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Study of Hydrogen Bonding in N′-(4,6-disubstituted-pyrimidin-2-yl)-N-[2-(2,4-dichlorophenoxypropionyl)]thiourea

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Abstract

Two of N′-N′-(4,6-disubstituted-pyrimidin-2-yl)-N-[2-(2,4-dichlorophenoxypropionyl)]thiourea (4a-4b) had been synthesized and their crystal structures had been determined by X-ray diffraction method. 4a crystallizes in the triclinic space group P-1, with a = 8.053(12) Å, α = 102.84(2)°, b = 10.541(16) Å, β = 106.99(2)°, c = 12.461(19) Å, γ = 94.615(19)°, and D c  = 1.470 mg/m3 for Z = 2. 4b crystallizes in the triclinic space group P-1, with a = 7.939(5) Å, α = 105.302(10)°, b = 10.183(7) Å, β = 105.729(9)°, c = 12.764(9) Å, γ = 90.698(11)°, and D c  = 1.517 mg/m3 for Z = 2.

Graphical Abstract

Two pyrimidine derivatives were synthesized and the crystal structures were determined by X-ray diffraction.

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Acknowledgments

We are grateful to China National Natural Science Foundation (No. 20543007), Shanghai Leading Academic Discipline Project (projects No. S30406, 08YZ71 and DZL807) for financial support and the Shanghai Branch of National Pesticide R&D South Center for the preliminary Biological Test.

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Authors and Affiliations

  1. Department of Chemistry, College of Life and Environmental Science, Shanghai Normal University, 200234, Shanghai, People’s Republic of China

    Guo-Hua Liu, Chuan-Shou Sun, Yun-Ning Xue, Mei Yao & Han Yu

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  1. Guo-Hua Liu
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  2. Chuan-Shou Sun
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Correspondence to Guo-Hua Liu.

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Liu, GH., Sun, CS., Xue, YN. et al. Study of Hydrogen Bonding in N′-(4,6-disubstituted-pyrimidin-2-yl)-N-[2-(2,4-dichlorophenoxypropionyl)]thiourea. J Chem Crystallogr 40, 675–680 (2010). https://doi.org/10.1007/s10870-010-9719-5

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