Abstract
Solution processed organometal trihalide materials spur tremendous attention due to their unprecedented performance in photovoltaic applications. However, submicron thick perovskite films are prone to morphological defects in the form of cracks, pinholes and porosity; the traits originated from their solution phase processing and subsequent crystallization. Moreover, pinholes and cracks in the thin film of spincoated Spiro-OMeTAD hole transport layer reduce the performance reliability by forming micro shorts and weaken the defense against moisture ingress to the perovskite layer. For the large scale processing of perovskite solar cell from the economically prudent solution phase processing, morphological shortcomings of both perovskite and hole transport layers need an urgent address. By selecting non-conventional lead precursor (lead acetate) and implementing anti-solvent treatment during film deposition, we able to form pinhole free and compact perovskite film. Crack free hole conducting layer is obtained by blending Spiro-OMeTAD with a conducting polymer without compromising in the solar cell performance. A detail investigation of the charge transport and charge extraction properties of the developed hole transport layers have been carried out. The developed CH3NH3PbI3 based perovskite solar cells show improved repeatability and performance.
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S.D. Stranks, H.J. Snaith, Metal-halide perovskites for photovoltaic and light-emitting devices. Nat. Nanotechnol. 10(5), 391–402 (2015)
H.H. Tsai, W.Y. Nie, J.C. Blancon, C.C.S. Toumpos, R. Asadpour, B. Harutyunyan, A.J. Neukirch, R. Verduzco, J.J. Crochet, S. Tretiak, L. Pedesseau, J. Even, M.A. Alam, G. Gupta, J. Lou, P.M. Ajayan, M.J. Bedzyk, M.G. Kanatzidis, A.D. Mohite, High-efficiency two-dimensional Ruddlesden-Popper perovskite solar cells. Nature 536(7616), 312–316 (2016)
W. Chen, Y.Z. Wu, Y.F. Yue, J. Liu, W.J. Zhang, X.D. Yang, H. Chen, E.B. Bi, I. Ashraful, M. Gratzel, L.Y. Han, Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers. Science 350(6263), 944–948 (2015)
N.J. Jeon, J.H. Noh, Y.C. Kim, W.S. Yang, S. Ryu, S.I. Seok, Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells. Nat. Mater. 13(9), 897–903 (2014)
C.C. Stoumpos, C.D. Malliakas, M.G. Kanatzidis, Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. Inorg. Chem. 52(15), 9019–9038 (2013)
S.D. Stranks, G.E. Eperon, G. Grancini, C. Menelaou, M.J.P. Alcocer, T. Leijtens, L.M. Herz, A. Petrozza, H.J. Snaith, Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342(6156), 341–344 (2013)
G.C. Xing, N. Mathews, S.Y. Sun, S.S. Lim, Y.M. Lam, M. Gratzel, S. Mhaisalkar, T.C. Sum, Long-range balanced electron- and hole-transport lengths in organic-inorganic CH3NH3PbI3. Science 342(6156), 344–347 (2013)
F.Y. Jiang, Y.G. Rong, H.W. Liu, T.F. Liu, L. Mao, W. Meng, F. Qin, Y.Y. Jiang, B.W. Luo, S.X. Xiong, J.H. Tong, Y. Liu, Z.F. Li, H.W. Han, Y.H. Zhou, Synergistic effect of PbI2 passivation and chlorine inclusion yielding high open-circuit voltage exceeding 1.15 V in both mesoscopic and inverted planar CH3NH3PbI3(Cl)-based perovskite solar cells. Adv. Funct. Mater. 26(44), 8119–8127 (2016)
W.C. Yang, Y. Yao, C.Q. Wu, Origin of the high open circuit voltage in planar heterojunction perovskite solar cells: role of the reduced bimolecular recombination. J. Appl. Phys. 117(9), 095502 (2015)
W.S. Yang, B.W. Park, E.H. Jung, N.J. Jeon, Y.C. Kim, D.U. Lee, S.S. Shin, J. Seo, E.K. Kim, J.H. Noh, S.I. Seok, Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells. Science 356(6345), 1376–1379 (2017)
J. Burschka, N. Pellet, S.J. Moon, R. Humphry-Baker, P. Gao, M.K. Nazeeruddin, M. Gratzel, Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 499(7458), 316–319 (2013)
K. A.Kojima, Y. Teshima, T. Shirai, Miyasaka, Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131(17), 6050–6051 (2009)
M.M. Lee, J. Teuscher, T. Miyasaka, T.N. Murakami, H.J. Snaith, Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338(6107), 643–647 (2012)
Y.X. Zhao, K. Zhu, Organic-inorganic hybrid lead halide perovskites for optoelectronic and electronic applications. Chem. Soc. Rev. 45(3), 655–689 (2016)
W. Zhang, M. Saliba, D.T. Moore, S.K. Pathak, M.T. Horantner, T. Stergiopoulos, S.D. Stranks, G.E. Eperon, J.A. Alexander-Webber, A. Abate, A. Sadhanala, S.H. Yao, Y.L. Chen, R.H. Friend, L.A. Estroff, U. Wiesner, H.J. Snaith, Ultrasmooth organic-inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells. Nat. Commun. 6, 6142 (2015)
H.S. Kim, C.R. Lee, J.H. Im, K.B. Lee, T. Moehl, A. Marchioro, S.J. Moon, R. Humphry-Baker, J.H. Yum, J.E. Moser, M. Gratzel, N.G. Park, Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci. Rep. 2, 591 (2012)
N.J. Jeon, J.H. Noh, W.S. Yang, Y.C. Kim, S. Ryu, J. Seo, S.I. Seok, Compositional engineering of perovskite materials for high-performance solar cells. Nature 517(7535), 476–480 (2015)
Y.C. Zhang, M. Elawad, Z. Yu, X.Q. Jiang, J.B. Lai, L.C. Sun, Enhanced performance of perovskite solar cells with P3HT hole-transporting materials via molecular p-type doping. Rsc Adv. 6(110), 108888–108895 (2016)
P. Qin, S. Tanaka, S. Ito, N. Tetreault, K. Manabe, H. Nishino, M.K. Nazeeruddin, M. Gratzel, Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency. Nat. Commun. 5, 3834 (2014)
S. Karuppuchamy, G. Murugadoss, K. Ramachandran, V. Saxena, R. Thangamuthu, Inorganic based hole transport materials for perovskite solar cells. J. Mater. Sci. Mater. Electron. 29(10), 8847–8853 (2018)
S. Chatterjee, A.J. Pal, Introducing Cu2O thin films as a hole-transport layer in efficient planar perovskite solar cell structures. J. Phys. Chem. C 120(3), 1428–1437 (2016)
J.R. Manders, S.W. Tsang, M.J. Hartel, T.H. Lai, S. Chen, C.M. Amb, J.R. Reynolds, F. So, Solution-processed nickel oxide hole transport layers in high efficiency polymer photovoltaic cells. Adv. Funct. Mater. 23(23), 2993–3001 (2013)
S. Weber, T. Rath, J. Mangalam, B. Kunert, A.M. Coclite, M. Bauch, T. Dimopoulos, G. Trimmel, Investigation of NiOx-hole transport layers in triple cation perovskite solar cells. J. Mater. Sci. Mater. Electron. 29(3), 1847–1855 (2018)
C. Besleaga, L.E. Abrarniuc, V. Stancu, A.G. Tomulescu, M. Sima, L. Trinca, N. Plugaru, L. Pintilie, G.A. Nemnes, M. Iliescu, H.G. Svavarsson, A. Manolescu, I. Pintilie, Iodine migration and degradation of perovskite solar cells enhanced by metallic electrodes. J. Phys. Chem. Lett. 7(24), 5168–5175 (2016)
K. Domanski, J.P. Correa-Baena, N. Mine, M.K. Nazeeruddin, A. Abate, M. Saliba, W. Tress, A. Hagfeldt, M. Gratzel, Not all that glitters is gold: metal-migration-induced degradation in perovskite solar cells. ACS Nano 10(6), 6306–6314 (2016)
S. Holliday, R.S. Ashraf, A. Wadsworth, D. Baran, S.A. Yousaf, C.B. Nielsen, C.H. Tan, S.D. Dimitrov, Z.R. Shang, N. Gasparini, M. Alamoudi, F. Laquai, C.J. Brabec, A. Salleo, J.R. Durrant, I. McCulloch, High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor. Nat. Commun. 7, 11585 (2016)
M. Zhang, H. Yu, J.H. Yun, M.Q. Lyu, Q. Wang, L.Z. Wang, Facile preparation of smooth perovskite films for efficient meso/planar hybrid structured perovskite solar cells. Chem. Commun. 51(49), 10038–10041 (2015)
L. Yang, U.B. Cappel, E.L. Unger, M. Karlsson, K.M. Karlsson, E. Gabrielsson, L.C. Sun, G. Boschloo, A. Hagfeldt, E.M.J. Johansson, Comparing spiro-OMeTAD and P3HT hole conductors in efficient solid state dye-sensitized solar cells. PCCP 14(2), 779–789 (2012)
J.F. Wang, L. Zhu, B.G. Zhao, Y.L. Zhao, J. Song, X.Q. Gu, Y.H. Qiang, Surface engineering of perovskite films for efficient solar cells. Sci. Rep. 7, 14478 (2017)
J.H. Im, H.S. Kim, N.G. Park, Morphology-photovoltaic property correlation in perovskite solar cells: one-step versus two-step deposition of CH3NH3PbI3. APL Mater 2(8), 081510 (2014)
W.Y. Nie, H.H. Tsai, R. Asadpour, J.C. Blancon, A.J. Neukirch, G. Gupta, J.J. Crochet, M. Chhowalla, S. Tretiak, M.A. Alam, H.L. Wang, A.D. Mohite, High-efficiency solution-processed perovskite solar cells with millimeter-scale grains. Science 347(6221), 522–525 (2015)
Y.G. Rong, Z.J. Tang, Y.F. Zhao, X. Zhong, S. Venkatesan, H. Graham, M. Patton, Y. Jing, A.M. Guloy, Y. Yao, Solvent engineering towards controlled grain growth in perovskite planar heterojunction solar cells. Nanoscale 7(24), 10595–10599 (2015)
S.D. Stranks, P.K. Nayak, W. Zhang, T. Stergiopoulos, H.J. Snaith, Formation of thin films of organic-inorganic perovskites for high-efficiency solar cells. Angew. Chem. Int. Ed. 54(11), 3240–3248 (2015)
D. Forgacs, M. Sessolo, H.J. Bolink, Lead acetate precursor based p-i-n perovskite solar cells with enhanced reproducibility and low hysteresis. J. Mater. Chem. A 3(27), 14121–14125 (2015)
P. Docampo, F.C. Hanusch, S.D. Stranks, M. Doblinger, J.M. Feckl, M. Ehrensperger, N.K. Minar, M.B. Johnston, H.J. Snaith, T. Bein, Solution deposition-conversion for planar heterojunction mixed halide perovskite solar cells. Adv. Energy Mater. 4(14), 1400355 (2014)
H.R. Tan, A. Jain, O. Voznyy, X.Z. Lan, F.P.G. de Arquer, J.Z. Fan, R. Quintero-Bermudez, M.J. Yuan, B. Zhang, Y.C. Zhao, F.J. Fan, P.C. Li, L.N. Quan, Y.B. Zhao, Z.H. Lu, Z.Y. Yang, S. Hoogland, E.H. Sargent, Efficient and stable solution-processed planar perovskite solar cells via contact passivation. Science 355(6326), 722–726 (2017)
P. Docampo, F.C. Hanusch, N. Giesbrecht, P. Angloher, A. Ivanova, T. Bein, Influence of the orientation of methylammonium lead iodide perovskite crystals on solar cell performance. APL Mater 2(8), 081508 (2014)
Q. Zhou, Z. Jin, H. Li, J. Wang, Enhancing performance and uniformity of CH3NH3PbI3–xClx perovskite solar cells by air-heated-oven assisted annealing under various humidities. Sci. Rep. 6, 21257 (2016)
G. Garcia-Belmonte, A. Munar, E.M. Barea, J. Bisquert, I. Ugarte, R. Pacios, Charge carrier mobility and lifetime of organic bulk heterojunctions analyzed by impedance spectroscopy. Org. Electron. 9(5), 847–851 (2008)
Acknowledgements
This work is supported by SERB extramural funding, India (No: EMR/2015/002415) and DST Nanomission, India (No: SR/NM/NT-1011/2105 (G)) CSIR fellowship 31/011(0927)/2015 EMR I.
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Sharma, A., Rath, A.K. Improved performance and reproducibility of perovskite solar cells by jointly tuning the hole transport layer and the perovskite layer deposition. J Mater Sci: Mater Electron 29, 12652–12661 (2018). https://doi.org/10.1007/s10854-018-9382-8
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DOI: https://doi.org/10.1007/s10854-018-9382-8