A new 3D Cd(II) metal–organic framework of [Cd2(HIDC)2(bibp)1.5]n (1) was synthesized hydrothermally by the reaction of imidazole-4,5-dicarboxylic acid (H2IDC) and 4,4′-bis(imidazol-1-ylmethyl)biphenyl (bibp) with Cd(NO3)2·4H2O. Single-crystal X-ray diffraction analysis reveals that this compound crystallizes in triclinic, space group Pī with a = 9.6610(3), b = 15.5866(5), c = 16.0228(6) Ǻ, α = 110.662(3), β = 101.521(3), γ = 107.115(3)˚, V = 2029.46(15) Ǻ3, Z = 2, Dc = 1.644 g cm−3, µ = 1.113 mm−1, F(000) = 1002, the final R1 = 0.0468 and wR2 = 0.0962 for 8932 observed reflections with I > 2σ(I). In 1, the alternately interconnection of Cd(II) ions by µ2-HIDC2− and µ3-HIDC2− anions resulted in the formation of 1D [Cd2(µ2-HIDC)(µ3-HIDC)]∞ with the right- and left-helical chains, which were further linked by the oxygen atoms derived from one of the carboxylate groups of µ3-HIDC2− anions, generating the 1D double helical chain structure of [Cd4(µ2-HIDC)2(µ3-HIDC)2]∞ along a axis. These adjacent 1D double chains are further linked by cis-µ2-bibp ligands to form a 2D network structure of [Cd4(µ2-HIDC)2(µ3-HIDC)2(cis-µ2-bibp)2]n, which are further pillared by trans-µ2-bibp ligands to generate a 3D layered-pillared metal–organic framework architecture of [Cd4(µ2-HIDC)2(µ3-HIDC)2(cis-µ2-bibp)2(trans-µ2-bibp)]n. Furthermore, the thermal stability and luminescent property of 1 have also been investigated.
A 3D Cd(II) layered-pillared metal–organic framework was synthesized hydrothermally. This new compound displays high thermal stability and intense fluorescent emission.
This is a preview of subscription content, access via your institution.
Buy single article
Instant access to the full article PDF.
Tax calculation will be finalised during checkout.
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
Tax calculation will be finalised during checkout.
Lu WG, Wei ZW, Gu ZY, Liu TF, Jihye Park JP, Tian J, Zhang MW, Zhang Q, Mathieu Bosch TG, Zhou HC (2014) Chem Soc Rev 43:5561–5593
Zhang XJ, Wang WJ, Hu ZJ, Wang GN, Uvdal K (2015) Coord Chem Rev 284:206–235
Cui YJ, Li B, He HJ, Zhou W, Chen BL, Qian GD (2016) Acc Chem Res 49:483–493
Lustig WP, Mukherjee S, Rudd ND, Desai AV, Li J, Ghosh SK (2017) Chem Soc Rev 46:3242–3285
Xie LH, Liu XM, He T, Li JR (2018) Chem 4:1911–1927
Pan L, Parker B, Huang XY, Olson DH, Lee J, Li J (2006) J Am Chem Soc 128:4180–4181
Wen HY, Chen CG, Wen HL, Mu XW, Yao K (2018) J Chem Crystallogr 48:12–18
Wang J, Lin ZJ, Ou YC, Yang NL, Zhang YH, Tong ML (2008) Inorg Chem 47:190–199
Sharif MA, Najafi GR (2019) J Chem Crystallogr 2:98–105
Gu JM, Kim WS, Huh S (2011) Dalton Trans 41:10826–10829
Yang F, Xu G, Dou YB, Wang B, Zhang H, Wu H, Zhou W, Li JR, Chen BL (2017) Nat Energy 2:877–883
Wang LVXL, Wang KC, Su B, Zou J, Xie XD, Li YB, Zhou JR HC (2017) J Am Chem Soc 139:211–217
Lu WG, Su CY, Lu TB, Jiang L, Chen JM (2006) J Am Chem Soc 128:34–35
Zou RQ, Sakurai H, Xu Q (2006) Angew Chem Int Ed 45:2542–2546
Liu YL, Kravtsov V, Larsen RW, Eddaoudi M (2006) Chem Commun 14:1488–1490
Liu YL, Kravtsov V, Eddaoudi M (2008) Angew Chem Int Ed 47:8446–8448
Alkordi MH, Liu YL, Larsen RW, Eubank JF, Eddaoudi M (2008) J Am Chem Soc 130:12639–12640
Gurunatha KL, Uemura K, Maji TK (2008) Inorg Chem 47:6578–6580
Otieno T, Gipson AM, Parkin S (2002) J Chem Crystallogr 32:81–85
Lu WG, Jiang L, Feng XL, Lu TB (2008) Cryst Growth Des 8:986–994
Chu Q, Liu GX, Huang YQ, Wang XF, Sun WY (2007) Dalton Trans 38:4302–4311
Duan XY, Li YZ, Su Y, Zang SQ, Zhu CJ, Meng QJ (2007) CrystEngComm 9:758–766
Li SL, Lan YQ, Ma JF, Yang J, Wei GH, Zhang LP, Su ZM (2008) Cryst Growth Des 8:675–684
Li SL, Lan YQ, Qin JS, Ma JF, Liu J, Yang J (2009) Cryst Growth Des 9:4142–4146
Liu HW, Lu WG (2011) Chin J Inorg Chem 27:1810–1816
Liu M, Li XP, Li JP, Sun WH, Yang ZP, Gong FB, Chen J, Ma JS, Yang GQ (2009) Transit Met Chem 34:185–190
Liu HW, Lu WG (2010) Chin J Struct Chem 29:1416–1420
Yu F, Yang XH, Liang ZW, Chen HL (2004) J Nanjing Univ (Nat Sci) 40:632–638
Sheldrick GM (2015) SHELXT-Integrated space-group and crystal-structure determination. Acta Crystallogr A71:3–8
Sheldrick GM (2015) Acta Crystallogr C 71:3–8
Spek AL (2009) Acta Cryst D 65:148–155
Calahorro AJ, Salinas-Castillo A, Fairen-Jimenez D, Seco JM, Mendicute-Fierro C, Gómez-Ruiz S, López-Viseras ME, Rodríguez-Diéguez A (2015) Inorg Chim Acta 427:131–137
Zhong DC, Lu WG (2015) Chin J Inorg Chem 31:1177–1184
Lu WG, Wang XB, Liu HW, Hong XL (2016) Chin J Struct Chem 35:383–391
This study is financially supported by the Natural Science Foundation of Guangdong Province (Nos. 2015A030313750 and 2016A030307048), Characteristic Innovation Projects Guangdong Provincial Department of Education (Natural Science Category, Nos. 2014KTSCX169 and 2018KTSCX208), and the Student Innovation and Entrepreneurship Training Program of China (201710576012). Dr. Tao Yang is supported by National Science Foundation of Guangxi (2018GXNSFAA281210).
The authors declare there are no conflicts of interest regarding the publication of this paper.
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations
Electronic supplementary material
Below is the link to the electronic supplementary material. CCDC 1843418 contains the supplementary crystallographic data for the compound 1. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving. html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax:(+ 44) 1223-336-033; or e-mail: firstname.lastname@example.org.
About this article
Cite this article
Wang, X., Shi, X., Yang, T. et al. Synthesis, Structure and Luminescent Property of a 3D Layered-Pillared Cd(II) Metal–Organic Framework Derived from Mixed Rigid and Flexible Ligands. J Chem Crystallogr 51, 50–56 (2021). https://doi.org/10.1007/s10870-020-00825-6
- Metal–organic framework
- Crystal structure
- Luminescent property