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Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

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Abstract

A novel samarium(III) polymer, [Sm2(C6H5COO)6(CH3OH)3]·CH3OH (1) has been synthesized and characterized by single crystal X-ray diffraction and magnetic measurements. Polymer 1 crystallizes in monoclinic space group P2(1)/c, with a = 15.1247(6), b = 18.3351(7), c = 21.1266(6) Å, β = 126.830(2)°, V = 4689.4(3) Å3, and Z = 4. Single crystal X-ray analysis reveals a chain-like structure of 1 consisted of alternating eight- and nine-coordinate Sm(III) ions bridged by benzoate ligands in different coordination modes. A treatment of the variable-temperature magnetic susceptibility using an expression deduced from free-ion approximation and molecular field theory suggests the existence of a weak antiferromagnetic coupling between the samarium ions.

Graphical Abstract

A novel one-dimensional samarium polymer containing alternating eight- and nine-coordinate Sm(III) ions has been generated by incorporating benzoic acid in three different binding modes in its deprotonated state.

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References

  1. Chen C, Zhang SY, Song HB, Shi W, Zhao B, Cheng P (2009) Inorg Chim Acta 362:2749

    Article  CAS  Google Scholar 

  2. Dong YB, Wang P, Ma JP, Zhao XX, Wang HY, Tang B, Huang RQ (2007) J Am Chem Soc 129:4872

    Article  CAS  Google Scholar 

  3. Li X, Wu XS, Sun HL, Xu LJ, Zi GF (2009) Inorg Chim Acta 362:2837

    Article  CAS  Google Scholar 

  4. Li Y, Zheng FK, Liu X, Zou WQ, Guo GC, Lu CZ, Huang JS (2006) Inorg Chem 45:6308

    Article  CAS  Google Scholar 

  5. Lin PH, Burchell TJ, Ungur L, Chibotaru LF, Wernsdorfer W, Murugesu M (2009) Angew Chem Int Ed 48:9489

    Article  CAS  Google Scholar 

  6. Yan PF, Zhang FM, Li GM, Zhang JW, Sun WB, Suda M, Einaga Y (2009) J Solid State Chem 182:1685

    Article  CAS  Google Scholar 

  7. Che TL, Gao QC, Zhang WP, Nan ZX, Li HX, Cai YG, Zhao JS (2009) Koord Khim 35:723

    CAS  Google Scholar 

  8. Zheng SL, Yang JH, Yu XL, Chen XM, Wong WT (2004) Inorg Chem 43:830

    Article  CAS  Google Scholar 

  9. Chen ZL, Jiang CF, Yan WH, Liang FP, Batten SR (2009) Inorg Chem 48:4674

    Article  CAS  Google Scholar 

  10. Wang XL, Qin C, Wang EB, Su ZM (2006) Chem Eur J 12:2680

    Article  CAS  Google Scholar 

  11. Rueff JM, Masciocchi N, Rabu P, Sironi A, Skoulios A (2001) Eur J Inorg Chem 2001:2843

    Article  Google Scholar 

  12. Zhou Y, Yuan D, Jiang F, Xu Y, Hong M (2006) J Mol Struct 796:203

    Article  CAS  Google Scholar 

  13. Ren N, Zhang JJ, Xu SL, Wang RF, Wang SP (2005) Thermochim Acta 438:172

    Article  CAS  Google Scholar 

  14. Contaldi S, Di Nicola C, Garau F, Karabach YY, Martins LMDRS, Monari M, Pandolfo L, Pettinari C, Pombeiro AJL (2009) Dalton Trans 4928

  15. Khanra S, Weyhermüller T, Bill E, Chaudhuri P (2006) Inorg Chem 45:5911

    Article  CAS  Google Scholar 

  16. Taylor MD, Carter CP, Wynter CI (1968) J Inorg Nucl Chem 30:1503

    Article  CAS  Google Scholar 

  17. Sheldrick GM (1997) SHELXS-97, program for crystal structure solution. University of Göttingen, Germany

    Google Scholar 

  18. Sheldrick GM (1997) SHELXL-97, program for crystal structure refinement. University of Göttingen, Germany

    Google Scholar 

  19. Singh UP, Kumar R, Upreti S (2007) J Mol Struct 831:97

    Article  CAS  Google Scholar 

  20. Lu ZD, Wen LL, Yao J, Zhu HZ, Meng QJ (2006) CrystEngComm 8:847

    Article  CAS  Google Scholar 

  21. Andruh M, Bakalbassis E, Kahn O, Trombe JC, Porcher P (1993) Inorg Chem 32:1616

    Article  CAS  Google Scholar 

  22. Wang Y, Li XL, Wang TW, Song Y, You XZ (2010) Inorg Chem 49:969

    Article  CAS  Google Scholar 

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Acknowledgments

We thank the Changchun Institute of Applied Chemistry (Start-up) and the National Natural Science Foundation of China (Grants 20871113 and 20921002) for their financial support.

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Authors and Affiliations

  1. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, 130022, China

    Shuang-Yan Lin & Gui-Xia Liu

  2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

    Shuang-Yan Lin, Lang Zhao, Gong-Feng Xu, Yun-Nan Guo & Jinkui Tang

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  1. Shuang-Yan Lin
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  2. Lang Zhao
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  3. Gong-Feng Xu
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  4. Yun-Nan Guo
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  5. Gui-Xia Liu
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  6. Jinkui Tang
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Correspondence to Gui-Xia Liu or Jinkui Tang.

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Lin, SY., Zhao, L., Xu, GF. et al. Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer. J Chem Crystallogr 41, 77–81 (2011). https://doi.org/10.1007/s10870-010-9842-3

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  • DOI: https://doi.org/10.1007/s10870-010-9842-3

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