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Journal of Chemical Crystallography

, Volume 45, Issue 10–12, pp 435–439 | Cite as

[V10O28]6− Clusters Modified by Alkaline-Earth Metals: New Synthesis Route, Structure and Characterization

  • Chaojun Du
  • Yingying Zhao
  • Lijuan Wang
  • Baokuan Chen
Original Paper
  • 243 Downloads

Abstract

Four [V10O28]6− clusters modified by alkaline-earth metals ions have been prepared by a new simple method in room temperature. The compound 1 is a novel linear tetra-nuclear strontium(II) cluster linked by water molecules and supported through [V10O28]6− leading to forming an interesting 1D chain. To the best our knowledge, this kind of linear tetra-nuclear strontium clusters and 1D chain have not been reported.

Graphical Abstract

Four [V10O28]6− clusters modified by alkaline-earth metals have been prepared by a new simple method in room temperature. The compound 1 is a novel linear tetra-nuclear strontium(II) cluster linked by water molecules and supported through [V10O28]6− leading to forming an interesting 1D chain. To the best our knowledge, this kind of linear tetra-nuclear strontium clusters and 1D chain have not been reported.

Keywords

Polyoxovanadates Alkaline-earth metals Clusters 

Notes

Acknowledgments

We are grateful to the National Natural Science Foundation of China (No. 21401111), Education Department Foundation of Henan Province (Nos. 14A150020, 14A150032) and Natural Science Foundation of Nanyang Normal University (Nos. ZX2014038, ZX2014045).

Supplementary material

10870_2015_611_MOESM1_ESM.docx (10 kb)
Supplementary material 1 (DOCX 10 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.School of Biochemical and Chemical EngineeringNanyang Institute of TechnologyNanyangPeople’s Republic of China
  2. 2.College of Chemistry and Pharmaceutical EngineeringNanyang Normal UniversityNanyangPeople’s Republic of China

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