Advertisement

Synthesis and Crystal Structure of (E)-1-(2,3-Dihydroxybenzlidene)-4,4-Dimethythiosemicarbazide

  • Ajay Pal Singh Pannu
  • Maninder Singh Hundal
Original Paper

Abstract

The Schiff base C10H13N3O2S is monoclinic, having unit cell parameters a = 9.788(1) Å, b = 9.615(1) Å, c = 12.605(1) Å, β = 108.41(1)° and V = 1125.56(2) Å3 and belongs to P21/n space group. The molecule is almost planar. The two hydroxyl groups present on the phenyl ring are involved in intermolecular H-bonding, which results in the stacking of molecules in the anti-parallel fashion leading an interesting network of channels. Besides this C–H⋯π and π–π (edge to edge) interactions appear to provide stability to the crystal lattice.

Graphical Abstract

Keywords

2,3-Dihydroxybenzaldehyde Thione Thiolate Antiparallel π Interactions 

Notes

Acknowledgment

A. P. S. Pannu is grateful to the University Grants Commission for research fellowship.

References

  1. 1.
    Cambell MJM (1975) Coord Chem Rev 15:279CrossRefGoogle Scholar
  2. 2.
    Padhye SB, Kauffman GB (1985) Coord Chem Rev 63:127CrossRefGoogle Scholar
  3. 3.
    Haiduo I, Silvestru C (1990) Coord Chem Rev 99:253CrossRefGoogle Scholar
  4. 4.
    West DX, Padye SB, Sonawane PB (1991) Struct Bond 76:1Google Scholar
  5. 5.
    Tion YP, Duan CY, Lu ZL, You XZ, Fun HK, Kandasamy S (1996) Polyhedron 15(13):2263CrossRefGoogle Scholar
  6. 6.
    Chattopadhyay D, Mazumdar SK, Banerjee T, Ghosh S, Mak TCW (1988) Acta Crystallogr C 44:1025CrossRefGoogle Scholar
  7. 7.
    Seena EB, Kurup MRP, Suresh E (2008) J Chem Crystallogr 38:93CrossRefGoogle Scholar
  8. 8.
    Jayasree S, Arvindakshan KK (1993) Transition Met Chem 18:85CrossRefGoogle Scholar
  9. 9.
    Bernstein J, Yale HL, Losee K, Holsing M, Martins J, Lott WA (1951) J Am Chem Soc 73:906CrossRefGoogle Scholar
  10. 10.
    Donovick R, Pansy F, Stryker G, Bernstein J (1950) J Bacteriol 59:667Google Scholar
  11. 11.
    Swesi AT, Farina Y, Kassim M, Weng S (2006) Acta Crystallogr E 62:o5457CrossRefGoogle Scholar
  12. 12.
    Siemens XSCANS (1994) X-ray single crystal analysis system, version 2.1. Siemens Analytical X-Ray Instruments Inc., MadisonGoogle Scholar
  13. 13.
    Altomare A, Cascarano G, Giacovazzo C, Guagliardi A (1993) J Appl Crystallogr 26:343CrossRefGoogle Scholar
  14. 14.
    Sheldrick GM (1997) SHELX97. University of Göttingen, GöttingenGoogle Scholar
  15. 15.
    Farrugia LJ (1999) J Appl Crystallogr 32:837CrossRefGoogle Scholar
  16. 16.
    Seena EB, Bessy Raj BN, Kurup MRP, Suresh E (2006) J Chem Crystallogr 36:189CrossRefGoogle Scholar
  17. 17.
    Tan KW, Farina Y, Hee C, Maah MJ, Weng S (2008) Acta Crystallogr E 64:o1073CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Ajay Pal Singh Pannu
    • 1
  • Maninder Singh Hundal
    • 1
  1. 1.Department of ChemistryGuru Nanak Dev UniversityAmritsarIndia

Personalised recommendations