Irisolidone (5,7-dihydroxy-6,4′-dimethoxyisoflavone) was isolated from the flowers of Pueraia lobata and its crystal structure was examined by X-ray single crystal diffraction. The crystal structure of irisolidone is monoclinic, space group P21/c with a = 15.491(9) Å, b = 7.895(4) Å, c = 13.321(7) Å, β = 110.546(9)° and Z = 4. Hydrogen bonding and aromatic π–π stacking assemble the title compound into a three-dimensional networking structure.
Similar content being viewed by others
References
Kim, T.J. Seoul National University Press: Seoul 1985; p 322.
Niiho, Y.; Yamazaki, T.; Nakajima, Y.; et al. Yakugaku Zasshi. 1989, 109(6), 424–431 (text in Japanese with English abstract).
Niiho, Y.; Yamazaki, T.; Nakajima, Y.; et al. Yakugaku Zasshi. 1990, 110(8), 604–611 (text in Japanese with English abstract).
Kim, D.H.; Yu, K.H.; Bae, E.A.; Han, M.J. Biol. Pharm. Bull. 1998, 21, 628–630.
Han, Y.O.; Han, M.J.; Park, S.H.; Kim, D.H. J. Pharmacol. Sci. 2003, 93, 331–336.
Yamazaki, T.; Nakajima, Y.; Niho, Y.; Hosono, T.; Kurashige, T.; Kinjo, J.; Nohara, T. J. Pharm. Pharmacol. 1997, 49(8), 831–833.
Yamazaki, T.; Hosono, T.; Matsushita, Y.; Kawashima, K.; Someya, M.; Nakajima, Y.; Narui, K.; Hibi, Y.; Ishizaki, M.; Kinjo, J.; Nohara, T. Int. J. Clin. Pharmacol. Res. 2002, 22(1), 23–28.
Bae, E.A.; Han, M.J.; Kim, D.H. Planta Med. 2001, 67, 161–163.
Zhang, Z.T.; Wang, X.B.; Liu, Q.G.; Zheng, J.B.; Yu, K.B. Cryst. Struct. Commun. 2005, 61, 29–31.
Zhang, Z.T.; Guo, Y.N.; Liu, Q.G. Chin. J. Chem. 2004, 22, 971–977.
Jiang, R.W.; Ye, W.C.; Woo, K.Y. J. Mol. Struct. 2002, 642, 77–84.
Janiak, C. J. Chem. Soc. Dalton Trans. 2000, 3885–3896.
Hunter, C.A.; Sanders, J.K. J. Am. Chem. Soc. 1990, 112, 5525–5534.
William, O.G.; Harbour, L.J.; Atwood, J.L. Science 1999, 285, 1049–1051.
Luque, A.; Sertucha, J.; Castillo, O.; Roman, P. New J. Chem. 2001, 1208–1214.
Kaafarani, B.R.; Pinkerton, A.A.; Neckers, B.C. Tetrahedron Lett. 2001, 42, 8137–8139.
Author information
Authors and Affiliations
Corresponding author
Additional information
Supplementary material
CCDC-267587 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html [or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033; email: deposit@ccdc.cam.ac.uk].
Rights and permissions
About this article
Cite this article
Zhang, ZT., Zhang, XL., Yang, BL. et al. Crystal structure of irisolidone from the flowers of Pueraia lobata . J Chem Crystallogr 36, 407–411 (2006). https://doi.org/10.1007/s10870-005-9033-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10870-005-9033-9