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Journal of Chemical Crystallography

, Volume 39, Issue 9, pp 688–691 | Cite as

Synthesis, Structure and Luminescent Property of a Novel Lanthanide Metal-Organic Coordination Polymer Yb3(BDC)4.5(DMF)2(H2O)3 · (DMF)2

  • Liyan Na
  • Ruinian Hua
  • Liying Zhang
  • Wei Zhang
  • Guiling Ning
COMMUNICATION

Abstract

A three-dimensional lanthanide metal-organic coordination polymer Yb3(BDC)4.5(DMF)2(H2O)3 · (DMF)2 has been synthesized by the reaction of the lanthanide metal ion (Yb3+) with 1,4-benzenedicarboxylic acid (H2BDC) under mild condition. The compound crystallizes in the triclinic system, space group PI with unit cell parameters a = 10.7428(9) Å, b = 11.2786(9) Å, c = 26.172(2) Å, α = 85.060(2)°, β = 88.1060(10)°, γ = 62.3670(10)°, V = 2798.9 (4) Å3, Z = 2. The crystal structure exhibits one-dimensional channels along the [011] direction. The fluorescent results showed that there were two emission peaks at 375 and 420 nm when the compound was excited by a 235 nm excitation.

Graphical Abstract

The preparation, X-ray structure and luminescent property are presented for a new lanthanide metal-organic coordination polymer Yb3(BDC)4.5(DMF)2(H2O)3 · (DMF)2.

Keywords

Metal-organic coordination polymer Lanthanide Crystal structure Luminescent property 

Notes

Acknowledgments

The authors are grateful to the National Natural Science Foundation of China (No. 20376009) for financial support of this work.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Liyan Na
    • 1
    • 2
  • Ruinian Hua
    • 2
  • Liying Zhang
    • 2
  • Wei Zhang
    • 2
  • Guiling Ning
    • 1
  1. 1.State Key Laboratory of Fine ChemicalsDalian University of TechnologyDalianChina
  2. 2.College of Life ScienceDalian Nationalities UniversityDalianChina

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