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Journal of Chemical Crystallography

, Volume 37, Issue 7, pp 497–502 | Cite as

A Novel Three Dimensional Organic–Inorganic Hybrid Based Porous Phase: Synthesis and Characterization of Reduced Oxovanadium pyromellitate, [VIV 2O2(H2O)2(C6H2(COO)4)]

  • Sabri Cevik
  • Mehmet Poyraz
  • Musa Sarı
  • Orhan Büyükgüngör
Original Research

Abstract

The hydrothermal reaction of a mixture of VOSO· xH2O, 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) and 0.1 M H2SO4 for 72 h at 160 °C gives blue needle like crystals of [VIV 2O2(H2O)2(C6H2(COO)4)] in 30% yield. The compound has a porous 3-D extended network structure having a rigid architecture which is held together by the multidentate functionalities of 1,2,4,5-benzenetetracarboxylate ligand. Crystal data for the compound: monoclinic space group C 2/c (No:15), a = 11.756(5) Å, b = 9.645(3) Å, c = 11.822(7) Å, β = 107.10(4)°, Z = 8. The compound constitutes the first example of a fully reduced oxovanadium based solid incorporating the organic ligand. This article consists of synthesis, crystal structure and characterization of [VIV 2O2(H2O)2(C6H2(COO)4)].

Keywords

Organic–inorganic hybrid composites Synthesis and design Hydrothermal synthesis Pyromellitate Reduced oxovanadium Structure and characterization 

Notes

Acknowledgment

This work was partly supported by grants from Afyon Kocatepe University (BAPK-FEF2005-0042) and Turkish State Planning Organization (DPT-2005 K-12060). In addition, the authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS-2 diffractometer purchased under grant F.279 of the University Research Fund.

References

  1. 1.
    Mallouk TE, Lee HJ (1990) Chem Educ 67:829CrossRefGoogle Scholar
  2. 2.
    Kahn O, Pei Y, Journaux Y (1992) In: Bruce DW, O’Hare D (eds) Inorganic materials. John Wiley & Sons, New York, p 59Google Scholar
  3. 3.
    Suib SL (1993) Chem Rev 93:803CrossRefGoogle Scholar
  4. 4.
    Haushalter RC, Meyer LM, Zubieta J (1995) In: Chisholm MH (ed) Early transition metal clusters with-donor ligands. VCH, New York, p 217Google Scholar
  5. 5.
    Basolo F, Johnson RC (1986) Coordination Chemistry. Science Reviews. NorthwoodGoogle Scholar
  6. 6.
    Reddy KM, Moudrakovski I, Sayari A (1994) Chem Commun J Chem Soc 1059Google Scholar
  7. 7.
    Sen T, Rajamohanan PR, Sivasanker S (1996) J Catal 163:354CrossRefGoogle Scholar
  8. 8.
    Hennig H (1999) Coord Chem Rev 182:101CrossRefGoogle Scholar
  9. 9.
    LaDuca RL, Brodkin C, Finn RC, Zubieta (2000) J Inorg Chem Commun 248Google Scholar
  10. 10.
    Khan MI, Deb S, Doedens RJ (2006) Inorg Chem Commun 9:25CrossRefGoogle Scholar
  11. 11.
    Barthelet K, Adil K, Millange F, Serre C, Riou D, Ferey G (2003) J Mater Chem 13:2208CrossRefGoogle Scholar
  12. 12.
    Cheetham AK, Ferey G, Loiseau T (1999) Angew Chem Int Ed 22:3269Google Scholar
  13. 13.
    Davis ME (2002) Nature 417:813CrossRefGoogle Scholar
  14. 14.
    Ferey G (2001) Chem Mater 13:3084CrossRefGoogle Scholar
  15. 15.
    Konar S, Mukherjee PS, Drew MGB, Ribas J, Ray Chaudhuri N (2003) Inorg Chem 42:2545CrossRefGoogle Scholar
  16. 16.
    (a) Rowsell JLC, Millward AR, Park KS, Yaghi OM (2004) J Am Chem Soc 126:5666. (b) Millward AR, Yaghi OM (2005) J Am Chem Soc 127:17998. (c) Li H, Eddaoudi M, Groy TL, Yaghi OM (1998) J Am Chem Soc 120:8571. (d) Li H, Davis CE, Groy TL, Kelley DG, Yaghi OM (1998) J Am Chem Soc 120:2186. (e) Eddaoudi M, Kim J, O’Keeffe M, Yaghi OM (2002) J Am Chem Soc 124:376. (f) Eddaoudi M, Li H, Yaghi OM (2000) J Am Chem Soc 122:1391. (g) Kim J, Chen B, Reineke TM, Li H, Eddaoudi M, Moler DB, O’Keeffe M, Yaghi OM (2001) J Am Chem Soc 123:8239. (h) Yaghi OM, Davis CE, Li G, Li H (1997) J Am Chem Soc 119:2861. (i) Barton TJ, Bull LM, Klemperer WG, Loy DA, McEnaney B, Misono M, Monson PA, Pez G, Scherer GW, Vartuli JC, Yaghi OM (1999) Chem Mater 11:2633. (j) Braun ME, Steffek CD, Kim J, Rasmussen PG, Yaghi OM (2001) Chem Commun 24:2532Google Scholar
  17. 17.
    Si SF, Wang RJ, Li YD (2003) Inorg Chem Commun 6:1151 Google Scholar
  18. 18.
    Evans OR, Lin WB (2000) Inorg Chem 39:2189CrossRefGoogle Scholar
  19. 19.
    Rabu P, Janvier P, Bujoli B (1999) J Mater Chem 1323Google Scholar
  20. 20.
    Soghomonian V, Haushalter RC, Zubieta J (1995) Chem Mater. 7:1648CrossRefGoogle Scholar
  21. 21.
    Klemperer WG (1990) Inorg Synth 27:71CrossRefGoogle Scholar
  22. 22.
    Stoe & Cie (2002) X-AREA (Version 1.18) and X-RED32 (Version 1.04). Stoe & Cie, Darmstadt, GermanyGoogle Scholar
  23. 23.
    Sheldrick GM (1997) SHELXS97 and SHELXL97, Program for crystal structure refinement. University of Gottingen, GermanyGoogle Scholar
  24. 24.
    Farrugia LJ (1997) J Appl Cryst. 30:565CrossRefGoogle Scholar
  25. 25.
    Spek AL (1999) PLATON99. University of Utrecht, The Netherlands Google Scholar
  26. 26.
    Fuess H, Hahn T, Wondratschek H, Muller U, Shmueli U, Prince E, Authier A, Kopsky V, Litvin DB, Rossmann MG, Arnold E, Hall S, McMahon B (Eds.) (1995) International Tables for Crystallography. Kluwer, Boston, vol C, Tables 6.1.1.4, 4.2.6.8, and 4.2.4.2Google Scholar
  27. 27.
    Brown ID (1981) In: O’Keefe M, Navrotdky A (eds) Structure and bonding in crystals, vol II. Academic Press, New YorkGoogle Scholar
  28. 28.
    Mehrotra RC, Bohra R (1978) Metal carboxylates. Academic Press, LondonGoogle Scholar
  29. 29.
    Hagrman D, Hammond RP, Haushalter R, Zubieta J (1998) Chem Mater 10:2091CrossRefGoogle Scholar
  30. 30.
    Hoskins BF, Robson R (1990) J Am Chem Soc 112:1546CrossRefGoogle Scholar
  31. 31.
    Ermer O (1991) Adv Mater 3, 608CrossRefGoogle Scholar
  32. 32.
    Lehn JM (1988) Angew Chem Chem Int Ed Engl 27:90Google Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Sabri Cevik
    • 1
  • Mehmet Poyraz
    • 1
  • Musa Sarı
    • 2
  • Orhan Büyükgüngör
    • 3
  1. 1.Department of Chemistry, Science and Literature FacultyAfyon Kocatepe UniversityAfyonkarahisarTurkey
  2. 2.Education Faculty, Department of Physics EducationGazi UniversityBesevler-AnkaraTurkey
  3. 3.Department of Physics, Science and Literature FacultyOndokuz Mayıs UniversityKurupelit-SamsunTurkey

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