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Journal of Chemical Crystallography

, Volume 36, Issue 10, pp 627–630 | Cite as

Triethyl ammonium salt of O,O′-bis(p-tolyl)dithiophosphate, [Et3NH]+[(4-MeC6H4O)2PS2]

  • A. L. Bingham
  • J. E. Drake
  • C. Gurnani
  • M. B. Hursthouse
  • M. E. Light
  • M. Nirwan
  • R. Ratnani
Article

Triethyl ammonium Salt of O,O′-bis(p-tolyl)dithiophosphate and O,O′-bis(m-tolyl)dithiophosphate have been obtained by reaction of p- and m-cresol, respectively with P2S5 in toluene and have been characterized by elemental analysis, IR, 1H and 31P NMR spectroscopy. The molecular structure of O,O′-bis(p-tolyl)dithiophosphate has been determined. Crystal data: [Et3NH]+[(4-MeC6H4O)2PS2]: Monoclinic, P21/c, a=15.2441(9) Å, b=10.415(2) Å, c=3.9726(9) Å, β=91.709(7)°, V=2217.5(1) Å−3, Z=4.

KEY WORDS:

Synthesis p-cresol o-cresol tolyl dithiophosphate NMR X-ray analysis 

Notes

Acknowledgment

M.N. thanks the CSIR, New Delhi for financial support. M.B.H. thanks the UK Engineering and Physical Sciences Council for support of the X-ray facilities at Southampton University. J.E.D. thanks the University of Windsor for financial support.

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • A. L. Bingham
    • 1
  • J. E. Drake
    • 2
  • C. Gurnani
    • 3
  • M. B. Hursthouse
    • 1
  • M. E. Light
    • 1
  • M. Nirwan
    • 3
  • R. Ratnani
    • 3
  1. 1.Department of ChemistryUniversity of SouthamptonHighfieldUK
  2. 2.Department of Chemistry and BiochemistryUniversity of WindsorWindsorCanada
  3. 3.Department of Pure & Applied ChemistryM.D.S. UniversityAjmerIndia

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