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Journal of Chemical Crystallography

, Volume 40, Issue 4, pp 391–395 | Cite as

Crystal Structure of Diethyl[(4chlorophenyl)(dibenzylamino)methyl]propanedioate

  • I. Meskini
  • L. Toupet
  • M. Akkurt
  • M. Daoudi
  • A. Kerbal
  • Z. H. Chohan
  • T. Ben Hadda
Communication

Abstract

The titled new functionalized N,O,O-ligand of type diethyl[(4-chlorophenyl)(dibenzylamino)methyl]propanedioate (4) is prepared in good yield through condensation of dibenzylamine, with 2-arylidene-malonic acid diethyl esters 3. The structure of 4 was determined by spectral (IR, 1H NMR), elemental analyses and X-ray diffraction data. The molecular conformation shows two possible pockets ready to coordinate two metal atoms.

Graphical Abstract

The structure of compound was determined by spectral (IR, 1H NMR), elemental analyses and X-ray diffraction data. The molecular conformation shows two possible pockets ready to coordinate two metal atoms.

Keywords

N,O,O-ligand β-Amino dicarbonyl Malonate Michael reaction Mechanism study 

Notes

Acknowledgements

This work was supported by grants from Project PGR-UMP-BH-2005 and the Centre National de Recherche Scientifique, Université de Rennes 1 (France).

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • I. Meskini
    • 1
  • L. Toupet
    • 2
  • M. Akkurt
    • 5
  • M. Daoudi
    • 1
  • A. Kerbal
    • 1
  • Z. H. Chohan
    • 3
  • T. Ben Hadda
    • 4
  1. 1.Laboratoire de Chimie OrganiqueUniversité Sidi Mohammed Ben AbdellahFèsMorocco
  2. 2.Institut de Physique - IPR - UMR CNRS 6251, Université de Rennes 1RennesFrance
  3. 3.Department of ChemistryBahauddin Zakariya UniversityMultanPakistan
  4. 4.Laboratoire de Chimie des MatériauxUniversité Med. 1ierOujdaMorocco
  5. 5.Department of Physics, Faculty of Arts and SciencesErciyes UniversityKayseriTurkey

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