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Crystal Structure of Antitubercular Complex: cis-(chloro)-[N,N′-bis-(diethyl-2,2′-bipyridine-3,3′-dicarboxylate)]ruthenium(II) Monohydrate

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Abstract

Diethyl-2,2′-bipyridine-3,3′-dicarboxylate (3 or L) reacts with RuCl3 · 3H2O to give cis-(Cl)-[Ru(L)2Cl2] · H2O (4) and structure of the complex was determined by spectral (IR, 1H-NMR), and mass spectroscopic data, elemental analyses and X-ray crystallography. The structure is solved in triclinic, space group p-1 with a = 10.658 (2), b = 12.446 (3), c = 14.186 (5) Å, α = 104.856 (3), β = 108.704 (3), γ = 94.973 (2)°, V = 1693.2 (8) Å3, Z = 2 with final R = 0.012. The geometry of the complex is shown to be a distorted octahedral with four nitrogens of two 2,2′-bipyridyl ligands in two different planes with Ru–N distance as 2.021 (2)−2.071 (3) Å. The cis-position is occupied by two chloride atoms with Ru–Cl distance as 2.4156 (12) and 2.4167 (13) Å. The trans-axial Cl2–Ru1–N and Cl1–Ru1–N4 angles are respectively, 172.42 (7) and 174.12 (7)°. A weak hydrogen bonding is observed between the two chlorides and hydrogens of neighbouring molecule [C–H···Cl distance as 2.72, 2.77 (4) Å]. A second type of weak hydrogen bonding is also observed between the oxygens of carboxylate groups and hydrogens of a neighbouring molecule [C–H···O distance as 2.53, 2.56 and 2.34 (4) Å].

Graphical Abstract

The structure of anti-tubercular precursor complexes, cis-(chloro)-[N,N′-bis-(diethyl-2,2′-bipyridine-3,3′-dicarboxylate)]ruthenium(II) monohydrate is solved by single crystal X-ray diffraction analysis which reveals geometry of the complex to be a distorted octahedral with four nitrogens of two 2,2′-bipyridyl ligands in two different planes. The cis-position is occupied by two chloride atoms.

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Acknowledgments

N. Sam and M. Daoudi are grateful to the ‘Projet Globale de Recherche de l’Université Mohammed Premier’ and ‘PROTARS I’ project for financial support.

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Authors and Affiliations

  1. Laboratoire de Chimie de Coordination et Catalyse (CNRS UMR 6509), Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France

    Loic Toupet & Pierre H. Dixneuf

  2. Department of Physics, F.A.S, Erciyes University, 38039, Kayseri, Turkey

    Mehmet Akkurt

  3. Laboratoire de Chimie Organique, Faculté des Sciences Dhar El Mehraz, 30000, Fez, Morocco

    Maria Daoudi & Abdelali Kerbal

  4. Laboratoire de Chimie des Matériaux, Faculté des Sciences, 60000, Oujda, Morocco

    Najat Sam & Taibi Ben Hadda

  5. Department of Chemistry, Bahauddin Zakariya University, Multan, Pakistan

    Zahid H. Chohan

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  1. Loic Toupet
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  2. Pierre H. Dixneuf
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  3. Mehmet Akkurt
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  4. Maria Daoudi
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  5. Najat Sam
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  6. Abdelali Kerbal
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  7. Zahid H. Chohan
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  8. Taibi Ben Hadda
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Correspondence to Zahid H. Chohan.

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Toupet, L., Dixneuf, P.H., Akkurt, M. et al. Crystal Structure of Antitubercular Complex: cis-(chloro)-[N,N′-bis-(diethyl-2,2′-bipyridine-3,3′-dicarboxylate)]ruthenium(II) Monohydrate. J Chem Crystallogr 39, 423–427 (2009). https://doi.org/10.1007/s10870-008-9495-7

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  • DOI: https://doi.org/10.1007/s10870-008-9495-7

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