Synthesis and luminescence properties of red-emitting NaBaBi2(PO4)3:Eu3+ phosphors


In this study, a series of Eu3+-doped NaBaBi2(PO4)3 red phosphors were synthesized by high-temperature solid-phase reaction method, and the phase structure and photoluminescence properties of the samples were investigated in detail. All the diffraction peaks of the phosphors with various Eu3+ concentrations are well matched with the NaBaBi2(PO4)3 standard phase, indicating that Eu3+ ions have no effect on the host structure. Under the excitation of 391 nm wavelength, the emission spectra consisted of four characteristic emission peaks at 595, 617, 656 and 703 nm, respectively. The strongest emission peaking at 617 nm originates from the 5D0 → 7F2 electron transitions of Eu3+ ions. The optimum concentration of Eu3+ ions in NaBaBi2(PO4)3:Eu3+ is 9% concentration. The phosphor exhibits strong absorption capacity in the near-ultraviolet region. The Commission International de I’Eclairage chromaticity coordinates of the NaBaBi2(PO4)3:Eu3+ samples are located in the red region, indicating that the phosphors are suitable red component to applied in near-ultraviolet-based white light-emitting diodes.

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  1. 1.

    X. Ma, L. Liao, Q. Guo, H. Liu, D. Yang, N. Liu, L. Mei, RSC Adv. 9, 35717 (2019)

    CAS  Article  Google Scholar 

  2. 2.

    M. Jayachandiran, S.M.M. Kennedy, J. Lumin. 219, 116951 (2020)

    CAS  Article  Google Scholar 

  3. 3.

    T. Pulli, T. Donsberg, T. Poikonen, F. Manoocheri, P. Karha, E. Ikonen, Light-Sci. Appl. 4, e332 (2015)

    CAS  Article  Google Scholar 

  4. 4.

    H.F. Guo, Q.F. Shi, K.V. Ivanovskikh, L. Wang, C. Cui, P. Huang, Mater. Res. Bull. 126, 110836 (2020)

    CAS  Article  Google Scholar 

  5. 5.

    R.R. Cui, X. Guo, C.Y. Deng, J. Lumin. 224, 117233 (2020)

    CAS  Article  Google Scholar 

  6. 6.

    L. Li, X. Tang, Z. Jiang, X. Zhou, S. Jiang, X. Luo, G. Xiang, K. Zhou, J. Alloy. Compd. 701, 515 (2017)

    CAS  Article  Google Scholar 

  7. 7.

    H.H. Li, X.H. Gong, Y.J. Chen, J.H. Huang, Y.F. Lin, Z.D. Luo, Y.D. Huang, J. Rare Earths 36, 456 (2018)

    Article  Google Scholar 

  8. 8.

    X. Li, C. Yang, Q.S. Liu, X.C. Wang, X.Y. Mi, Ceram. Int. 46, 17376 (2020)

    CAS  Article  Google Scholar 

  9. 9.

    X. Zou, L.H. He, R. Li, Q.J. Zheng, Y.F. Liu, C.G. Xu, D.M. Lin, J. Mater. Sci. 28, 2826 (2017)

    CAS  Google Scholar 

  10. 10.

    Y. Zhang, W.T. Gong, G.L. Ning, New J. Chem. 40, 10136 (2016)

    CAS  Article  Google Scholar 

  11. 11.

    J. Zhao, C.F. Guo, T. Li, X.Y. Su, N.M. Zhang, J.Y. Chen, Dyes Pigm. 132, 159 (2016)

    CAS  Article  Google Scholar 

  12. 12.

    Y. Zhang, S. Sun, P.F. Yin, Y.L. Yang, L.Y. Fu, J. Wang, X. Feng, H.B. Rao, Y.Y. Wang, J. Lumin. 224, 117268 (2020)

    CAS  Article  Google Scholar 

  13. 13.

    X.G. Zhang, J.L. Zhang, M.L. Gong, Opt. Mater. 36, 850 (2014)

    CAS  Article  Google Scholar 

  14. 14.

    M. Yu, X.R. Xu, W.T. Zhang, X.F. Chen, P.C. Zhang, Y. Huang, J. Alloy. Compd. 817, 152761 (2020)

    CAS  Article  Google Scholar 

  15. 15.

    J.Y. Xiang, J.W. Yang, N.J. Luo, J. Zhu, S.P. Huang, Y. Mao, Results Phys. 13, 102258 (2019)

    Article  Google Scholar 

  16. 16.

    X.Y. Huang, S.Y. Wang, B. Li, Q. Sun, H. Guo, Opt. Lett. 43, 1307 (2018)

    CAS  Article  Google Scholar 

  17. 17.

    W.H. Zhang, Y.J. Chen, X.J. Geng, Y. Yang, L.J. Xiao, J. Lumin. 224, 117324 (2020)

    CAS  Article  Google Scholar 

  18. 18.

    N. Shaishta, W.U. Khan, S.K.B. Mane, A. Hayat, D.D. Zhou, J. Khan, N. Mehmood, H.K. Inamdar, G. Manjunatha, Int. J. Energy Res. 44, 8328 (2020)

    CAS  Article  Google Scholar 

  19. 19.

    J.B. Luo, Z.S. Sun, Z.P. Zhu, X.G. Zhang, Z.C. Wu, F.W. Mo, Ceram. Int. 46, 11994 (2020)

    CAS  Article  Google Scholar 

  20. 20.

    J. Zhang, Y.H. Wang, Solid-State Lett. 13, J35 (2010)

    CAS  Article  Google Scholar 

  21. 21.

    X.G. Zhang, C.Y. Zhou, J.H. Song, L.Y. Zhou, M.L. Gong, J. Alloys Compd. 592, 283 (2014)

    CAS  Article  Google Scholar 

  22. 22.

    B.Z. Yang, Z.P. Yang, Y.F. Liu, F.C. Lu, P.L. Li, Y.M. Yang, X. Li, Ceram. Int. 38, 4895 (2012)

    CAS  Article  Google Scholar 

  23. 23.

    T. Yaba, R. Wangkhem, N.S. Singh, J. Alloys Compd. 843, 156022 (2020)

    CAS  Article  Google Scholar 

  24. 24.

    T. Richhariya, N. Brahme, D.P. Bisen, A. Choubey, Y. Patle, E. Chandrawanshi, J. Mater. Sci. 31, 13667 (2020)

    CAS  Google Scholar 

  25. 25.

    E.A. Rathnakumari, M. Jayachandiran, S.M.M. Kennedy, Optik 186, 221 (2019)

    CAS  Article  Google Scholar 

  26. 26.

    D. Zhao, Y. Xue, R. Zhang, Y. Fan, B. Liu, Y. Li, S. Zhang, Dalton Trans. 49, 10104 (2020)

    CAS  Article  Google Scholar 

  27. 27.

    A.R. Camacho, F.C. Romo, A.G. Murillo, J.O. Uc, J. Aust. Ceram. Soc. 56, 447 (2020)

    CAS  Article  Google Scholar 

  28. 28.

    C. Wei, D.H. Xu, Z.F. Yang, J.L. Li, A.C. Geng, X. Li, J.Y. Sun, J. Mater. Sci. 30, 15512 (2019)

    CAS  Google Scholar 

  29. 29.

    D. Zhao, X.Y. Han, Y.L. Xue, R.J. Zhang, S.R. Zhang, Y.N. Li, J. Mater. Sci. 31, 9911 (2020)

    CAS  Google Scholar 

  30. 30.

    D.G. Deng, H. Yu, Y.Q. Li, Y.J. Hua, G.H. Jia, S.L. Zhao, H.P. Wang, L.H. Huang, Y.Y. Li, C.X. Li, S.Q. Xu, J. Mater. Chem. C. 1, 3149 (2013)

    Google Scholar 

  31. 31.

    Y.J. Han, S. Wang, H. Liu, L. Shi, A.J. Song, X.L. Lu, J.Y. Wei, Z.Y. Mao, D.J. Wang, Z.F. Mu, Z.W. Zhang, S.L. Niu, J. Alloys Compd. 844, 156070 (2020)

    CAS  Article  Google Scholar 

  32. 32.

    L. Wang, W.L. Guo, Y. Tian, P. Huang, Q.F. Shi, C.E. Cui, Ceram. Int. 42, 13648 (2016)

    CAS  Article  Google Scholar 

  33. 33.

    J.X. Wu, M. Li, H.L. Jia, Z.G. Liu, H.J. Jia, J. Lumin. 225, 117367 (2020)

    CAS  Article  Google Scholar 

  34. 34.

    S.R. Zhang, D. Zhao, Y.C. Fan, Z. Ma, Y.L. Xue, Y.N. Li, J. Solid State Chem. 279, 120965 (2019)

    CAS  Article  Google Scholar 

  35. 35.

    R. Vijayakumar, H. Guo, X.Y. Huang, Dyes Pigm. 156, 8 (2018)

    CAS  Article  Google Scholar 

  36. 36.

    M.K. Pradhan, T.L. Rao, U.K. Goutam, S. Dash, Spectrochim. Acta A 240, 118593 (2020)

    CAS  Article  Google Scholar 

  37. 37.

    Y.J. Han, S. Wang, H. Liu, L. Shi, S.X. Liu, Y. Zhang, C. Liu, X.F. Shi, Q. Wang, Z.F. Mu, Z.Y. Mao, D.J. Wang, Z.W. Zhang, J. Mol. Struct. 1210, 127998 (2020)

    CAS  Article  Google Scholar 

  38. 38.

    L.X. Zhang, Y. Xie, X. Geng, B. Deng, H.L. Geng, R.J. Yu, J. Lumin. 225, 117365 (2020)

    CAS  Article  Google Scholar 

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Conceptualization: PH, ZD, TW; Methodology: PH, TW; Material preparation: PH, ZL, YM; Date collection and analysis: PH; Writing—original and preparation: PH; Writing—review and editing: PH, ZD, TW.

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Correspondence to Zhaoping Deng.

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Hu, P., Deng, Z., Wang, T. et al. Synthesis and luminescence properties of red-emitting NaBaBi2(PO4)3:Eu3+ phosphors. J Mater Sci: Mater Electron (2021).

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