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Synthesis and Characterization of a New Bi-Supported Dawson-Like Heteropolytungstate

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Abstract

A new bi-supported Dawson-like heteropolytungstate [Cu(phen)(H2O)]2[Cu(phen)(H2O)3]2H[SbW18O60]·5H2O (1) (phen = 1,10-phenanthroline) was synthesized and characterized. The crystal data are listed as follows: C48H59Cu4N8O73SbW18 (Mr = 5600.23), Triclinic, space group P-1, a = 12.4169(9) Å, b = 13.9072(10) Å, c = 14.5712(11) Å, α = 93.8210(10)°, β = 100.0840(10)°, γ = 93.3720(10)°, Z = 1. The counter cation Cu(II) centers show two kinds of coordination environments: octahedral Cu(1) and tetragonal pyramidal Cu(2). The corner-shared Cu(1) and Cu(2) polyhedra are anchored to the surface of polyanion through Cu(1)–O interaction. There are extensive and effective intermolecular hydrogen bonding and π···π interactions to stabilize the structure of compound 1.

Graphical Abstract

A bi-supported Dawson-like heteropolytungstate [Cu(phen)(H2O)]2[Cu(phen)(H2O)3]2H[SbW18O60]·5H2O was synthesized and characterized.

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References

  1. Miras HN, Cooper GJT, Long DL, Bögge H, Müller A, Streb C, Cronin L (2010) Science 327:72–74

    Article  CAS  Google Scholar 

  2. Mishra PP, Pigga J, Liu TB (2008) J Am Chem Soc 130:1548–1549

    Article  CAS  Google Scholar 

  3. Yin QS, Tan JM, Besson C, Geletii YV, Musaev DG, Kuznetsov AE, Luo Z, Hardcastle KI, Hill CL (2010) Science 328:342–345

    Article  CAS  Google Scholar 

  4. Pradeep CP, Long DL, Newton GN, Song YF, Cronin L (2008) Angew Chem Int Ed 47:4388–4391

    Article  CAS  Google Scholar 

  5. Gao PS, Cheng TC, Mak W (2009) J Am Chem Soc 131:18257–18259

    Article  CAS  Google Scholar 

  6. Peng ZH (2004) Angew Chem Int Ed Engl 43:930–935

    Article  CAS  Google Scholar 

  7. Zheng ST, Zhang J, Yang GY (2008) Angew Chem Int Ed Engl 47:3909–3913

    Article  CAS  Google Scholar 

  8. Han ZG, Chai T, Zhai XL, Wang JY, Hu CW (2009) Solid State Sci 11:1998–2002

    Article  CAS  Google Scholar 

  9. Song YF, Long DL, Cronin L (2007) Angew Chem Int Ed 46:3900–3904

    Article  CAS  Google Scholar 

  10. Coronado E, Galán-Mascarós JR, Giménez-Saiz C, Gómez-García CJ, Martínez-Ferrero E, Almeida M, Lopes EB, Capelli SC, Llusar RM (2004) J Mater Chem 14:1867–1872

    Article  CAS  Google Scholar 

  11. Coronado E, Giménez-Saiz C, Gómez-García CJ, Capelli SC (2004) Angew Chem Int Ed 43:3022–3025

    Article  CAS  Google Scholar 

  12. Long DL, Burkholder E, Cronin L (2007) Chem Soc Rev 36:105–121

    Article  CAS  Google Scholar 

  13. Liu TB, Diemann E, Li HL, Dress AWM, Müller A (2003) Nature 426:59–61

    Article  CAS  Google Scholar 

  14. Long DL, Cronin L (2006) Chem Eur J 12:3698–3706

    Article  CAS  Google Scholar 

  15. Song YF, McMillan N, Long DL, Thiel J, Ding YL, Chen HS, Gadegaard N, Cronin L (2008) Chem Eur J 14:2349–2354

    Article  CAS  Google Scholar 

  16. Pradeep CP, Long DL, Newton GN, Song YF, Cronin L (2008) Angew Chem Int Ed 47:4388–4391

    Article  CAS  Google Scholar 

  17. Krebs B, Klein R, Pope MT, Müller A (eds) (1994) Polyoxometalates: from platonic solids to anti-retroviral activity. Kluwer Academic, Dordrecht, p 55

    Google Scholar 

  18. Brown ID, Alternatt D (1985) Acta Cryst B 41:244–247

    Article  Google Scholar 

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Acknowledgments

This work was financially supported by the Natural Science Foundation of China (20701011), and the Natural Science Foundation of Hebei province (No. B2011205035), and the Education Department Foundation of Hebei province (Z2006436).

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Authors and Affiliations

  1. College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang, 050024, Hebei, China

    Zhangang Han, Qinghua Hao, Zhaohui Wang & Xueliang Zhai

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  1. Zhangang Han
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  2. Qinghua Hao
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  3. Zhaohui Wang
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  4. Xueliang Zhai
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Correspondence to Zhangang Han.

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Han, Z., Hao, Q., Wang, Z. et al. Synthesis and Characterization of a New Bi-Supported Dawson-Like Heteropolytungstate. J Chem Crystallogr 43, 1–5 (2013). https://doi.org/10.1007/s10870-012-0376-8

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  • DOI: https://doi.org/10.1007/s10870-012-0376-8

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