Abstract
Hydrated cadmium perchlorate reacted with sodium azide and 2,2′-bypyridine-3,3′-diol (H2L) in ethanol solution and resulted in the formation of a two-dimensional coordination polymer: [Cd(μ-N3)(μ-HL)(H2O)]n. The complex has been characterized by elemental analysis and IR spectrum, and its crystal structure determined by X-ray crystallography and the complex crystallizes in the monoclinic system with space group P21/c and a = 7.2849(14), b = 9.9568(19), c = 17.058(3) Ǻ, β = 102.254(2)°. In the complex both azide anion and monodepronated 2,2′-bypyridine-3,3′-diol anion (HL) act as bridge ligands and led to the formation of a two-dimensional sheet structure on (100) plane, and the O–H⋯N hydrogen bond made the sheets pile up along [100] direction, which forms a supramolecular three-dimensional structure.
Graphical Abstract
The title two-dimensional Cd(II) coordination polymer was synthesized by cadmium perchlorate, sodium azide and 2,2′-bypyridine-3,3′-diol and its crystal structure determined. Single crystal X-ray diffraction analysis reveals that the two-dimensional coordination polymer was fabricated with azide anion and monodeprotonated 2,2′-bypyridine-3,3′-diol as mixed bridge ligands.
Similar content being viewed by others
References
Villanueva M, Mesa JL, Urtiaga MK, Corte’s R, Lezama L, Arriortua MI, Rojo T (2001) Eur J Inorg Chem 1581
Ruiz E, Cano J, Alvarez S, Alenany P (1998) J Am Chem Soc 120:11122
Goher MAS, Cano J, Journaux Y, Abu-Youssef MAM, Mautner FA, Escuer A, Vicente R (2000) Chem Eur J 6:778
Triki S, Gomez-Garcia CJ, Ruiz E, Sala-Pala J (2005) Inorg Chem 44:5501
Abu-Youssef MAM (2005) J Coord Chem 58:1377
He X, Lu C-Z (2004) Anorg Allg Chem 630:2583
Thompson AMWC, Jeffery JC, Liard DJ, Ward MD (1996) J Chem Soc, Dalton Trans 879
Stephenson MD, Hardie MJ (2007) Cryst Eng Commun 9:496
Mainz GH, Kelsterbach PG (2002) US Patent 6,500,956 B1
Sheldrick GM (1996) SADABS, version 2.10. University of Göttingen, Germany
Bruker (2001) SHELXTL, version 6.12. Bruker AXS Inc., Madison, Wisconsin, USA
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, JM. Synthesis and Crystal Structure a Two-Dimensional Coordination Polymer: [Cd(μ-N3)(μ-HL)(H2O)]n [HL = Monodeprotonated 2,2′-bypyridine-3,3′-diol]. J Chem Crystallogr 39, 143–146 (2009). https://doi.org/10.1007/s10870-008-9444-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10870-008-9444-5