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Significance of encapsulating organic temperature sensors through spatial atmospheric atomic layer deposition for protection against humidity

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Abstract

Printed organic sensors are of significant importance owing to their simplicity, low cost, easy fabrication and solution processability. However, organic sensors often face the problem of performance degradation when exposed to ambient environment therefore, the effect of humidity needs to be studied for prolonging the lifetime of organic sensors. In this study, we propose atomically thin and highly reliable encapsulation layer on the surface of an organic functional material to enhance its lifetime as a temperature sensing unit. Our organic temperature sensor is based on a conductive and uniform IDT pattern deposited on a glass substrate through advanced printing technology of reverse offset. Thin film of PEDOT:PSS is used as the temperature sensitive functional layer deposited through electrohydrodynamic atomization while the organic thin film was encapsulated with aluminum oxide (Al2O3) through spatial atmospheric atomic layer deposition system (SAALD). The temperature range of the developed sensors was from 25 to 90 °C with relative humidity reaching up to 75% RH. The obtained results exhibited that Al2O3 encapsulation deposited through SAALD significantly enhanced the linearity, repeatability, endurance (50 cycles), retention (1 month) and lifetime of organic temperature sensor as compared to the non-encapsulated sensor. The performance degradation mechanism of non-encapsulated sensor due to humid environment has been discussed in detail. This study contributes an important step forward for preserving the performance and elongating the lifetime of organic electronic devices through a single atomically thin encapsulation.

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References

  1. N. Dubey, M. Leclerc, J. Polym. Sci. B 49, 467 (2011)

    Article  Google Scholar 

  2. T.K. Das, S. Prusty, Polym. Plast. Technol. Eng. 51, 1487 (2012)

    Article  Google Scholar 

  3. S.K. Mahadeva, S. Yun, J. Kim, Sens. Actuators A 165, 194 (2011)

    Article  Google Scholar 

  4. K.H. Choi, H.B. Kim, K. Ali, M. Sajid, G. Uddin Siddiqui, D.E. Chang, H.C. Kim, J.B. Ko, H.W. Dang, Y.H. Doh, Sci. Rep. 5, 15178 (2015)

    Article  Google Scholar 

  5. M. Sajid, H.B. Kim, Y.J. Yang, J. Jo, K.H. Choi, Sens. Actuators B 246, 809 (2017)

    Article  Google Scholar 

  6. J. Zhou, D.H. Anjum, L. Chen, X. Xu, I.A. Ventura, L. Jiang, G. Lubineau, J. Mater. Chem. C 2, 9903 (2014)

    Article  Google Scholar 

  7. S. Ouyang, Y. Xie, D. Wang, D. Zhu, X. Xu, T. Tan, J. DeFranco, H.H. Fong, J. Polym. Sci. B 52, 1221 (2014)

    Article  Google Scholar 

  8. M. Borghetti, M. Serpelloni, E. Sardini, S. Pandini, Sens. Actuators A 243, 71 (2016)

    Article  Google Scholar 

  9. A. Pierre, M. Sadeghi, M.M. Payne, A. Facchetti, J.E. Anthony, A.C. Arias, Adv. Mater. 26, 5722 (2014)

    Article  Google Scholar 

  10. X. Zhang, J. Wu, J. Wang, J. Zhang, Q. Yang, Y. Fu, Z. Xie, Sol. Energy Mater. Sol. Cells 144, 143 (2016)

    Article  Google Scholar 

  11. K.S. Karimov, Z. Ahmad, F. Touati, M. Mahroof-Tahir, M. Muqeet, Rehman, S. Zameer, Abbas, Chin. Phys. B 24, 116102 (2015)

    Article  Google Scholar 

  12. R.A. Nawrocki, E.M. Galiger, D.P. Ostrowski, B.A. Bailey, X. Jiang, R.M. Voyles, N. Kopidakis, D.C. Olson, S.E. Shaheen, Org. Electron. 15, 1791 (2014)

    Article  Google Scholar 

  13. K.H. Choi, J. Ali, Y.H. Doh, Jpn. J. Appl. Phys. 54, 035103 (2015)

    Article  Google Scholar 

  14. I.-H. Ko, S.-J. Kim, J. Lim, S.-H. Yu, J. Ahn, J.-K. Lee, Y.-E. Sung, Electrochim. Acta 187, 340 (2016)

    Article  Google Scholar 

  15. S. Cho, M. Kim, J. Jang, ACS Appl. Mater. Interfaces 7, 10213 (2015)

    Article  Google Scholar 

  16. D. Yu, Y.-Q. Yang, Z. Chen, Y. Tao, Y.-F. Liu, Opt. Commun. 362, 43 (2016)

    Article  Google Scholar 

  17. M.S. Weaver, L.A. Michalski, K. Rajan, M.A. Rothman, J.A. Silvernail, J.J. Brown, P.E. Burrows, G.L. Graff, M.E. Gross, P.M. Martin, M. Hall, E. Mast, C. Bonham, W. Bennett, M. Zumhoff, Appl. Phys. Lett. 81, 2929 (2002)

    Article  Google Scholar 

  18. D. Yang, Y.q. Yang, Y. Duan, P. Chen, C.L. Zang, Y. Xie, D.M. Liu, X. Wang, Y.H. Duan, F.B. Sun, Q. Gao, K.W. Xue, ECS Solid State Lett. 2, R31 (2013)

    Article  Google Scholar 

  19. S.M. Jeong, W.H. Koo, S.H. Choi, H.K. Baik, Solid State Electron. 49, 838 (2005)

    Article  Google Scholar 

  20. A.G. Erlat, R.J. Spontak, R.P. Clarke, T.C. Robinson, P.D. Haaland, Y. Tropsha, N.G. Harvey, E.A. Vogler, J. Phys. Chem. B 103, 6047 (1999)

    Article  Google Scholar 

  21. D.-S. Wuu, T.-N. Chen, C.-C. Wu, C.-C. Chiang, Y.-P. Chen, R.-H. Horng, F.-S. Juang, Chem. Vap. Depos. 12, 220 (2006)

    Article  Google Scholar 

  22. S.M. George, Chem. Rev. 110, 111 (2010)

    Article  Google Scholar 

  23. K. Ali, J. Ali, S.M. Mehdi, K.-H. Choi, Y.J. An, Appl. Surf. Sci. 353, 1186 (2015)

    Article  Google Scholar 

  24. C. Bali, A. Brandlmaier, A. Ganster, O. Raab, J. Zapf, A. Hübler, Mater. Today Proc. 3, 739 (2016)

    Article  Google Scholar 

  25. C.M. Homenick, R. James, G.P. Lopinski, J. Dunford, J. Sun, H. Park, Y. Jung, G. Cho, P.R.L. Malenfant, ACS Appl. Mater. Interfaces 8, 27900 (2016)

    Article  Google Scholar 

  26. M.M. Rehman, B.-S. Yang, Y. Yang, K.S. Karimov, K.H. Choi, Curr. Appl. Phys. 17, 533 (2017)

    Article  Google Scholar 

  27. J. Ali, M.M. Rehman, G.U. Siddiqui, S. Aziz, K.H. Choi, Physica B 531, 223 (2018)

    Article  Google Scholar 

  28. M.M. Rehman, G.U. Siddiqui, M.M. ur Rehman, H.B. Kim, Y.H. Doh, K.H. Choi, Mater. Res. Bull. 105, 28 (2018)

    Article  Google Scholar 

  29. G.U. Siddiqui, M.M. Rehman, K.H. Choi, Polymer (Guildford) 100, 102 (2016)

    Article  Google Scholar 

  30. G.U. Siddiqui, M.M. Rehman, K.H. Choi, J. Mater. Chem. C 5, 5528 (2017)

    Article  Google Scholar 

  31. Y.J. Yang, M.M. Rehman, G.U. Siddiqui, K.H. Na, K.H. Choi, Curr. Appl. Phys. 17, 1733 (2017)

    Article  Google Scholar 

  32. G.U. Siddiqui, M.M. Rehman, Y.-J. Yang, K.H. Choi, J. Mater. Chem. C. 5, 862 (2017)

    Article  Google Scholar 

  33. M.M. Rehman, G.U. Siddiqui, J.Z. Gul, S.-W. Kim, J.H. Lim, K.H. Choi, Sci. Rep. 6, 36195 (2016)

    Article  Google Scholar 

  34. M.M. Rehman, G.U. Siddiqui, S. Kim, K.H. Choi, J. Phys. D 50, 335104 (2017)

    Article  Google Scholar 

  35. M.M. Rehman, G.U. Siddiqui, Y.H. Doh, K.H. Choi, Semicond. Sci. Technol. 32, 095001 (2017)

    Article  Google Scholar 

  36. G.U. Siddiqui, M. Sajid, J. Ali, S.W. Kim, Y.H. Doh, K.H. Choi, Sens. Actuators B 266, 354 (2018)

    Article  Google Scholar 

  37. F. Zhang, W. Yang, A. Pang, Z. Wu, H. Qi, J. Yao, Z. Fan, J. Shao, Appl. Surf. Sci. 254, 6410 (2008)

    Article  Google Scholar 

  38. M.M. ur Rehman, K.T. Kim, K.H. Na, K.H. Choi, Appl. Surf. Sci. 422, 273 (2017)

    Article  Google Scholar 

  39. J. Feng, C.-M. Chan, Polymer (Guildford) 41, 7279 (2000)

    Article  Google Scholar 

  40. T. Vuorinen, J. Niittynen, T. Kankkunen, T.M. Kraft, M. Mäntysalo, Sci. Rep. 6, 35289 (2016)

    Article  Google Scholar 

  41. M.D. Dankoco, G.Y. Tesfay, E. Benevent, M. Bendahan, Mater. Sci. Eng. B 205, 1 (2016)

    Article  Google Scholar 

  42. A. Benchirouf, S. Palaniyappan, R. Ramalingame, P. Raghunandan, T. Jagemann, C. Müller, M. Hietschold, O. Kanoun, Sens. Actuators B 224, 344 (2016)

    Article  Google Scholar 

  43. P. Kuberský, T. Syrový, A. Hamáček, S. Nešpůrek, J. Stejskal, Procedia Eng. 120, 614 (2015)

    Article  Google Scholar 

  44. U. Ail, M.J. Jafari, H. Wang, T. Ederth, M. Berggren, X. Crispin, Adv. Funct. Mater. 26, 6288 (2016)

    Article  Google Scholar 

  45. W.A. Daoud, J.H. Xin, Y.S. Szeto, Sens. Actuators B 109, 329 (2005)

    Article  Google Scholar 

  46. M. Kus, S. Okur, Sens. Actuators B 143, 177 (2009)

    Article  Google Scholar 

  47. T. Takano, H. Masunaga, A. Fujiwara, H. Okuzaki, T. Sasaki, Macromolecules 45, 3859 (2012)

    Article  Google Scholar 

Download references

Acknowledgements

This material is based upon work supported by the Ministry of Trade, industry & Energy (Ml, Korea) under Industrial Technology Innovation Program. No. 10063277, "Development of pattern deposition system based on roll to roll processing under low temperature and atmospheric pressure condition for smart thin film device fabrication". And we would like to acknowledge the financial support from the R&D Convergence Program of NST (National Research Council of Science & Technology) of Republic of Korea (CAP-15-04-KITECH).

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Correspondence to Jeong Beom Ko or Kyung Hyun Choi.

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Mutee ur Rehman, M., Muqeet Rehman, M., Sajid, M. et al. Significance of encapsulating organic temperature sensors through spatial atmospheric atomic layer deposition for protection against humidity. J Mater Sci: Mater Electron 29, 14396–14405 (2018). https://doi.org/10.1007/s10854-018-9572-4

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