Journal of Chemical Crystallography

, Volume 46, Issue 10–12, pp 421–428 | Cite as

Synthesis and Crystal Structures of the Nickel(II) and [Tri(n-butyl)]tin(IV) Complexes with the New Sulfonamide Carboxylic Acid, 4-{(2-Nitrophenylsulfonamido)methyl}cyclohexanecarboxylic Acid

  • Muhammad Danish
  • Rabia Ayub Butt
  • Saba Akbar
  • Muhammad Ashfaq
  • Graham Smith
Original Paper


The structures of the nickel(II) and [tri(n-butyl)]tin(IV) complexes with the sulfonamide carboxylic acid, 4-{(2-nitrophenylsulfonamido)methyl}cyclohexanecarboxylic acid, [Ni(C14H17N2O6S)2(H2O)4], (1), and [Sn(C4H9)3(C14H17N2O6S)]n, (2) have been determined. Crystals of 1 are triclinic, space group P−1, with unit cell dimensions a = 5.2264(4), b = 6.2415(2), c = 27.1409(16) Å, α = 85.682(4), β = 89.935(4), γ = 82.861(5)o and Z = 1, while compound 2 is monoclinic, space group C2/c, with unit cell dimensions a = 30.425(3), b = 10.1384(5), c = 19.4463(13) Å, β = 92.303(7)o and Z = 8. Compound 1 is a discrete centrosymmetric octahedral NiO6 complex comprising four waters and two O-donors from inversion-related monodentate carboxylate ligands. Compound 2 is coordination polymeric with the five-coordinate SnIV centre having the common trigonal bipyramidal repeat unit with three tri(n-butyl) groups occupying the trigonal plane of the bipyramid and the carboxylate O-donors bridging the apical sites.

Graphical Abstract


NiII and SnIV complexes Sulfonamide carboxylates Hydrogen-bonding 



We are thankful to Higher Education Commission (HEC) of Pakistan for funding this work under the Project No. 20-2549/NRPU/R&D/HEC/12. GS acknowledges support from the Science and Engineering Faculty, Queensland University of Technology, Brisbane, Australia.

Supplementary material

10870_2016_671_MOESM1_ESM.docx (57 kb)
Supplementary material 1 (DOCX 57 kb)


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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of GujratGujratPakistan
  2. 2.Science and Engineering FacultyQueensland University of TechnologyBrisbaneAustralia

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