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Journal of Chemical Crystallography

, Volume 39, Issue 6, pp 395–398 | Cite as

Structural Conformation of a Novel 1-Benzhydrylpiperazine Derivative: 1-Benzhydryl-4-(toluene-4-sulfonyl)-piperazine

  • S. Naveen
  • C. S. Ananda Kumar
  • S. B. Benaka Prasad
  • K. Vinaya
  • M. A. Sridhar
  • J. Shashidhara Prasad
  • K. S. Rangappa
Original Paper

Abstract

The title compound 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine was synthesized and the structure was investigated by X-ray crystallography. The title compound, C24H26N2O2S crystallizes in the monoclinic crystal class in the space group P21/c with cell parameters a = 13.5800(10) Å, b = 8.9630(7) Å, c = 18.9040(10) Å, β = 106.851(3)°, Z = 4 and V = 2202.1(3) Å3. The structure has been solved by direct methods and refined to R 1 = 0.0468 for 3174 observed reflections I > 2σ(I). The structure reveals that the piperazine ring is in a chair conformation. The geometry around the S atom is a distorted tetrahedron.

Graphical Abstract

The title compound 1-benzhydryl-4-(toluene-4-sulfonyl)-piperazine was synthesized and the structure was investigated by X-ray crystallography. The title compound, C24H26N2O2S crystallizes in the monoclinic crystal class in the space group P21/c with cell parameters a = 13.5800(10) Å, b = 8.9630(7) Å, c = 18.9040(10) Å, β = 106.851(3)°, Z = 4 and V = 2202.1(3) Å3. The structure has been solved by direct methods and refined to R 1 = 0.0468 for 3174 observed reflections I > 2σ(I). The structure reveals that the piperazine ring is in a chair conformation. The geometry around the S atom is a distorted tetrahedron.

Keywords

Benzhydrylpiperazine Sulfonyl chloride Crystal structure Tetrahedral configuration 

Notes

Acknowledgements

The authors are grateful to Department of Science and Technology and Government of India for financial assistance under the projects SP/I2/FOO/93 and UGC-SAP(Phase-I)No.F.540/10/DRS/2004(SAP-I). One of the author K. Vinaya, would like to thank CSIR, Government of India for the award of Senior Research Fellowship.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • S. Naveen
    • 1
  • C. S. Ananda Kumar
    • 2
  • S. B. Benaka Prasad
    • 2
  • K. Vinaya
    • 2
  • M. A. Sridhar
    • 1
  • J. Shashidhara Prasad
    • 1
  • K. S. Rangappa
    • 2
  1. 1.Department of Studies in Physics, ManasagangotriUniversity of MysoreMysoreIndia
  2. 2.Department of Studies in ChemistryUniversity of MysoreMysoreIndia

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