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[V10O28]6− Clusters Modified by Alkaline-Earth Metals: New Synthesis Route, Structure and Characterization

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Abstract

Four [V10O28]6− clusters modified by alkaline-earth metals ions have been prepared by a new simple method in room temperature. The compound 1 is a novel linear tetra-nuclear strontium(II) cluster linked by water molecules and supported through [V10O28]6− leading to forming an interesting 1D chain. To the best our knowledge, this kind of linear tetra-nuclear strontium clusters and 1D chain have not been reported.

Graphical Abstract

Four [V10O28]6− clusters modified by alkaline-earth metals have been prepared by a new simple method in room temperature. The compound 1 is a novel linear tetra-nuclear strontium(II) cluster linked by water molecules and supported through [V10O28]6− leading to forming an interesting 1D chain. To the best our knowledge, this kind of linear tetra-nuclear strontium clusters and 1D chain have not been reported.

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Acknowledgments

We are grateful to the National Natural Science Foundation of China (No. 21401111), Education Department Foundation of Henan Province (Nos. 14A150020, 14A150032) and Natural Science Foundation of Nanyang Normal University (Nos. ZX2014038, ZX2014045).

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Authors and Affiliations

  1. School of Biochemical and Chemical Engineering, Nanyang Institute of Technology, Nanyang, 473000, People’s Republic of China

    Chaojun Du

  2. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Yingying Zhao, Lijuan Wang & Baokuan Chen

Authors
  1. Chaojun Du
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  2. Yingying Zhao
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  3. Lijuan Wang
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  4. Baokuan Chen
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Corresponding authors

Correspondence to Lijuan Wang or Baokuan Chen.

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Du, C., Zhao, Y., Wang, L. et al. [V10O28]6− Clusters Modified by Alkaline-Earth Metals: New Synthesis Route, Structure and Characterization. J Chem Crystallogr 45, 435–439 (2015). https://doi.org/10.1007/s10870-015-0611-1

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  • DOI: https://doi.org/10.1007/s10870-015-0611-1

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