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Two Novel Cationic Frameworks Based on Cadmium(II) Vinylphosphonate with 4,4′-Bipyridine as Coligand

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Abstract

The reaction of cadmium nitrate and vinylphosphonic acid (H2L) with 4,4′-bipyridine (bipy) as coligand led to two novel cadmium(II) vinylphosphonates, namely, [Cd4(L)3(NO3)(bipy)4(H2O)3]·(NO3)·3(H2O) (1) and [Cd3(HL)3(L)(bipy)3(H2O)4]·(NO3)·3.5(H2O) (2). Both compounds feature a cationic framework which encloses charge-balanced nitrate anions as well as guest water molecules. They represent the first examples of metal-organic frameworks based on mixed bridging ligands that contain a low-carbon-number alkylphosphonate. Notably, the cationic framework of 2 manifests an unprecedented (4,5)-connected net topology with point symbol of (42·6·83)·(43·65·82)2.

Graphical Abstract

Two novel cationic frameworks based on cadmium(II) vinylphosphonate with 4,4′-bipyridine as coligand are reported here.

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Acknowledgments

This work was supported by the NNSF of China (21061001, 21361002), and the Young Scientists Training Program of Jiangxi Province (20122BCB23020).

Conflict of interests

The authors declare no conflict of interests.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou, 341000, People’s Republic of China

    Yingping Zhao, Cuicui Zhao, Tingting Xu, Qing Huang & Ziyi Du

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  1. Yingping Zhao
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  2. Cuicui Zhao
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  3. Tingting Xu
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  4. Qing Huang
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  5. Ziyi Du
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Corresponding author

Correspondence to Ziyi Du.

Appendix: Supplementary Material

Appendix: Supplementary Material

CCDC 951627 and 951628 contain the supplementary crystallographic data for this article. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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Zhao, Y., Zhao, C., Xu, T. et al. Two Novel Cationic Frameworks Based on Cadmium(II) Vinylphosphonate with 4,4′-Bipyridine as Coligand. J Chem Crystallogr 44, 480–486 (2014). https://doi.org/10.1007/s10870-014-0542-2

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  • DOI: https://doi.org/10.1007/s10870-014-0542-2

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