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Synthesis, Crystal Structure and Fluorescence Properties of Three 1-D Coordination Polymers Based on Fluconazole

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Abstract

Three complexes based on fluconazole, {[Cd(HFlu)2(bptc)0.5]·4.5H2O}n (1), {[Cd(HFlu)2(OH-BDC)]·8H2O}n (2), {[Mn(HFlu)2(OH-BDC)]·8H2O}n (3). (HFlu = fluconazole; H4bptc = 3,3′,4,4′-biphenyltetracarboxylic acid; OH-H2BDC = 5-hydroxyisophthalic acid) have been synthesized and structurally characterized. Complex 1 is a 1D loop-containing chain with a large number of free water molecules, which are further interconnected via O–H···O and O–H···N hydrogen bonds to form a 3D supramolecular framework. Complex 2 and 3 are both a 1D tubular structure with the distorted dinuclear cadmium rectangular shaped cavity and a large number of free water molecules are accommodated in the 1D tubular structure. The photoluminescent properties of the coordination polymers have also been investigated.

Graphical Abstract

Three 1-D complexes based on fluconazole have been reported, together with their photoluminescent properties.

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Acknowledgments

This work is supported by the Innovation Project of Guangxi University for Nationalities (gxun-chx2013099).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, People’s Republic of China

    Gang-Hong Pan, Shi-Hua Xu, Wen-Jia Xu, Peng Liang, Wei-Man Tian & Zhong-Jing Huang

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  1. Gang-Hong Pan
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  2. Shi-Hua Xu
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  3. Wen-Jia Xu
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  4. Peng Liang
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Correspondence to Zhong-Jing Huang.

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Pan, GH., Xu, SH., Xu, WJ. et al. Synthesis, Crystal Structure and Fluorescence Properties of Three 1-D Coordination Polymers Based on Fluconazole. J Chem Crystallogr 44, 312–319 (2014). https://doi.org/10.1007/s10870-014-0516-4

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  • DOI: https://doi.org/10.1007/s10870-014-0516-4

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