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Synthesis, Spectroscopic Studies and X-ray Analysis of (E)-2-(2-Fluorophenyl)-3-(6-Nitrobenzo[d][1,3]dioxol-5-yl) Acrylic Acid

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Abstract

In the solid-state structure of the title compound, C16H10FNO6, the configuration about the C=C double bond is E. The compound crystallized in the triclinic system, having space group P-1 with unit cell dimensions a = 5.829(10) Å, b = 8.801(16) Å, c = 13.543(3) Å, α = 87.753(15)°, β = 81.945(15)°, γ = 86.342(14)°. The structure of the molecule is V-shaped and in the crystal the molecules are linked to form inversion dimers connected by pairs of C–H···O hydrogen bonds.

Index Abstract

The compound, C16H10FNO6, has been prepared and analyzed by analytical techniques like FTIR, NMR and X-ray crystallography. The crystal structure of title compounds have a triclinic system with E configuration about the C=C double bond. The molecules are connected by pairs of C–H···O hydrogen bonds.

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Authors and Affiliations

  1. Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320, Pakistan

    Mukhtiar Hussain, Muhammad Hanif & Saqib Ali

  2. Institute of Physics, University of Neuchâtel, Rue Emile-Argand 11, CH-2009, Neuchâtel, Switzerland

    Muhammad Altaf & Helen Stoeckli-Evans

Authors
  1. Mukhtiar Hussain
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  2. Muhammad Hanif
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  3. Muhammad Altaf
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  4. Saqib Ali
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  5. Helen Stoeckli-Evans
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Correspondence to Saqib Ali.

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Hussain, M., Hanif, M., Altaf, M. et al. Synthesis, Spectroscopic Studies and X-ray Analysis of (E)-2-(2-Fluorophenyl)-3-(6-Nitrobenzo[d][1,3]dioxol-5-yl) Acrylic Acid. J Chem Crystallogr 41, 30–33 (2011). https://doi.org/10.1007/s10870-010-9830-7

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  • DOI: https://doi.org/10.1007/s10870-010-9830-7

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