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Preparation of thermally stable nanocrystalline hydroxyapatite by hydrothermal method

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Abstract

Thermally stable hydroxyapatite (HAp) was synthesized by hydrothermal method in the presence of malic acid. X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FT-IR), Raman spectroscopy, scanning electron microscopy (SEM), differential thermal analysis (DTA), thermogravimetric analysis (TGA) was done on the synthesized powders. These analyses confirmed the sample to be free from impurities and other phases of calcium phosphates, and were of rhombus morphology along with nanosized particles. IR and Raman analyses indicated the adsorption of malic acid on HAp. Thermal stability of the synthesized HAp was confirmed by DTA and TGA. The synthesized powders were thermally stable upto 1,400°C and showed no phase change. The proposed method might be useful for producing thermally stable HAp which is a necessity for high temperature coating applications.

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Acknowledgment

The authors acknowledge the grant from Department of Science and Technology, New Delhi through Research Project No. SR/SO/HS-05/2005.

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Authors and Affiliations

  1. Crystal Growth Centre, Anna University, Chennai, 600025, Tamil Nadu, India

    S. Prakash Parthiban, K. Elayaraja, E. K. Girija & S. Narayana Kalkura

  2. Department of Intelligent Materials Engineering, Graduate School of Engineering, Osaka City University (OCU), Osaka, 558-8585, Japan

    Y. Yokogawa

  3. Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, Tamil Nadu, India

    R. Kesavamoorthy

  4. Department of Chemistry, Anna University, Chennai, 600025, Tamil Nadu, India

    M. Palanichamy

  5. Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi, 110067, India

    K. Asokan

Authors
  1. S. Prakash Parthiban
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  2. K. Elayaraja
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  3. E. K. Girija
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  4. Y. Yokogawa
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  5. R. Kesavamoorthy
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  6. M. Palanichamy
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  7. K. Asokan
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  8. S. Narayana Kalkura
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Correspondence to S. Narayana Kalkura.

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Prakash Parthiban, S., Elayaraja, K., Girija, E.K. et al. Preparation of thermally stable nanocrystalline hydroxyapatite by hydrothermal method. J Mater Sci: Mater Med 20 (Suppl 1), 77–83 (2009). https://doi.org/10.1007/s10856-008-3484-4

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  • DOI: https://doi.org/10.1007/s10856-008-3484-4

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