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A lead-free perovskite Bi1/2(Na1/4Li1/4)TiO3: investigation on structural, electrical properties, and device application

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Abstract

In the present era, global challenges are focused to meet the security of energy due to excessive energy demands. The coal and petroleum-based fossil fuels are soon fading out due to current energy-generating units; hence, the energy from renewable energy sources becomes an alternative medium and new scientific investment. Research is carried out to boost the efficiency of these devices. The multifunctional materials having superior properties are the need of the hour to provide insight towards producing low-cost energy devices. A perovskite having the chemical formula Bi1/2(Na1/4Li1/4)TiO3 (BNLTO) is synthesized using a solid-state reaction. The standard techniques were used to investigate the structural and electrical characterizations at various experimental conditions. The X-ray diffraction (XRD) spectra elucidated the presence of an orthorhombic symmetry in the synthesized sample. The high dielectric constant and low loss factor is evolved at various frequencies and temperatures. The Nyquist plot depicts the association of the combined effect of grain and grain boundary. The activation energies evaluated from the loss and modulus spectrum are noted as ~ 1.26 eV and 0.81 eV, respectively. The charge carriers contribute to the conduction mechanism at high temperature. Finally, a poled piezoelectric energy harvester is fabricated to check its capabilities for the conversion of small impact from hand palm into electrical energy.

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Authors and Affiliations

  1. Department of Physics, National Institute of Technology, Silchar, Silchar, 788010, India

    Subrat Kumar Barik & Koustav Kashyap Gogoi

  2. Department of Electronics and Instrumentation Engineering, National Institute of Technology, Silchar, 788010, India

    Sudarsan Sahoo

  3. Department of Robotics Engineering, Daegu Gyeongbuk Institute of Science & Technology (DGIST), Daegu, 42988, South Korea

    Hoe Joon Kim & Sugato Hajra

Authors
  1. Subrat Kumar Barik
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  2. Koustav Kashyap Gogoi
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  3. Sudarsan Sahoo
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  4. Hoe Joon Kim
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  5. Sugato Hajra
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Correspondence to Subrat Kumar Barik.

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Barik, S.K., Gogoi, K.K., Sahoo, S. et al. A lead-free perovskite Bi1/2(Na1/4Li1/4)TiO3: investigation on structural, electrical properties, and device application. J Mater Sci: Mater Electron 32, 4629–4638 (2021). https://doi.org/10.1007/s10854-020-05201-w

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  • DOI: https://doi.org/10.1007/s10854-020-05201-w

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