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Journal of Chemical Crystallography

, Volume 38, Issue 4, pp 239–242 | Cite as

Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

  • Kathryn L. Seward
  • Joseph M. Ellsworth
  • Mark D. Smith
  • Hans-Conrad zur Loye
Original Paper

Abstract

A novel three-dimensional coordination polymer [Ni(pca)2(H2O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl2·(H2O)6 with pcaH (pcaH = 2-pyrazinecarboxcylic acid). Complex 1 contains one-dimensional zigzag chains that are H-bonded to adjacent chains, generating a three-dimensional network that crystallizes in the P212121 space group, and is isostructural with a previous structure containing Co (Liang et al. Inorg Chim Acta 328:152–158, 2002). In structure 1, a = 7.79(6), b = 9.90(8), and c = 14.90(12) Å.

Graphical Abstract

Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

Kathryn L. Seward, Joseph M. Ellsworth, Mark D. Smith, Hans-Conrad zur Loye

A novel three-dimensional coordination polymer [Ni(pca)2(H2O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl2·(H2O)6 with pcaH (pcaH = 2-pyrazinecarboxcylic acid) and characterized by single crystal X-ray diffraction
.

Keywords

Solvothermal synthesis Coordination polymer Pyrazinecarboxylic acid 

Notes

Acknowledgements

Financial support from the National Science Foundation through Grant CHE-0714439 and the University of South Carolina Nano center is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Kathryn L. Seward
    • 1
  • Joseph M. Ellsworth
    • 1
  • Mark D. Smith
    • 1
  • Hans-Conrad zur Loye
    • 1
  1. 1.Department of Chemistry and BiochemistryUniversity of South CarolinaColumbiaUSA

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