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Synthesis and Crystal Structures of Two Novel Complexes with N-[2-(5-Bromo-2-Hydroxybenzylideneamino)Ethyl]-4-Methylbenzenesulfonamide as Ligand

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Abstract

Two novel complexes constructed from the sulfonamide Schiff base ligand H 2 L, N-[2-(5-bromo-2-hydroxybenzylideneamino)ethyl]-4-methylbenzene-sulfonamide, [Cu(HL)2] (1) and [CuL(H2O)] (2) are synthesized and characterized via X-ray single-crystal diffraction, elemental analysis, FT-IR and UV–Vis. 1 and 2 both form 1-D supramolecular architectures by π–π stacking interactions. 1 and 2 both crystallize in monoclinic, with space group C2/c and P2/c for 1 and 2, with unit cell parameters a = 27.640(18) Å, b = 7.907(5) Å, c = 17.945(14) Å, β = 118.27(2)°, V = 3454(4) Å3, Z = 4 for 1, and a = 16.758(5) Å, b = 7.272(2) Å, c = 15.080(4) Å, β = 106.334(5)°, V = 1763.6(9) Å3, Z = 4 for 2.

Graphical Abstract

Two novel Cu(II) sulfonamide Schiff base complexes were prepared and characterized.

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Acknowledgments

This work was supported by the Natural Science Foundation of Shaanxi Province (Program No. 2009JQ2003) and Fundamental Research Funds for the Central Universities (Program No. GK200902011).

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Authors and Affiliations

  1. Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an, 710062, Shaanxi, People’s Republic of China

    Shu-Ni Li, Quan-Guo Zhai, Man-Cheng Hu & Yu-Cheng Jiang

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  1. Shu-Ni Li
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  2. Quan-Guo Zhai
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Correspondence to Shu-Ni Li.

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Li, SN., Zhai, QG., Hu, MC. et al. Synthesis and Crystal Structures of Two Novel Complexes with N-[2-(5-Bromo-2-Hydroxybenzylideneamino)Ethyl]-4-Methylbenzenesulfonamide as Ligand. J Chem Crystallogr 41, 12–16 (2011). https://doi.org/10.1007/s10870-010-9825-4

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