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CdS nanowires encapsulated liquid crystal in-plane switching of LCD device

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Abstract

Well-defined ultra-thin ‘wire’ like cadmium sulfide (CdS) nanostructures have been synthesized by applying simple cost-effective hydrothermal route. The content of nanostructures modifies the nature of surface interaction between two liquid crystal (LC) components as revealed by optical and electrical investigation. Those synthesized nanowires have an average diameter of about 7–10 nm and length up to several micrometers region. A possible mechanism has been proposed and the addition of cataionic surfactant cetyltrimethylammonium bromide (CTAB) into the two mixed-solvents would play an important role on the growth dynamics of the desired product. Those CdS-nanowires dispersing LC was found a remarkable signature on the nucleation and provides a more fundamental approach to modify the crystallographic configuration of host nanostructures. Polarizing optical microscopy (POM) revealed temperature dependent various phases appearence in different textural patterns are the proof the significant influence of CdS nanomaterials complete homogenious dispersion with host LC-matrix. Most observed phenomena are discussed in terms of a new smectic ordering labeled as ‘Smectic X*’, which is sandwiched between the traditional ‘Nematic’ and convectional ‘Smectic C*’ phases. This feature article deals with dielectric relaxations, rotational viscosity, spontaneous polarization in the smectic C phase have been analyzed. A range of remarkable responses of the capacitance with voltage in a Preisach model, fourfold dipolar species in hybrid nanocomposites matrix as well as bi-stable DC switching also offering recent breakthroughs in next generation smart display (LCD) and novel switchable device.

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References

  1. Y. Xia et al., One-dimensional nanostructures: synthesis, characterization, and applications. Adv. Mater. 15(5), 353–389 (2003)

    Article  CAS  Google Scholar 

  2. A.L. Prieto et al., Electrodeposition of ordered Bi2Te3 nanowire arrays. J. Am. Chem. Soc. 123(29), 7160–7161 (2001)

    Article  CAS  Google Scholar 

  3. L. Brus, Quantum crystallites and nonlinear optics. Appl. Phys. A 53(6), 465–474 (1991)

    Article  Google Scholar 

  4. H. Weller, Colloidal semiconductor q-particles: chemistry in the transition region between solid state and molecules. Angew. Chem. Int. Ed. 32(1), 41–53 (1993)

    Article  Google Scholar 

  5. K. Pal et al., A facile strategy for the fabrication of uniform CdS nanowires with high yield and its controlled morphological growth with the assistance of PEG in hydrothermal route. Appl. Surf. Sci. 258(1), 163–168 (2011)

    Article  CAS  Google Scholar 

  6. K. Pal et al., Synthetic strategy of porous ZnO and CdS nanostructures doped ferroelectric liquid crystal and its optical behavior. J. Mol. Struct. 1035, 76–82 (2013)

    Article  CAS  Google Scholar 

  7. K. Pal et al., Dielectric and I–V characteristics of high luminous CdS nanostructures with confined geometrical growth. J. Mol. Struct. 1041, 16–22 (2013)

    Article  CAS  Google Scholar 

  8. K. Pal et al., Switching of ferroelectric liquid crystal doped with cetyltrimethylammonium bromide-assisted CdS nanostructures. Nanotechnology 24(12), 125702 (2013)

    Article  Google Scholar 

  9. K. Pal et al., Ultraviolet visible spectroscopy of CdS nano-wires doped ferroelectric liquid crystal. J. Mol. Liq. 164(3), 233–238 (2011)

    Article  CAS  Google Scholar 

  10. K. Pal et al., Temperature variation dielectric behavior of TiO2 nanocabbages and doped W-182 (AFLC). J. Lumin. 136, 278–284 (2013)

    Article  CAS  Google Scholar 

  11. K. Pal et al., Optical and electrical investigation of ZnO nano-wire array to micro-flower from hierarchical nano-rose structures. J. Nanosci. Nanotechnol. 16(1), 400–409 (2016)

    Article  CAS  Google Scholar 

  12. K. Pal et al., Influence of ZnO nanostructures in liquid crystal interfaces for bistable switching applications. Appl. Surf. Sci. 357, 1499–1510 (2015)

    Article  CAS  Google Scholar 

  13. K. Pal et al., Design, synthesis and application of hydrogen bonded smectic liquid crystal matrix encapsulated ZnO nanospikes. J. Mater. Chem. C 3(45), 11907–11917 (2015)

    Article  CAS  Google Scholar 

  14. G.C. Pimentel, A. McClellan, Hydrogen bonding. Annu. Rev. Phys. Chem. 22(1), 347–385 (1971)

    Article  CAS  Google Scholar 

  15. T. Elsaesser, H. Becker, Ultrafast Hydrogen Bonding Dynamics and Proton Transfer Processes in the Condensed Phase, vol. 23 (Springer, New York, 2013)

    Google Scholar 

  16. I. Gitsov, K. Wooley, J. Fréchet, Angew. Chem. Int. Ed. 31, 1200 (1992)

    Article  Google Scholar 

  17. I. Gitsov, K.L. Wooley, C.J. Hawker, P.T. Ivanova, J.M.J. Fréchet, Macromolecules 26, 5621 (1993)

    Article  CAS  Google Scholar 

  18. L. Yu, Hydrogen bond-induced ferroelectric liquid crystals. Liq. Cryst. 14(5), 1303–1309 (1993)

    Article  CAS  Google Scholar 

  19. K. Pal et al., Switchable, self-assembled CdS nanomaterials embedded in liquid crystal cell for high performance static memory device. Mater. Lett. 169, 37–41 (2016)

    Article  CAS  Google Scholar 

  20. S. Miller et al., Modeling ferroelectric capacitor switching with asymmetric nonperiodic input signals and arbitrary initial conditions. J. Appl. Phys. 70(5), 2849–2860 (1991)

    Article  Google Scholar 

  21. S. Miller et al., Device modeling of ferroelectric capacitors. J. Appl. Phys. 68(12), 6463–6471 (1990)

    Article  Google Scholar 

  22. P. Yang et al., Electrical properties of SrBi2Ta2O9 ferroelectric thin films at low temperature. Appl. Phys. Lett. 81(24), 4583–4585 (2002)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The author Dr. Kaushik Pal is grateful to his associate colleagues & doctoral research scholars at Wuhan University, China. Especially, Dr. Pal, owe to his sincere thanks to associate colleagues included Bachelor/Masters/Ph.D. students, spectroscopy/electron microscopy operators, as well as entire team of research scholars are also gratefully acknowledged during “Visiting Scientist” associate ship at CNU, South Korea. We are honor to Prof. Mohan’s co-workers of the Liquid Crystals Research Laboratory at Bannari Amman Institute of Technology, Sathyamangalam encouraging liquid crystal preparation. Sincere ‘Thanks’ goes to Dean (Research), at BIHER Chennai (India) for providing Dr. Pal to develope the excellence of research foundation associated with existing Nanotechnology laboratory. The research scholars from Niel University, Egypt are gratefully acknowledged for giving scopes to develop research ideas and scientific innovations. The author Mohamed Abd Elkodous is also grateful to Dean (Research) for giving research friendly scopes at Nile University, Egypt.

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Correspondence to Kaushik Pal.

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All the authors have declared that, there is no conflict of interest regarding the contribution to the feature article publication.

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Pal, K., Elkodous, M.A. & Mohan, M.L.N.M. CdS nanowires encapsulated liquid crystal in-plane switching of LCD device. J Mater Sci: Mater Electron 29, 10301–10310 (2018). https://doi.org/10.1007/s10854-018-9083-3

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