Abstract
(1−x−y)(K0.45Na0.55)NbO3–yBi0.5Na0.5ZrO3–xBaHfO3–0.2%MnO2 ceramics without antimony have been fabricated by the conventional solid-state method, and influences of Bi0.5Na0.5ZrO3 and BaHfO3 contents on their structure and electrical properties are studied. Composition modification can result in the formation of rhombohedral–orthorhombic–tetragonal phase coexistence in the ceramics (y = 0.04 and 0.01 ≤ x ≤ 0.02 as well as x = 0.01 and 0.04 ≤ y ≤ 0.045). In the region of this phase boundary, the ceramics exhibit both enhanced piezoelectric properties (d33 ~ 385 pC/N, kp ~ 51%, S ~ 0.157%) and high Curie temperature (TC ~ 320 °C). Especially, good comprehensive properties and the absence of antimony make the material more environmentally friendly.
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Authors gratefully acknowledge the support of the National Natural Science Foundation of China (NSFC Nos. 51722208 and 51332003), the Key Technologies Research and Development Program of Sichuan Province (No. 2018JY0007) and the Fundamental Research Funds for the Central Universities (2012017yjsy111). Authors thank Mrs. Wang Hui (Analytical & Testing Center of Sichuan University) for performing the FE-SEM measurements.
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Ding, Y., Zheng, T., Xie, R. et al. High-performance potassium sodium niobate-based lead-free materials without antimony. J Mater Sci: Mater Electron 29, 14487–14494 (2018). https://doi.org/10.1007/s10854-018-9582-2
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DOI: https://doi.org/10.1007/s10854-018-9582-2