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Synthesis and Crystal Structure of a Novel Supramolecular Complex: [Co(2-Me-3,4-qudc)(Phen)2(H2O)]·4.5H2O

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Abstract

A novel 3D supramolecular complex, [Co(2-Me-3,4-qudc)(Phen)2(H2O)] 4.5H2O (2-Me-3,4-qudc = 2-methylquinoline-3,4-dicarboxylate dianion, phen = 1,10-phenanthroline), has been synthesized under mild condition and characterized by elemental analyses, IR spectrum, thermogravimetric analysis and single-crystal X-ray diffraction. The complex crystallizes in the monoclinic space group P2(1) /n with unit cell parameters a = 13.1701(12) Å, b = 18.6728(19) Å, c = 15.0683(16) Å, β = 13.617(2), V = 3395.3(6) Å3, Z = 4. The 3D framework of the title compound is formed via O–H⋯O hydrogen-bonds and π–π stacking interactions. The lattice waters are stable at room temperature, but when thermally decomposed, the water loss is irreversible.

Graphical Abstract

A novel supramolecular complex [Co(2-Me-3,4-qudc)(Phen)2(H2O)]·4.5H2O have been synthesized and characterized.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (20761002), PR China, the Natural Science Foundation of Guangxi (0832080), PR China.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, 530004, People’s Republic of China

    Hu-Jun Hao & Cui-Wu Lin

  2. College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning, 530006, People’s Republic of China

    Hu-Jun Hao, Xian-Hong Yin, Feng Zhang, Zhi-Rong Luo & Qiao-Lan Wu

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  1. Hu-Jun Hao
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  2. Xian-Hong Yin
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  3. Cui-Wu Lin
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  4. Feng Zhang
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Correspondence to Cui-Wu Lin.

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Hao, HJ., Yin, XH., Lin, CW. et al. Synthesis and Crystal Structure of a Novel Supramolecular Complex: [Co(2-Me-3,4-qudc)(Phen)2(H2O)]·4.5H2O. J Chem Crystallogr 41, 26–29 (2011). https://doi.org/10.1007/s10870-010-9827-2

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  • DOI: https://doi.org/10.1007/s10870-010-9827-2

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