Cr-doping effects on optical and magnetic properties of BaSn1−xCrxO3

Abstract

Polycrystalline bulk samples of BaSn1−xCrxO3 with different Cr concentrations were prepared by standard solid state reaction method. The effects of Cr concentration on crystal structure of BaSn1−xCrxO3, as well as optical and magnetic properties were investigated. Powder X-ray diffraction (XRD) shows that each of these samples possess a perovskite structure with \( Pm\bar{3}m \) space group. The Cr ions are located at the substitution Sn sites as revealed by the XRD, Diffuse reflectance spectra and Raman spectra. Moreover, it is found that room-temperature ferromagnetism (FM) can be reversed by annealing in the nitrogen atmosphere. This can be well explained by a modified model of F-center mediated FM.

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References

  1. 1.

    A.J. Smith, A.J.E. Welch, Some mixed metal oxides of perovskite structure. Acta Crystallogr. 13, 653–656 (1960)

    Article  Google Scholar 

  2. 2.

    Y. Shimizu, Y. Fukuyama, T. Narikiyo, H. Arai, T. Seiyama, Perovskite-type oxides having semiconductivity as oxygen sensors. Chem. Lett. 9, 377–380 (1985)

    Article  Google Scholar 

  3. 3.

    J. Cerdà, J. Arbiol, R. Diaz, G. Dezanneau, J.R. Morante, Synthesis of perovskite-type BaSnO3 particles obtained by a new simple wet chemical route based on a sol-gel process. Mater. Lett. 56, 131–136 (2002)

    Article  Google Scholar 

  4. 4.

    Q.Z. Liu, B. Li, J.Q. Liu, H. Li, Z.L. Liu, K. Dai, G.P. Zhu, P. Zhang, J.M. Dai, F. Chen, Structure and band gap tuning of transparent (Ba1-xSrx)SnO3 thin films epitaxially grown on MgO substrates. Europhys. Lett. 98, 47010–47014 (2012)

    Article  Google Scholar 

  5. 5.

    P.H. Borse, A.J. Upendra, M.J. Sang, J.S. Jang, J.S. Lee, Band gap tuning of lead-substituted BaSnO3 for visible light photocatalysis. Appl. Phys. Lett. 90, 4103–4107 (2007)

    Article  Google Scholar 

  6. 6.

    X. Luo, Y.S. Oh, A. Sirenko, P. Gao, T.A. Tyson et al., High carrier mobility in transparent Ba1−xLaxSnO3 crystals with a wide band gap. Appl. Phys. Lett. 100, 2112–2117 (2012)

    Google Scholar 

  7. 7.

    K. Balamurugan, E.K. Senthil, B. Ramachandran, S. Venkatesh, K.N. Harish, Dielectric resonance and magnetic properties of Fe-3% doped BaSnO3 thin films grown by pulsed laser deposition. J. Appl. Phys. 111, 107–112 (2012)

    Article  Google Scholar 

  8. 8.

    N.H. Hong, J. Sakai et al., Ferromagnetism in transition-metal-doped TiO2 thin films. Phys. Rev. B 70, 204–210 (2004)

    Google Scholar 

  9. 9.

    G.S. Chang, J. Forrest, E.Z. Kurmaev, A.N. Morozovska, M.D. Glinchuk, J.A. McLeod, A. Moewes, T.P. Surkova, Oxygen-vacancy-induced ferromagnetism in undoped SnO2 thin films. Phys. Rev. B 85, 5319–5324 (2012)

    Google Scholar 

  10. 10.

    H.H. Nguyen, P. Nathalie, S. Joe, Ferromagnetism observed in pristine SnO2 thin films. Phys. Rev. B 77, 3205–3209 (2008)

    Google Scholar 

  11. 11.

    P. Kharel, C. Sudakar, M.B. Sahana, G. Lawes, R. Suryanarayanan et al., Room temperature ferromagnetism in Cr-doped In2O3 on high vacuum annealing of thin films and bulk samples. J. Appl. Phys. 101, 117–120 (2007)

    Article  Google Scholar 

  12. 12.

    H.H. Nguyen, J. Sakai, W. Prellier, H. Awatef, Transparent Cr-doped SnO2 thin films: ferromagnetism beyond room temperature with a giant magnetic moment. J. Phys.: Condens. Matter 17, 1697–1702 (2005)

    Google Scholar 

  13. 13.

    H.H. Nguyen, J. Sakai, P. Nathalie, B. Virginie, Room-temperature ferromagnetism observed in undoped semiconducting and insulating oxide thin films. Phys. Rev. B 73, 2404–2408 (2006)

    Google Scholar 

  14. 14.

    N.H. Hong, J. Sakai, N.T. Huong, N. Poirot, A. Ruyter, Role of defects in tuning ferromagnetism in diluted magnetic oxide thin films. Phys. Rev. B 72, 5336–5340 (2005)

    Google Scholar 

  15. 15.

    K. Balamurugan, K.N. Harish, B. Ramachandrana, R.M.S. Ramachandra, C.J. Arout, P.N. Santhosh, Magnetic and optical properties of Mn-doped BaSnO3. Solid State Commun. 149, 884–887 (2009)

    Article  Google Scholar 

  16. 16.

    M.R. Manju, V. Punith Kumar, D. Vijaylakshmi, Investigation of ferromagnetic properties in Fe/Co substituted BaSnO3 perovskite stannates. Phys. B: Condens. Matter 500, 14–19 (2016)

    Article  Google Scholar 

  17. 17.

    D.B. Wiles, R.A. Young, A new computer program for Rietveld analysis of X-ray powder diffraction patterns. J. Appl. Crystallogr. 14, 149–151 (1981)

    Article  Google Scholar 

  18. 18.

    C.P. Udawatte, M. Yoshimura, Preparation of well-crystallized BaSnO3 powders under hydrothermal conditions. Mater. Lett. 47, 7–10 (2001)

    Article  Google Scholar 

  19. 19.

    H. Mizoguchi, P. Chen, P. Boolchand, V. Ksenofontov, C. Felser, P.W. Barnes, P.M. Woodward, Electrical and optical properties of Sb-Doped BaSnO3. Chem. Mater. 25, 3858–3866 (2013)

    Article  Google Scholar 

  20. 20.

    J.M.D. Coey, M. Venkatesan, C.B. Fitzgerald, Donor impurity band exchange in dilute ferromagnetic oxides. Nat. Mater. 4, 173–179 (2005)

    Article  Google Scholar 

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Acknowledgements

This work was supported by Natural Science Research Project for Universities from the Education Department of Anhui Province (KJ2017A344), Natural Science Foundation of Fuyang Normal University (2017FSKJ08ZD), The Open Foundation of State Key Laboratory of Rare Earth Permanent Magnetic Materials (XTYC-K201807), Cooperative research project of Fuyang Normal University and Fuyang Municipal Government (XDHX2016010 and XDHX20173300).

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Correspondence to FuHai Su or Jianming Dai.

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Zhang, P., Su, F., Wang, Q. et al. Cr-doping effects on optical and magnetic properties of BaSn1−xCrxO3. J Mater Sci: Mater Electron 30, 16316–16320 (2019). https://doi.org/10.1007/s10854-019-02002-8

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