Dielectric and optical properties of chitosan-Pb and chitosan-Bi nanocomposites

Abstract

In this work, chitosan was used as powerful chelating agent and an excellent template for synthesis of metal oxide nanoparticles. Chitosan-Pb and Chitosan-Bi nanoparticles have been synthesized by incorporating PbO/BiO nanoparticles within the chitosan matrix using a simple solution cast method. Dielectric and optical properties of the nanocomposite film were studied. Moreover, the effect of temperature on the dielectric properties of the hybrid film was determined. The absorption and transmittance were measured for the prepared samples by using UV–Vis spectrophotometer. The optical parameters such as refractive index, absorption coefficient, energy band gap, dispersion energy, oscillation energy, and the skin or penetration depth for the chitosan-PbO/-BiO nanocomposite were obtained.

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References

  1. 1.

    C. Vilela, R. J. B. Pinto, S. Pinto, P. Marques, A. Silvestr, Polysaccharides-Based Hybrids with Metal Nanoparticles, Polysaccharide Based Hybrid Materials, ch2 9–30 (2018).

  2. 2.

    G. Kickelbick, Prog. Polym. Sci. 28, 83–114 (2003)

    CAS  Article  Google Scholar 

  3. 3.

    T. Xu, J. Membr. Sci. 263, 1–29 (2005)

    CAS  Article  Google Scholar 

  4. 4.

    M. Dash, F. Chiellini, R.M. Ottenbrite, E. Chiellini, Prog. Polym. Sci. 36, 981–1014 (2011)

    CAS  Article  Google Scholar 

  5. 5.

    Wu, Li-Qun, P. Anand Gadre, Yi Hyunmin, J. Mark Kastantin, W. Gary Rubloff, E. William Bentley, F. Gregory Payne, and Reza Ghodssi, Langmuir 18, 8620–8625 (2002).

  6. 6.

    A.J. Varma, S.V. Deshpande, J.F. Kennedy, Carbohyd. Polym. 55, 77–93 (2004)

    CAS  Article  Google Scholar 

  7. 7.

    S.M. Riyadh, K.D. Khalil, A.H. Bashal, Catalysts 10, 100 (2020)

    CAS  Article  Google Scholar 

  8. 8.

    K. Asadpour-Zeynali, F. Mollarasouli, Cent. Eur. J. Chem. 12, 711–718 (2014)

    CAS  Google Scholar 

  9. 9.

    Y.L. Liu, W.H. Chen, Y.H. Chang, Carbohyd. Polym. 76, 232–238 (2009)

    CAS  Article  Google Scholar 

  10. 10.

    C. Zhang, Q. Chi, J. Dong, Y. Cui, X. Wang, L. Liu, Q. Lei, Scientific reports 6, 33508 (2016)

    CAS  Article  Google Scholar 

  11. 11.

    C. Bilkan, S. Altındal, Y. Azizian-Kalandaragh, Phys. B 515, 28 (2017)

    CAS  Article  Google Scholar 

  12. 12.

    A. Nikravan, Y. Badali, Ş Altındal, I. Uslu, I. Orak, J. Electron. Mater 46, 5728 (2017)

    CAS  Article  Google Scholar 

  13. 13.

    M. Safwan Sazali, et al, Results in Physics 15, 102740 (2019).

  14. 14.

    O.B. Mergen, E. Arda, G.A. Evingur, J. Compos. Mater. 54, 1497–1510 (2019)

    Article  Google Scholar 

  15. 15.

    B. Aziz Shujahadeen, Nanomaterials, 7, 444 (2017).

  16. 16.

    Anu, K. Yadav, Materials Today: Proceedings, 15 February (2020). https://doi.org/10.1016/j.matpr.2020.01.467.

  17. 17.

    M. Abid, M. Et-tabirou, M. Taibi, Mater. Sci. Eng. B 97, 20–24 (2003)

    Article  Google Scholar 

  18. 18.

    M. Hdidar, S. Chouikhi, A. Fattoum, M. Arous, A. Kallel, J. Alloy. Compd. 750, 375–383 (2018)

    CAS  Article  Google Scholar 

  19. 19.

    T.A. Abdel-Baset, A. Hassen, Phys. B 499, 24–28 (2016)

    CAS  Article  Google Scholar 

  20. 20.

    A. Abou Elfadl, A. M. Ismail & M. I. Mohammed, Journal of Materials Science: Materials in Electronics 3, 8297–8307 (2020).

  21. 21.

    R.B. Belgacem, M. Chaari, A. Matoussi, J. Alloy. Compd. 651, 49–58 (2015)

    Article  Google Scholar 

  22. 22.

    S.A. Khan, J.K. Lal, A.A. Al-Ghamdi, Opt. Laser Technol. 42, 839–844 (2010)

    CAS  Article  Google Scholar 

  23. 23.

    J. Tauc, R. Grigorovici, A. Vencu, Phys. Status. Solidi. B 15, 627–637 (1996)

    Article  Google Scholar 

  24. 24.

    E.M. El-Menyawy, A.A.A. Darwish, I.T. Zedan, Opt. Laser Technol. 79, 158–163 (2016)

    CAS  Article  Google Scholar 

  25. 25.

    D. Bhattacharyya, S. Chaudhuri, A.K. Pal, Vacuum 43, 313–316 (1992)

    CAS  Article  Google Scholar 

  26. 26.

    F. Urach, Phys. Rev. 92, 1324 (1953)

    Article  Google Scholar 

  27. 27.

    M. Abdel-Baki, F. El-Diasty, Curr. Opin. Solid State Mater. Sci. 10, 21–29 (2006)

    Article  Google Scholar 

  28. 28.

    N. Banu, A.H. Bhuiyan, K.S. Hossain, Adv. Polym. Technol. 37, 84–94 (2018)

    Article  Google Scholar 

  29. 29.

    S.A. Fayek, M.R. Balboul, K.H. Marzouk, Thin Solid Films 515, 7281–7285 (2007)

    CAS  Article  Google Scholar 

  30. 30.

    H. Mahr, Cryst. Phys. Rev. 125, 1510–1516 (1962)

    CAS  Article  Google Scholar 

  31. 31.

    H. Eugene, Optics, fourth edition, Adelphi University, San Francisco, Boston, New York, (2002), Ch 4. P. 139.

  32. 32.

    J.I. Pankove, Optical Processes in Semiconductors (Dover Publications Inc., New York, 1975).

    Google Scholar 

  33. 33.

    P.W. Gilberd, J. Phys. F Met. Phys. 12, 8 (1982)

    Google Scholar 

  34. 34.

    H. Eugene, Optics, 4th edn. (Adelphi University, San Francisco, Boston, New York, 2002), p. 113

    Google Scholar 

  35. 35.

    A.A. Zaki, M. Hagar, N.R.E. Radwan, Optik 139, 95–103 (2017)

    CAS  Article  Google Scholar 

  36. 36.

    O.G. Abdullah, S.B. Aziz, K.M. Omer, Y.M. Salih, J. Mater. Sci. 26, 3–9 (2015)

    Google Scholar 

  37. 37.

    T.G. Urs, G.K. Gowtham, M.B. Nandaprakash, D. Mahadevaiah, Y. Sangappa, R. Somashekar, Indian J. Phys. 91, 53–60 (2017)

    CAS  Article  Google Scholar 

  38. 38.

    R.T. Potzsch, B.C. Stahl, H. Komber, C.J.H.B.I. Voit, Polym. Chem. 5, 11–21 (2014)

    Article  Google Scholar 

  39. 39.

    A.A. Zaki, A.A. El-Amin, Opt. Laser Technol. 97, 71–76 (2017)

    CAS  Article  Google Scholar 

  40. 40.

    W. Sellmeier, Ann Phys Chem. 143, 271 (1871)

    Google Scholar 

  41. 41.

    S.H. Wemple, M. DiDomenico, Phys. Rev. B 3, 38–51 (1971)

    Article  Google Scholar 

  42. 42.

    S.H. Wemple, M. DiDomenico, Phys. Rev. Lett. 23, 1156 (1969)

    CAS  Article  Google Scholar 

Download references

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Correspondence to Ayman A. Zaki or T. A. Abdel-Basset.

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Zaki, A.A., Abdel-Basset, T.A., Haggar, M. et al. Dielectric and optical properties of chitosan-Pb and chitosan-Bi nanocomposites. J Mater Sci: Mater Electron 32, 3603–3611 (2021). https://doi.org/10.1007/s10854-020-05107-7

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