations of lower aldehydes and lower fatty acids under long-range transport in central Japan. Atmos. Environ. 29, 255–266 (1995). doi:10.1016/1352-2310(94)00231-9
Shepson, P.B., Hastie, D.R., Schiff, H.I., Polizzi, M., Bottenheim, J.W., Anlauf, K., Mackay, G.I., Karecki, D.R.: Atmospheric concentrations and temporal variations of C1–C3 carbonyl compounds at two rural sites in central Ontario. Atmos. Environ. 25A, 2001–2015 (1991)
Sin, D.W.M., Wong, Y., Louie, P.K.K.: Trends of ambient carbonyl compounds in the urban environment of Hong Kong. Atmos. Environ. 35, 5961–5969 (2001). doi:10.1016/S1352-2310(01)00359-4
Uebori, M., Imamura, K.: Analysis of aliphatic and aromatic carbonyl compounds in ambient air by LC/MS/MS. Anal. Sci. 20, 1459–1462 (2004). doi:10.2116/analsci.20.1459
Vasconcellos, P.C., Carvalho, L.R.F., Pool, C.S.: Volatile organic compounds inside urban tunnels of Sao Paulo City, Brazil. J. Braz. Chem. Soc 16(6A), 1210–1216 (2005). doi:10.1590/S0103-50532005000700019
Villanueva-Fierro, I., Popp, C.J., Martin, R.S.: Biogenic emissions and ambient concentrations of hydrocarbons, carbonyl compounds and organic acids from ponderosa pine and cottonwood trees at rural and forested sites in Central New Mexico. Atmos. Environ. 38(2), 249–260 (2004). doi:10.1016/j.atmosenv.2003.09.051
Viskari, E.-L., Vartiainen, M., Pasanen, P.: Seasonal and diurnal variation information and acetaldehyde concentrations along a highway in Eastern Finland. Atmos. Environ. 34, 917–923 (2000). doi:10.1016/S1352-2310(99)00307-6
Wang, B., Lee, S.C., Ho, K.F.: Characteristics of carbonyls: Concentrations and source strengths for indoor and outdoor residential microenvironments in China. Atmos. Environ. 41, 2851–2861 (2007). doi:10.1016/j.atmosenv.2006.11.039
Wen, S., Feng, Y., Wang, X., Sheng, G., Fu, J., Bi, X.: Development of a compound-specific isotope analysis method for acetone via 2, 4-dinitrophenylhydrazine derivatization. Rapid Commun. Mass Spectrom. 18(22), 2669–2672 (2004). doi:10.1002/rcm.1674
Wen, S., Feng, Y., Yu, Y., Bi, X., Wang, X., Sheng, G., Fu, J., Peng, P.: Development of a compound-specific isotope analysis method for atmospheric formaldehyde and acetaldehyde. Environ. Sci. Technol. 9(16), 6202–6207 (2005). doi:10.1021/es049553q
Wildt, J., Kobel, K., Schuh-Thomas, G., Heiden, A.C.: Emissions of oxygenated volatile organic compounds from plants. Part II: Emissions of saturated aldehydes. J. Atmos. Chem. 45, 173–196 (2003). doi:10.1023/A:1024030821349
Yan, Z.G., Wang, C.Z.: Wound-induced green leaf volatiles cause the release of acetylated derivatives and a terpenoid in maize. Phytochemistry 67, 34–42 (2006). doi:10.1016/j.phytochem.2005.10.005
Yu, Y., Wen, S., Feng, Y., Bi, X., Wang, X., Peng, P., Sheng, G., Fu, J.: Development of a compound-specific isotope analysis method for atmospheric formaldehyde via NaHSO3 and cysteamine derivatization. Anal. Chem. 78(4), 1206–1211 (2006). doi:10.1021/ac051616f
Yu, Y., Wen, S., Lü, H., Feng, Y., Wang, X., Sheng, G., Fu, J.: Characteristics of atmospheric carbonyls and VOCs in forest park in south China. Environ. Monit. Assess. 137, 275–285 (2008). doi:10.1007/s10661-007-9759-2
Zhang, J., He, Q., Lioy, P.J.: Characteristics of aldehydes:concentrations, sources, and exposure for indoor and outdoor residential microenvironments. Environ. Sci. Technol. 28, 146–152 (1994). doi:10.1021/es00050a020
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The authors gratefully acknowledge the NOAA Air Resources Laboratory (ARL) for the provision of the HYSPLIT transport and dispersion model and/or READY website (http://www.arl.noaa.gov/ready.html) used in this publication. This work was financially supported by the Chinese National Natural Science Foundation (40503012, 40773047), Shanghai Leading Academic Disciplines (S30109) and innovation fund of Shanghai University.
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Huang, J., Feng, Y., Li, J. et al. Characteristics of carbonyl compounds in ambient air of Shanghai, China. J Atmos Chem 61, 1–20 (2008). https://doi.org/10.1007/s10874-009-9121-x
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DOI: https://doi.org/10.1007/s10874-009-9121-x