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Synthesis, Crystal Structure and Luminescent Properties of One Silver Complex with 3,5-Diphenylpyrazole

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Abstract

A new Ag(I) complex Ag(HL)2(NO3) 1 has been synthesized with 3,5-diphenylpyrazole (HL) and characterized by IR spectrum, elemental analysis and X-ray crystallography. The crystallographic data for the complex 1: triclinic \( P{\bar{\text{1}}} \), a = 10.4369(17) Å, b = 10.4837(18) Å, c = 12.963(2) Å, α = 69.318(2)°, β = 86.733(3)°, γ = 88.263(2)°, V = 1324.7(4) Å3, Z = 2, Dc = 1.530 Mg m−3, F(000) = 620, μ = 0.803 mm−1, R 1 = 0.0251, wR 2 = 0.0638. Ag(I) atom is bound to two nitrogen atoms from two ligands. In solid state there are π···π interactions and C–H···π interactions between adjacent units to generate 2D supramolecular structure. The title complex shows strong luminescent emission at 389 and 467 nm in solid state at room temperature.

Graphical Abstract

A new silver complex has been synthesized with 3,5-diphenylpyrazole, in which π···π interactions and C–H···π interactions link the molecules to form two-dimensional supramolecular network.

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Acknowledgments

This study was supported by China Postdoctoral Special Science Foundation Funded Project, China Postdoctoral Science Foundation, the Foundation for University Youth Key Teacher of Henan Province of China and the Foundation co-established by the Province and the Ministry of Henan University.

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Authors and Affiliations

  1. Institute of Molecular and Crystal Engineering School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, People’s Republic of China

    Dongbin Dang, Haiyan Li, Guangshui Zheng & Yan Bai

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  1. Dongbin Dang
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  2. Haiyan Li
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  3. Guangshui Zheng
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  4. Yan Bai
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Correspondence to Yan Bai.

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Dang, D., Li, H., Zheng, G. et al. Synthesis, Crystal Structure and Luminescent Properties of One Silver Complex with 3,5-Diphenylpyrazole. J Chem Crystallogr 41, 1612–1615 (2011). https://doi.org/10.1007/s10870-011-0148-x

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