Abstract
Polyaniline (PANI) with different nanostructures has been synthesized through a simple chemical oxidation method without using any hard or soft templates. A correlation between structure, chemical construction, electrical conductivity, and electromagnetic shielding properties were extensively investigated. The obtained PANI nanostructures exhibit various morphologies by just simply changing the doping acids. The PANI doped with hydrochloric acid (denoted as PANI-HCl) and doped with camphorsulfonic acid (denoted as PANI-CSA) exhibite the “holothurian-like” morphology, while the PANI doped with phosphoric acid (denoted as PANI-H3PO4) presents the nanofiber structure. The “holothurian-like” structure showed larger diameters and length than the nanofibers. During the three samples, the PANI-CSA exhibits the highest electrical conductivity (1.28 ± 0.17 S cm−1) due to the large oxidation extent, crystallinity, and crystallite size. An excellent electromagnetic interference (EMI) shielding effectiveness (SE) as 20.7 dB of PANI-CSA was achieved with the thickness of only 0.35 mm. All these samples present an absorption-dominated shielding mechanism. Moreover, the SE values obtained from the experiments are higher than the theoretical calculations. All these above results indicated that the EMI shielding performance and dielectric permittivity were strongly affected by the microstructure and the chemical construction. We believe that this one-step procedure represents a promising protocol to control the nanostructures and properties of PANI for applications as advanced EMI shielding materials.
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A.N. Esfahani, A.A. Katbab, A. Taeb, L. Simon, M.A. Pope, Correlation between mechanical dissipation and improved X-band electromagnetic shielding capabilities of amine functionalized graphene/thermoplastic polyurethane composites. Eur. Polym. J. 95, 520–538 (2017)
Y. Zhang, X. Fang, B. Wen, W. Zou, Facile preparation of asymmetric Ni/PVC film with controlled structure: application as a high-performance EMI shielding material. J. Appl. Polym. Sci. 132, 42560 (2015)
Z. Durmus, A. Durmus, M.Y. Bektay, H. Kavas, I.S. Unver, B. Aktas, Quantifying structural and electromagnetic interference (EMI) shielding properties of thermoplastic polyurethane-carbon nanofiber/magnetite nanocomposites. J. Mater. Sci. 51, 8005–8017 (2016)
Y. Zhang, M. Qiu, Y. Yu, B. Wen, L. Cheng, A novel polyaniline-coated bagasse fiber composite with core-shell heterostructure provides effective electromagnetic shielding performance. ACS Appl. Mat. Interfaces 9, 809–818 (2017)
B.G. Soares, N. Riany, A.A. Silva, G.M.O. Barra, S. Livi, Dual-role of phosphonium: based ionic liquid in epoxy/MWCNT systems: electric, rheological behavior and electromagnetic interference shielding effectiveness. Eur. Polym. J. 84, 77–88 (2016)
Y. Zhang, X.X. Fang, B.Y. Wen, Asymmetric Ni/PVC films for high-performance electromagnetic interference shielding. Chin. J. Polym. Sci. 33, 899–907 (2015)
B. Altava, V. Compañ, A. Andrio, L. del Castillo, S. Mollá, M. Burguete, E. Garcia-Verdugo, S. Luis, Conductive films based on composite polymers containing ionic liquids absorbed on crosslinked polymeric ionic-like liquids (SILLPs). Polymer 72, 69–81 (2015)
B. Somboonsub, S. Srisuwan, M.A. Invernale, S. Thongyai, P. Praserthdam, D.A. Scola, G.A. Sotzing, Comparison of the thermally stable conducting polymers PEDOT, PANi, and PPy using sulfonated poly (imide) templates. Polymer 51, 4472–4476 (2010)
G. Ćirić-Marjanović, Recent advances in polyaniline research: polymerization mechanisms, structural aspects, properties and applications. Synth. Met. 177, 1–47 (2013)
S. Srisuwan, S. Thongyai, G.A. Sotzing, P. Praserthdam, Preparation and characterization of conductive polyimide-graft-polyaniline. Microelectron. Eng. 104, 22–28 (2013)
A.K. Sharma, P. Bhardwaj, K.K. Singh, S.K. Dhawan, Improved microwave shielding properties of polyaniline grown over three-dimensional hybrid carbon assemblage substrate. Appl. Nanosci. 5, 635–644 (2015)
A. Saboor, A.N. Khan, H.M. Cheema, K. Yaqoob, A. Shafqat, Effect of polyaniline on the dielectric and EMI shielding behaviors of styrene acrylonitrile. J. Mater. Sci.: Mater. Electron. 27, 9634–9641 (2016)
N.P. Tavandashti, M. Ghorbani, A. Shojaei, Controlled growth of hollow polyaniline structures: from nanotubes to microspheres. Comput. Theor. Polym. Sci. 54, 5586–5594 (2013)
E.M. Erro, A.M. Baruzzi, R.A. Iglesias, Fast electrochromic response of ultraporous polyaniline nanofibers. Polymer 55, 2440–2444 (2014)
X. Zhang, J. Zhu, N. Haldolaarachchige, J. Ryu, D.P. Young, S. Wei, Z. Guo, Synthetic process engineered polyaniline nanostructures with tunable morphology and physical properties. Polymer 53, 2109–2120 (2012)
L.C. Jia, D.X. Yan, C.H. Cui, X. Jiang, X. Ji, Z.M. Li, Electrically conductive and electromagnetic interference shielding of polyethylene composites with devisable carbon nanotube networks. J. Mater. Chem. C 3, 9369–9378 (2015)
T. David, J.K. Mathad, T. Padmavathi, A. Vanaja, Synthesis of polyaniline and carboxylic acid functionalized SWCNT composites for electromagnetic interference shielding coatings. Polymer 55, 5665–5672 (2014)
A.R.A. Schettini, D. Khastgir, B.G. Soares, Microwave dielectric properties and EMI shielding effectiveness of poly(styrene-b-styrene-butadiene-styrene) copolymer filled with PAni.Dodecylbenzenesulfonic acid and carbon black. Polym. Eng. Sci. 52, 2041–2048 (2012)
T. Anwer, M.O. Ansari, F. Mohammad, Dodecylbenzenesulfonic acid micelles assisted in situ preparation and enhanced thermoelectric performance of semiconducting polyaniline–zirconium oxide nanocomposites. J. Ind. Eng. Chem. 19, 1653–1658 (2013)
N.R. Chiou, L.J. Lee., A.J. Epstein, Self-assembled polyaniline nanofibers/nanotubes. Chem. Mater. 19, 3589–3591 (2007)
L.J. Zhang, M.X. Wan, Synthesis and characterization of self-assembled polyaniline nanotubes doped with D-10-camphorsulfonic acid. Nanotechnology 13, 750–755 (2002)
G.H. Lim, H.J. Choi, Synthesis of self-assembled rectangular-shaped polyaniline nanotubes and their physical characteristics. J. Ind. Eng. Chem. 47, 51–55 (2017)
J. Stejskal, I. Sapurina, M. Trchová, Polyaniline nanostructures and the role of aniline oligomers in their formation. Prog. Polym. Sci. 35, 1420–1481 (2010)
D. Li, R.B. Kaner, Shape and aggregation control of nanoparticles: not shaken, not stirred. J. Am. Chem. Soc. 128, 968–975 (2006)
N. Joseph, J. Varghese, M. Sebastian, Self assembled polyaniline nanofibers with enhanced electromagnetic shielding properties. RSC Adv. 5, 20459–20466 (2015)
Z. Zhang, Z. Wei, L. Zhang, M. Wan, Polyaniline nanotubes and their dendrites doped with different naphthalene sulfonic acids. Acta Mater. 53, 1373–1379 (2005)
F.X. Perrin, T.A. Phan, D.L. Nguyen, Preparation and characterization of polyaniline in reversed micelles of decylphosphonic acid for active corrosion protection coatings. Eur. Polym. J. 66, 253–265 (2015)
A. Drelinkiewicz, Z. Kalemba-Jaje, E. Lalik, R. Kosydar, Organo-sulfonic acids doped polyaniline: based solid acid catalysts for the formation of bio-esters in transesterification and esterification reactions. Fuel 116, 760–771 (2014)
J. Wang, K. Zhang, L. Zhao, Sono-assisted synthesis of nanostructured polyaniline for adsorption of aqueous Cr(VI): effect of protonic acids. Chem. Eng. J. 239, 123–131 (2014)
M. Bláha, M. Varga, J. Prokeš, A. Zhigunov, J. Vohlídal, Effects of the polymerization temperature on the structure, morphology and conductivity of polyaniline prepared with ammonium peroxodisulfate. Eur. Polym. J. 49, 3904–3911 (2013)
F. Rezaei, N.P. Tavandashti, A.R. Zahedi, Morphology of polyaniline nanofibers synthesized under different conditions. Res. Chem. Intermed. 40, 1233–1247 (2014)
A.M. Youssef, Morphological studies of polyaniline nanocomposite based mesostructured TiO2 nanowires as conductive packaging materials. RSC Adv. 4, 6811–6820 (2013)
S. Atifi, W.Y. Hamad, Emulsion-polymerized flexible semi-conducting CNCs–PANI–DBSA nanocomposite films. RSC Adv. 6, 65494–65503 (2016)
O. Abdulrazzaq, S.E. Bourdo, V. Saini, F. Watanabe, B. Barnes, A. Ghosh, A.S. Biris, Tuning the work function of polyaniline via camphorsulfonic acid: an X-ray photoelectron spectroscopy investigation. RSC Adv. 5, 33–40 (2014)
S. Tao, B. Hong, Z. Kerong, An infrared and Raman spectroscopic study of polyanilines co-doped with metal ions and H+. Spectrochim. Acta A 66, 1364–1368 (2007)
H.R. Tantawy, D.E. Aston, J.R. Smith, J.L. Young, Comparison of electromagnetic shielding with polyaniline nanopowders produced in solvent-limited conditions. ACS Appl. Mater. Interfaces 5, 4648–4658 (2013)
N. Joseph, J. Varghese, M.T. Sebastian, Self assembled polyaniline nanofibers with enhanced electromagnetic shielding properties. RSC Adv. 5, 20459–20466 (2015)
M. Das, D. Sarkar, Effect of oxidizing agent on ammonia sensing of DBSA doped polyaniline nanocomposite thin film. J. Mater. Sci.: Mater. Electron. 27, 4109–4119 (2016)
M. Magioli, B.G. Soares, A.S. Sirqueira, M. Rahaman, D. Khastgir, EMI shielding effectiveness and dielectrical properties of SBS/PAni.DBSA blends: effect of blend preparation. J. Appl. Polym. Sci. 125, 1476–1485 (2012)
A.R.A. Schettini, B.G. Soares, Study of microwave absorbing properties of polyaniline/STF conducting composites prepared by in situ polymerization. Macromol. Symp. (2011). https://doi.org/10.1002/masy.200900106
M.H. Al-Saleh, U. Sundararaj, Electromagnetic interference shielding mechanisms of CNT/polymer composites. Carbon 47, 1738–1746 (2009)
Y. Chen, Y. Li, M. Yip, N. Tai, Electromagnetic interference shielding efficiency of polyaniline composites filled with graphene decorated with metallic nanoparticles. Compos. Sci. Technol. 80, 80–86 (2013)
H. Ghasemi, U. Sundararaj, Electrical properties of in situ polymerized polystyrene/polyaniline composites: the effect of feeding ratio. Synth. Met. 162, 1177–1183 (2012)
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (21274007), Young Core Personal Project & Beijing Outstanding Talent Training Project (2017000020124G079), the Science and Technology Development Project of Beijing Municipal Commission of Education (SQKM201610011001), Innovative Research Team of Polymeric Functional Film of Beijing Technology and Business University (19008001071), the Two Sections Cultivation Fund of Beijing Technology and Business University (LKJJ2016-23), and Beijing College Students’ Scientific Research Training Program.
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Qiu, M., Zhang, Y. & Wen, B. Facile synthesis of polyaniline nanostructures with effective electromagnetic interference shielding performance. J Mater Sci: Mater Electron 29, 10437–10444 (2018). https://doi.org/10.1007/s10854-018-9100-6
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DOI: https://doi.org/10.1007/s10854-018-9100-6